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Page 1
Configurations and Sensory Properties of the Stereoisomers of 2,6-Dimethyl-4-propyl-1,3-oxathiane and 2,4-Dimethyl-6-propyl-1,3-oxathiane.
Riegel AD, Wakabayashi H, Wakabayashi M, Rynešová M, Dudko V, Eisenreich W, Engel KH. Riegel AD, et al. J Agric Food Chem. 2022 Apr 20;70(15):4712-4724. doi: 10.1021/acs.jafc.2c00509. Epub 2022 Apr 5. J Agric Food Chem. 2022. PMID: 35380838
The heterocyclic compounds 2,6-dimethyl-4-propyl-1,3-oxathiane 1 and 2,4-dimethyl-6-propyl-1,3-oxathiane 2 were obtained by condensing 4-mercapto-2-heptanol and 2-mercapto-4-heptanol, respectively, with acetaldehyde. ...The data demonstrate the impact of the positio …
The heterocyclic compounds 2,6-dimethyl-4-propyl-1,3-oxathiane 1 and 2,4-dimethyl-6-propyl-1,3-oxathiane 2 were obtained by co …
Chiral analysis of cis-2-methyl-4-propyl-1,3-oxathiane and identification of cis-2,4,4,6-tetramethyl-1,3-oxathiane in wine.
Wang X, Capone DL, Roland A, Jeffery DW. Wang X, et al. Food Chem. 2021 Mar 2;357:129406. doi: 10.1016/j.foodchem.2021.129406. Online ahead of print. Food Chem. 2021. PMID: 33892361
cis-2-Methyl-4-propyl-1,3-oxathiane (cis-2-MPO), arising from 3-sulfanylhexan-1-ol (3-SH) and acetaldehyde, was recently identified in wine, but the enantiomeric distribution was unknown. ...This new 1,3-oxathiane, which presents a novel fate for 4-MSPOH, was detect …
cis-2-Methyl-4-propyl-1,3-oxathiane (cis-2-MPO), arising from 3-sulfanylhexan-1-ol (3-SH) and acetaldehyde, was recently identified i …
Identification and Quantitative Analysis of 2-Methyl-4-propyl-1,3-oxathiane in Wine.
Chen L, Capone DL, Jeffery DW. Chen L, et al. J Agric Food Chem. 2018 Oct 17;66(41):10808-10815. doi: 10.1021/acs.jafc.8b04027. Epub 2018 Oct 5. J Agric Food Chem. 2018. PMID: 30289700
On the basis of the chemistry of wine and the co-occurrence of 3-sulfanylhexan-1-ol (3-SH) and acetaldehyde, we investigated the existence of 2-methyl-4-propyl-1,3-oxathiane (1) and identified the presence of a single detectable geometric isomer, cis-1, in wines for the fi …
On the basis of the chemistry of wine and the co-occurrence of 3-sulfanylhexan-1-ol (3-SH) and acetaldehyde, we investigated the existence o …
Poly(thieno[3,4-b]-1,4-oxathiane): medium effect on electropolymerization and electrochromic performance.
Wang Z, Xu J, Lu B, Zhang S, Qin L, Mo D, Zhen S. Wang Z, et al. Langmuir. 2014 Dec 30;30(51):15581-9. doi: 10.1021/la503948f. Epub 2014 Dec 17. Langmuir. 2014. PMID: 25469424
The asymmetrical sulfur analog of 3,4-ethylenedioxythiophene (EDOT), thieno[3,4-b]-1,4-oxathiane (EOTT), was synthesized, and its electropolymerization was comparatively investigated by employing different solvent-electrolyte systems (room temperature ionic liquid 1-butyl- …
The asymmetrical sulfur analog of 3,4-ethylenedioxythiophene (EDOT), thieno[3,4-b]-1,4-oxathiane (EOTT), was synthesized, and its ele …
cis-Bis(dimethyl sulfoxide-S)dinitratopalladium(II) and cis-dinitratobis(1,4-oxathiane-S)palladium(II).
Johansson MH, Oskarsson A. Johansson MH, et al. Acta Crystallogr C. 2001 Nov;57(Pt 11):1265-7. doi: 10.1107/s0108270101013579. Epub 2001 Nov 13. Acta Crystallogr C. 2001. PMID: 11706243
The Pd atom in each of the two title compounds, [Pd(NO(3))(2)(C(2)H(6)OS)(2)], (I), and [Pd(NO(3))(2)(C(4)H(8)OS)(2)], (II), coordinates two O atoms from two nitrate ligands and two S atoms from dimethyl sulfoxide (dmso) and thioxane (systematic name: 1,4-oxathiane) ligand …
The Pd atom in each of the two title compounds, [Pd(NO(3))(2)(C(2)H(6)OS)(2)], (I), and [Pd(NO(3))(2)(C(4)H(8)OS)(2)], (II), coordinates two …
RIFM fragrance ingredient safety assessment, 2-methyl-4-propyl-1,3-oxathiane, CAS registry number 67715-80-4.
Api AM, Belsito D, Botelho D, Bruze M, Burton GA Jr, Buschmann J, Dagli ML, Date M, Dekant W, Deodhar C, Francis M, Fryer AD, Jones L, Joshi K, La Cava S, Lapczynski A, Liebler DC, O'Brien D, Patel A, Penning TM, Ritacco G, Romine J, Sadekar N, Salvito D, Schultz TW, Sipes IG, Sullivan G, Thakkar Y, Tokura Y, Tsang S. Api AM, et al. Food Chem Toxicol. 2020 Jul 15;141 Suppl 1:111378. doi: 10.1016/j.fct.2020.111378. Epub 2020 Apr 26. Food Chem Toxicol. 2020. PMID: 32348817 Review. No abstract available.
Sonochemical synthesis of novel C(60) fullerene 1,4-oxathiane derivative through the intermediate fullerene radical anion.
Kinzyabaeva ZS, Sabirov DS. Kinzyabaeva ZS, et al. Ultrason Sonochem. 2020 Oct;67:105169. doi: 10.1016/j.ultsonch.2020.105169. Epub 2020 May 8. Ultrason Sonochem. 2020. PMID: 32417624 Free article.
Based on the experimental results and quantum chemical calculations, we have proposed a mechanism for the conversion of C(60) and 2-mercaptoethanol to the C(60)-1,4-oxathiane adduct....
Based on the experimental results and quantum chemical calculations, we have proposed a mechanism for the conversion of C(60) and 2-mercapto …
Kinetics of the gas-phase reactions of OH and NO3 radicals and O3 with 1,4-thioxane and 1,4-dithiane.
Aschmann SM, Long WD, Atkinson R. Aschmann SM, et al. J Phys Chem A. 2008 Dec 25;112(51):13556-65. doi: 10.1021/jp8074018. J Phys Chem A. 2008. PMID: 19093823
For the OH radical reactions, the temperature-dependent rate expressions obtained were k(OH + 1,4-thioxane) = 2.54 x 10(-12) e((619+/-51)/T) cm(3) molecule(-1) s(-1) (278-349 K) and k(OH + 1,4-dithiane) = 3.71 x 10(-12) e((621+/-163)/T) cm(3) molecule(-1) s(- …
For the OH radical reactions, the temperature-dependent rate expressions obtained were k(OH + 1,4-thioxane) = 2.54 x 10 …
Vibrational frequencies and structural determinations of 1,4-thioxane.
Ellzy MW, Jensen JO, Hameka HF, Kay JG, Zeroka D. Ellzy MW, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2001 Oct;57(12):2417-32. doi: 10.1016/s1386-1425(01)00423-1. Spectrochim Acta A Mol Biomol Spectrosc. 2001. PMID: 11767836
We present a detailed analysis of the structure and infrared spectra of 1,4-thioxane. The vibrational frequencies of the 1,4-thioxane molecule were analyzed using standard quantum chemical techniques. ...High-energy forms of 1,4 …
We present a detailed analysis of the structure and infrared spectra of 1,4-thioxane. The vibrational frequencies of th …
86 results