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Antagonistic Activity of Volatile Organic Compounds Produced by Acid-Tolerant Pseudomonas protegens CLP-6 as Biological Fumigants To Control Tobacco Bacterial Wilt Caused by Ralstonia solanacearum.
Zhao Q, Cao J, Cai X, Wang J, Kong F, Wang D, Wang J. Zhao Q, et al. Appl Environ Microbiol. 2023 Feb 28;89(2):e0189222. doi: 10.1128/aem.01892-22. Epub 2023 Feb 1. Appl Environ Microbiol. 2023. PMID: 36722969 Free PMC article.
Finally, the main volatile compounds were identified by solid-phase microextraction (SPME)-gas chromatography-mass spectroscopy (GC-MS) as S-methyl thioacetate, methyl thiocyanate, methyl disulfide, 1-decene, 2-ethylhexanol, 1,4-undecadiene, 1-undecene, 1,3-benzothi …
Finally, the main volatile compounds were identified by solid-phase microextraction (SPME)-gas chromatography-mass spectroscopy (GC-MS) as S …
Extracting accurate infrared lineshapes from weak vibrational probes at low concentrations.
Maia RNA, Mitra S, Baiz CR. Maia RNA, et al. MethodsX. 2023 Aug 1;11:102309. doi: 10.1016/j.mex.2023.102309. eCollection 2023 Dec. MethodsX. 2023. PMID: 37577166 Free PMC article.
In this protocol we demonstrate:A streamlined approach for the precise extraction of weak infrared absorption lineshapes from a strong solvent background.A protocol combining a spectral filter, background modeling, and subtraction.Our methodology successfully extracts the CN stre …
In this protocol we demonstrate:A streamlined approach for the precise extraction of weak infrared absorption lineshapes from a strong solve …
Origin of thiocyanate spectral shifts in water and organic solvents.
Zhao R, Shirley JC, Lee E, Grofe A, Li H, Baiz CR, Gao J. Zhao R, et al. J Chem Phys. 2022 Mar 14;156(10):104106. doi: 10.1063/5.0082969. J Chem Phys. 2022. PMID: 35291777 Free PMC article.
In this paper, we demonstrate several reasons for the difficulty in constructing a general-purpose vibrational map for methyl thiocyanate (MeSCN), a model for cyanylated biological probes. ...
In this paper, we demonstrate several reasons for the difficulty in constructing a general-purpose vibrational map for methyl thio …
2D-IR spectroscopy of carbohydrates: Characterization of thiocyanate-labeled β-glucose in CHCl3 and H2O.
Gasse P, Stensitzki T, Mai-Linde Y, Linker T, Müller-Werkmeister HM. Gasse P, et al. J Chem Phys. 2023 Apr 14;158(14):145101. doi: 10.1063/5.0139166. J Chem Phys. 2023. PMID: 37061468
Upon improved synthesis and the removal of all protecting groups, we successfully performed 2D-IR spectroscopy of beta-glucose in H(2)O. All experimental results are compared to those of methyl-thiocyanate as a reference sample. Overall, we show that the concept of …
Upon improved synthesis and the removal of all protecting groups, we successfully performed 2D-IR spectroscopy of beta-glucose in H(2)O. All …
Quantification of methyl thiocyanate in the headspace of Pseudomonas aeruginosa cultures and in the breath of cystic fibrosis patients by selected ion flow tube mass spectrometry.
Shestivska V, Nemec A, Dřevínek P, Sovová K, Dryahina K, Spaněl P. Shestivska V, et al. Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2459-67. doi: 10.1002/rcm.5146. Rapid Commun Mass Spectrom. 2011. PMID: 21818806
The kinetics library was extended by a new entry for methyl thiocyanate accounting for overlaps with isotopologues of hydrated hydronium ions. ...SIFT-MS was also used to analyze the breath of 28 children with CF and the concentrations of methyl thiocyanat …
The kinetics library was extended by a new entry for methyl thiocyanate accounting for overlaps with isotopologues of hydrated …
Identification of glucosinolates and volatile odor compounds in microwaved radish (Raphanus sativus L.) seeds and the corresponding oils by UPLC-IMS-QTOF-MS and GC × GC-qMS analysis.
Jia X, Yu P, An Q, Ren J, Fan G, Wei Z, Li X, Pan S. Jia X, et al. Food Res Int. 2023 Jul;169:112873. doi: 10.1016/j.foodres.2023.112873. Epub 2023 Apr 27. Food Res Int. 2023. PMID: 37254321
The major odor compounds were (methyldisulfanyl)methane, dimethyltrisulfane, (methylsulfinyl)methane, 3-(methylsulfanyl)-1-propanol, methyl thiocyanate, hexanenitrile, 5-(methylsulfanyl)pentanenitrile, and 4-isothiocyanato-1-butene with odor activity value (OAV) hig …
The major odor compounds were (methyldisulfanyl)methane, dimethyltrisulfane, (methylsulfinyl)methane, 3-(methylsulfanyl)-1-propanol, meth …
Burying Beetle Parents Adaptively Manipulate Information Broadcast from a Microbial Community.
Trumbo ST, Philbrick PKB, Stökl J, Steiger S. Trumbo ST, et al. Am Nat. 2021 Mar;197(3):366-378. doi: 10.1086/712602. Epub 2021 Jan 14. Am Nat. 2021. PMID: 33625971
We contrasted gas chromatography-mass spectrometry (GC-MS) volatile profiles from carcasses that were or were not prepared by a resident pair of Nicrophorus orbicollis. Methyl thiocyanate (MeSCN), the primary attractant for burying beetles seeking a fresh carcass, w …
We contrasted gas chromatography-mass spectrometry (GC-MS) volatile profiles from carcasses that were or were not prepared by a resident pai …
Enhanced Menshutkin SN2 Reactivity in Mesoporous Silica: The Influence of Surface Catalysis and Confinement.
Zheng W, Yamada SA, Hung ST, Sun W, Zhao L, Fayer MD. Zheng W, et al. J Am Chem Soc. 2020 Mar 25;142(12):5636-5648. doi: 10.1021/jacs.9b12666. Epub 2020 Mar 5. J Am Chem Soc. 2020. PMID: 32077695
A significant enhancement in the Menshutkin S(N)2 reaction between 1-methylimidazole (MeIm) and methyl thiocyanate (MeSCN) is observed when the reaction is confined in the nanoscale silica pores of MCM41 and SBA15. ...
A significant enhancement in the Menshutkin S(N)2 reaction between 1-methylimidazole (MeIm) and methyl thiocyanate (MeSCN) is …
Experimental two-dimensional infrared spectra of methyl thiocyanate in water and organic solvents.
Shirley JC, Baiz CR. Shirley JC, et al. J Chem Phys. 2024 Mar 21;160(11):114501. doi: 10.1063/5.0190343. J Chem Phys. 2024. PMID: 38488086
Specifically, we catalog spectra of the nitrile stretching mode of methyl thiocyanate (MeSCN) in fourteen different solvents, including non-polar, polar, and protic solvents. ...
Specifically, we catalog spectra of the nitrile stretching mode of methyl thiocyanate (MeSCN) in fourteen different solvents, …
The antimicrobial volatile power of the rhizospheric isolate Pseudomonas donghuensis P482.
Ossowicki A, Jafra S, Garbeva P. Ossowicki A, et al. PLoS One. 2017 Mar 30;12(3):e0174362. doi: 10.1371/journal.pone.0174362. eCollection 2017. PLoS One. 2017. PMID: 28358818 Free PMC article.
The production of certain volatiles such as dimethyl sulfide, S-methyl thioacetate, methyl thiocyanate, dimethyl trisulfide, 1-undecan and HCN is depended on the GacS/GacA two-component regulatory system. ...
The production of certain volatiles such as dimethyl sulfide, S-methyl thioacetate, methyl thiocyanate, dimethyl trisulfide, 1 …
34 results