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Addition/oxidative rearrangement of 3-furfurals and 3-furyl imines: new approaches to substituted furans and pyrroles.
Kelly AR, Kerrigan MH, Walsh PJ. Kelly AR, et al. J Am Chem Soc. 2008 Mar 26;130(12):4097-104. doi: 10.1021/ja710988q. Epub 2008 Mar 4. J Am Chem Soc. 2008. PMID: 18314989
This later method has been applied to the enantioselective preparation of an intermediate in Honda's synthesis of the natural product (-)-canadensolide. Mechanistic studies involving deuterium-labeled furyl alcohol suggest that the oxidative rearrangement proceeds through …
This later method has been applied to the enantioselective preparation of an intermediate in Honda's synthesis of the natural product (-)- …