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Orotic acid decarboxylation in water and nonpolar solvents: a potential role for desolvation in the action of OMP decarboxylase.
Lewis CA Jr, Wolfenden R. Lewis CA Jr, et al. Biochemistry. 2009 Sep 15;48(36):8738-45. doi: 10.1021/bi901085m. Biochemistry. 2009. PMID: 19678695 Free PMC article.
The uncatalyzed decarboxylation of 1-methylorotate in water is shown to involve the monoanion, although uncharged 1-methylorotic acid is decarboxylated at a similar rate. To measure the extent to which the rate of the nonenzymatic decarboxylation of orotate d …
The uncatalyzed decarboxylation of 1-methylorotate in water is shown to involve the monoanion, although uncharged 1-methylorotic
A proficient enzyme.
Radzicka A, Wolfenden R. Radzicka A, et al. Science. 1995 Jan 6;267(5194):90-3. doi: 10.1126/science.7809611. Science. 1995. PMID: 7809611