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Pyrethrins.
[No authors listed] [No authors listed] 2023 Sep 15. Drugs and Lactation Database (LactMed®) [Internet]. Bethesda (MD): National Institute of Child Health and Human Development; 2006–. 2023 Sep 15. Drugs and Lactation Database (LactMed®) [Internet]. Bethesda (MD): National Institute of Child Health and Human Development; 2006–. PMID: 30000694 Free Books & Documents. Review.
Creating Pyrethrin Mimetic Phosphonates as Chemical Genetics Tools Targeting the GDSL Esterase/Lipase TcGLIP to Investigate Pyrethrin Biosynthesis.
Matsuo N, Sugisaka Y, Aoyama S, Ihara M, Shinoyama H, Hosokawa M, Kamakura Y, Tanaka D, Tanabe Y, Matsuda K. Matsuo N, et al. J Med Chem. 2023 Jun 22;66(12):7959-7968. doi: 10.1021/acs.jmedchem.3c00285. Epub 2023 Jun 13. J Med Chem. 2023. PMID: 37309671 Free PMC article.
The compounds were synthesized by reacting mono-alkyl or mono-benzyl-substituted phosphonic dichloride with pyrethrolone, the alcohol moiety of pyrethrin I and II, and then p-nitrophenol. n-Pentyl (C5) and n-octyl (C8)-substituted compounds were the most potent of t …
The compounds were synthesized by reacting mono-alkyl or mono-benzyl-substituted phosphonic dichloride with pyrethrolone, the alcohol moiety …
High diversity of natural Dalmatian pyrethrum based on pyrethrin composition at intra- and interpopulation level.
Varga F, Jeran N, Šatović Z, Biošić M, Grdiša M. Varga F, et al. Phytochemistry. 2021 Dec;192:112934. doi: 10.1016/j.phytochem.2021.112934. Epub 2021 Sep 15. Phytochemistry. 2021. PMID: 34536804
The population of Mali Losinj had the most favourable pyrethrin profile, including the lowest variability in total pyrethrin content, the highest pyrethrin I (PI) content (up to 60.47%) and PI/PII ratio (up to 5.88), as well as the lowest pyrethrin II (PII) content. …
The population of Mali Losinj had the most favourable pyrethrin profile, including the lowest variability in total pyrethrin content, the hi …
Total Syntheses of All Six Chiral Natural Pyrethrins: Accurate Determination of the Physical Properties, Their Insecticidal Activities, and Evaluation of Synthetic Methods.
Kawamoto M, Moriyama M, Ashida Y, Matsuo N, Tanabe Y. Kawamoto M, et al. J Org Chem. 2020 Mar 6;85(5):2984-2999. doi: 10.1021/acs.joc.9b02767. Epub 2020 Feb 11. J Org Chem. 2020. PMID: 31912734
Chiral total syntheses of all six insecticidal natural pyrethrins (three pyrethrin I and three pyrethrin II compounds) contained in the chrysanthemum (pyrethrum) flower were performed. ...Insecticidal activity assay (KD(50) and IC(50)) against the common mosquito (C …
Chiral total syntheses of all six insecticidal natural pyrethrins (three pyrethrin I and three pyrethrin II compounds) contain …
Biomarker of pyrethrum exposure.
Leng G, Gries W, Selim S. Leng G, et al. Toxicol Lett. 2006 Apr 10;162(2-3):195-201. doi: 10.1016/j.toxlet.2005.09.030. Epub 2005 Oct 27. Toxicol Lett. 2006. PMID: 16257148
To obtain information about the elimination kinetics of pyrethrum in humans, urinary excretion of CDCA was investigated in three volunteers after oral intake of 0.3mg pyrethrin I. CDCA was detected during the first 36 h after intake with elimination being most rapid …
To obtain information about the elimination kinetics of pyrethrum in humans, urinary excretion of CDCA was investigated in three volunteers …
Key Amino Acids for Transferase Activity of GDSL Lipases.
Yamashiro T, Shiraishi A, Nakayama K, Satake H. Yamashiro T, et al. Int J Mol Sci. 2022 Dec 1;23(23):15141. doi: 10.3390/ijms232315141. Int J Mol Sci. 2022. PMID: 36499468 Free PMC article.
The Gly-Asp-Ser-Leu (GDSL) motif of esterase/lipase family proteins (GELPs) generally exhibit esterase activity, whereas transferase activity is markedly preferred in several GELPs, including the Tanacetum cinerariifolium GDSL lipase TciGLIP, which is responsible for the biosynth …
The Gly-Asp-Ser-Leu (GDSL) motif of esterase/lipase family proteins (GELPs) generally exhibit esterase activity, whereas transferase activit …
Molecular Markers for Pyrethrin Autoxidation in Stored Pyrethrum Crop: Analysis and Structure Determination.
Freemont JA, Littler SW, Hutt OE, Mauger S, Meyer AG, Winkler DA, Kerr MG, Ryan JH, Cole HF, Duggan PJ. Freemont JA, et al. J Agric Food Chem. 2016 Sep 28;64(38):7134-41. doi: 10.1021/acs.jafc.6b02959. Epub 2016 Sep 19. J Agric Food Chem. 2016. PMID: 27599033
It was found that pyrethrins I and II, the major pyrethrin esters present in pyrethrum, undergo autoxidation more readily than the minor pyrethrin esters, the jasmolins and cinerins. Chromatographic analysis of pyrethrin I and II autoxidation mixtures showed some co …
It was found that pyrethrins I and II, the major pyrethrin esters present in pyrethrum, undergo autoxidation more readily than the minor pyr …
Chemical diversity of the natural populations of Dalmatian pyrethrum (Tanacetum cinerariifolium (TREVIR.) SCH.BIP.) in Croatia.
Grdiša M, Babić S, Periša M, Carović-Stanko K, Kolak I, Liber Z, Jug-Dujaković M, Satovic Z. Grdiša M, et al. Chem Biodivers. 2013 Mar;10(3):460-72. doi: 10.1002/cbdv.201200015. Chem Biodivers. 2013. PMID: 23495162
The total pyrethrin content ranged from 0.36 to 1.30% (dry flower weight; DW) and the pyrethrin I/pyrethrin II ratio ranged from 0.64 to 3.33%. The statistical analyses revealed that the correlations between the percentage of pyrethrin I and of all the …
The total pyrethrin content ranged from 0.36 to 1.30% (dry flower weight; DW) and the pyrethrin I/pyrethrin II ratio ranged fr …
Permethrin as a Potential Furin Inhibitor through a Novel Non-Competitive Allosteric Inhibition.
Feng D, Ren L, Wu J, Guo L, Han Z, Yang J, Xie W, Wang Y, Xu F, Su X, Li D, Cao H. Feng D, et al. Molecules. 2023 Feb 16;28(4):1883. doi: 10.3390/molecules28041883. Molecules. 2023. PMID: 36838867 Free PMC article.
A novel furin inhibitor, permethrin, which is a derivative from pyrethrin I generated by Pyrethrum cinerariifolium Trev. was identified, and this study confirmed that it binds to a novel allosteric pocket of furin through non-competitive inhibition. ...
A novel furin inhibitor, permethrin, which is a derivative from pyrethrin I generated by Pyrethrum cinerariifolium Trev. was i …
Antiplasmodial and antitrypanosomal activity of pyrethrins and pyrethroids.
Hata Y, Zimmermann S, Quitschau M, Kaiser M, Hamburger M, Adams M. Hata Y, et al. J Agric Food Chem. 2011 Sep 14;59(17):9172-6. doi: 10.1021/jf201776z. Epub 2011 Aug 3. J Agric Food Chem. 2011. PMID: 21786822
We isolated the five pyrethrins [i.e., pyrethrin II (1), jasmolin II (2), cinerin II (3), pyrethrin I (4), and jasmolin I (5)] from this extract. These were tested together with 15 synthetic pyrethroids for their activity against P. falciparum and Trypanosoma brucei …
We isolated the five pyrethrins [i.e., pyrethrin II (1), jasmolin II (2), cinerin II (3), pyrethrin I (4), and jasmolin I (5)] …
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