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The recognition of a diarylimine as a metabonate produced during incubation of N-benzyl-4-chloroaniline with hepatic microsomal preparations.
Low CM, Ulgen M, Gorrod JW. Low CM, et al. J Pharm Pharmacol. 1994 Jul;46(7):585-90. doi: 10.1111/j.2042-7158.1994.tb03862.x. J Pharm Pharmacol. 1994. PMID: 7996388
Evidence is presented for the formation of N-benzylidene-4-chloroaniline as a metabonate during the metabolism of N-benzyl-4-chloroaniline. Control studies suggest that the diarylimine is formed as a chemical artifact from the debenzylation products (b …
Evidence is presented for the formation of N-benzylidene-4-chloroaniline as a metabonate during the metabolism of N-benzyl- …
A concise and efficient concurrent synthesis of 6,11-dihydrodibenzo[b,e]azepines and 5,6,11,12-tetrahydrodibenzo[b,f]azocines and their conversion to 4-oxo-8,13-dihydro-4H-benzo[5,6]azepino[3,2,1-ij]quinoline-5-carboxylates and N-acetyl-5,6,11,12-tetrahydrodibenzo[b,f]azocines: synthetic sequence, spectroscopic characterization and the structures of two products.
Acosta Quintero LM, Palma A, Cobo J, Glidewell C. Acosta Quintero LM, et al. Acta Crystallogr C Struct Chem. 2019 Jun 1;75(Pt 6):650-656. doi: 10.1107/S2053229619005746. Epub 2019 May 15. Acta Crystallogr C Struct Chem. 2019. PMID: 31166916
Reaction of 2-allyl-N-benzyl-4-fluoroaniline or 2-allyl-N-benzyl-4-chloroaniline with 98% sulfuric acid leads to the concurrent formation of halogeno-substituted 11-ethyl-6,11-dihydrodibenzo[b,e]azepines, (II), and halogeno-substituted 11-methyl-5,6,11 …
Reaction of 2-allyl-N-benzyl-4-fluoroaniline or 2-allyl-N-benzyl-4-chloroaniline with 98% sulfuric acid leads to …