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Potent immunosuppressants, 2-alkyl-2-aminopropane-1,3-diols.
Fujita T, Hirose R, Yoneta M, Sasaki S, Inoue K, Kiuchi M, Hirase S, Chiba K, Sakamoto H, Arita M. Fujita T, et al. J Med Chem. 1996 Oct 25;39(22):4451-9. doi: 10.1021/jm960391l. J Med Chem. 1996. PMID: 8893839
Asymmetric synthesis of trisubstituted oxazolidinones by the thiourea-catalyzed aldol reaction of 2-isocyanatomalonate diester.
Sakamoto S, Kazumi N, Kobayashi Y, Tsukano C, Takemoto Y. Sakamoto S, et al. Org Lett. 2014 Sep 19;16(18):4758-61. doi: 10.1021/ol502198e. Epub 2014 Sep 9. Org Lett. 2014. PMID: 25203516
With this in mind, this procedure was successfully applied to the first total synthesis of mycestericin C, which was completed in 12 steps and represents one of the shortest reported sequences for the construction of natural products of this type....
With this in mind, this procedure was successfully applied to the first total synthesis of mycestericin C, which was completed …
Fungal metabolites. Part 14. Novel potent immunosuppressants, mycestericins, produced by Mycelia sterilia.
Sasaki S, Hashimoto R, Kiuchi M, Inoue K, Ikumoto T, Hirose R, Chiba K, Hoshino Y, Okumoto T, Fujita T. Sasaki S, et al. J Antibiot (Tokyo). 1994 Apr;47(4):420-33. doi: 10.7164/antibiotics.47.420. J Antibiot (Tokyo). 1994. PMID: 8195042 Free article.
Their structures were elucidated on the basis of spectroscopic studies and chemical evidence. The acetate of mycestericin C was identical with the acetate of 6,7-dihydromyriocin. ...
Their structures were elucidated on the basis of spectroscopic studies and chemical evidence. The acetate of mycestericin C wa …