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Year Number of Results
1964 1
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1971 2
1972 1
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1974 3
1975 1
1976 4
1978 1
1979 1
1981 1
1982 2
1983 3
1984 1
1985 3
1986 2
1987 1
1988 2
1989 3
1990 1
1991 1
1992 5
1993 2
1994 4
1995 2
1996 3
1997 3
1998 1
1999 3
2000 3
2001 5
2002 3
2003 6
2004 10
2005 7
2006 4
2007 11
2008 14
2009 9
2010 14
2011 15
2012 19
2013 26
2014 21
2015 21
2016 22
2017 32
2018 31
2019 34
2020 40
2021 45
2022 41
2023 52
2024 8

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505 results

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Page 1
Intracation and Interanion-Cation Charge-Transfer Properties of Tetrathiafulvalene-Bismuth-Halide Hybrids.
Zhang X, Zhang P, Weng YG, Tang ZZ, Zhu QY, Dai J. Zhang X, et al. Inorg Chem. 2018 Sep 4;57(17):11113-11122. doi: 10.1021/acs.inorgchem.8b01692. Epub 2018 Aug 14. Inorg Chem. 2018. PMID: 30106568
Tetrathiafulvalene (TTF) derivatives as promising hole transport materials in assembling hybrid halide perovskite solar cells have attracted great attention; however, electron transfer or charge-transfer (CT) between TTF and metal halides has been studied with less detail at the …
Tetrathiafulvalene (TTF) derivatives as promising hole transport materials in assembling hybrid halide perovskite solar cells have attracted …
Bismuth-Catalyzed Amide Reduction.
Yang X, Kuziola J, Béland VA, Busch J, Leutzsch M, Burés J, Cornella J. Yang X, et al. Angew Chem Int Ed Engl. 2023 Aug 7;62(32):e202306447. doi: 10.1002/anie.202306447. Epub 2023 Jun 28. Angew Chem Int Ed Engl. 2023. PMID: 37283567
In this article we report that a cationic version of Akiba's Bi(III) complex catalyzes the reduction of amides to amines using silane as hydride donor. ...
In this article we report that a cationic version of Akiba's Bi(III) complex catalyzes the reduction of amides to amines using silane …
Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations.
Wang X, Lei B, Zhang Z, Chen M, Rong H, Song H, Zhao L, Mo Z. Wang X, et al. Nat Commun. 2023 May 23;14(1):2968. doi: 10.1038/s41467-023-38606-2. Nat Commun. 2023. PMID: 37221189 Free PMC article.
Herein, we describe the synthesis of a family of antimony(I) and bismuth(I) cations supported by a bis(silylene) ligand [(TBDSi(2))Pn][BAr(F)(4)] (TBD = 1, 8, 10, 9-triazaboradecalin; Ar(F) = 3,5-CF(3)-C(6)H(3); Pn = Sb, (2); Bi, (3)). ...The reactions of 2 and 3 wi …
Herein, we describe the synthesis of a family of antimony(I) and bismuth(I) cations supported by a bis(silylene) ligand [(TBDS …
Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes.
García-Romero Á, Martín-Álvarez JM, Miguel D, Wright DS, Álvarez CM, García-Rodríguez R. García-Romero Á, et al. Inorg Chem. 2021 Dec 20;60(24):19206-19218. doi: 10.1021/acs.inorgchem.1c03004. Epub 2021 Dec 9. Inorg Chem. 2021. PMID: 34882394 Free PMC article.
The use of antimony and bismuth in supramolecular chemistry has been largely overlooked in comparison to the lighter elements of Group 15, and the coordination chemistry of the tripodal ligands [Sb(3-py)(3)] and [Bi(3-py)(3)] (L) containing the heaviest p-block element bri …
The use of antimony and bismuth in supramolecular chemistry has been largely overlooked in comparison to the lighter elements of Grou …
Halide Double Perovskite Ferroelectrics.
Zhang W, Hong M, Luo J. Zhang W, et al. Angew Chem Int Ed Engl. 2020 Jun 8;59(24):9305-9308. doi: 10.1002/anie.201916254. Epub 2020 Apr 1. Angew Chem Int Ed Engl. 2020. PMID: 32168414
However, to date, no ferroelectric material based on halide double perovskites has been discovered. Herein, by hetero-substitution of lead and cation intercalation of n-propylamine, the first halide double perovskite ferroelectric, (n-propylammonium)(2) CsAgBiBr(7) (1), is …
However, to date, no ferroelectric material based on halide double perovskites has been discovered. Herein, by hetero-substitution of lead a …
Organic Spacer Cation Assisted Modulation of the Structure and Properties of Bismuth Halide Perovskites.
Pious JK, Muthu C, Vijayakumar C. Pious JK, et al. Acc Chem Res. 2022 Feb 1;55(3):275-285. doi: 10.1021/acs.accounts.1c00545. Epub 2021 Nov 22. Acc Chem Res. 2022. PMID: 34806368
These issues initiated an effort towards the development of environmentally friendly, lead-free perovskites. In this context, bismuth halide perovskites (BHPs) were ideal rivals for lead-based congeners due to their excellent chemical stability, lower toxicity, and structu …
These issues initiated an effort towards the development of environmentally friendly, lead-free perovskites. In this context, bismuth …
Barium- and Bismuth-loaded Clinoptilolite Micro- and Nano-Particles as Proposed New Efficient Contrast Agents.
Hosseini A, Ebadollahi-Natanzi A, Foroughi M, Shetab-Boushehri SV. Hosseini A, et al. Comb Chem High Throughput Screen. 2020;23(3):191-195. doi: 10.2174/1386207323666200218113537. Comb Chem High Throughput Screen. 2020. PMID: 32067613
Clinoptilolite particles have a high surface area, negative surface charge, cation adsorption and exchange capacities. Barium sulfate (BaSO4) and bismuth subnitrate (Bi5H9N4O22) suspensions have been used for upper and lower gastrointestinal imaging but Ba2+ and Bi3 …
Clinoptilolite particles have a high surface area, negative surface charge, cation adsorption and exchange capacities. Barium sulfate …
Bismuth in Dynamic Covalent Chemistry: Access to a Bowl-Type Macrocycle and a Barrel-Type Heptanuclear Complex Cation.
Stoy A, Jürgensen M, Millidoni C, Berthold C, Ramler J, Martínez S, Buchner MR, Lichtenberg C. Stoy A, et al. Angew Chem Int Ed Engl. 2023 Oct 9;62(41):e202308293. doi: 10.1002/anie.202308293. Epub 2023 Sep 1. Angew Chem Int Ed Engl. 2023. PMID: 37522394
To date, these fundamentally important synthetic and conceptual challenges in the context of DCvC have predominantly been tackled by exploiting compounds of lighter p-block elements, even though heavier p-block elements show low bond dissociation energies and appear to be ideally …
To date, these fundamentally important synthetic and conceptual challenges in the context of DCvC have predominantly been tackled by exploit …
A Multidimensional Approach to Carbodiphosphorane-Bismuth Coordination Chemistry: Cationization, Redox-Flexibility, and Stabilization of a Crystalline Bismuth Hydridoborate.
Obi AD, Dickie DA, Tiznado W, Frenking G, Pan S, Gilliard RJ Jr. Obi AD, et al. Inorg Chem. 2022 Dec 5;61(48):19452-19462. doi: 10.1021/acs.inorgchem.2c03337. Epub 2022 Nov 22. Inorg Chem. 2022. PMID: 36412917
Bismuth complexes stabilized by carbon-based donor ligands are underserved by their instability, often due to facile ligand dissociation and deleterious protonolysis. Herein, we show that the ortho-bismuthination of hexaphenylcarbodiphosphorane enables a robust framework w …
Bismuth complexes stabilized by carbon-based donor ligands are underserved by their instability, often due to facile ligand dissociat …
Coordination Chemistry of the Antimony(III) and Bismuth(III) Cations using Bis(alpha-iminopyridine) as Ligand.
Haldar H, Yildiz CB, Majumdar M. Haldar H, et al. Chempluschem. 2023 Jul;88(7):e202300211. doi: 10.1002/cplu.202300211. Chempluschem. 2023. PMID: 37394682
Bis(alpha-iminopyridine) L has been employed as the redox non-innocent Schiff-base ligand to coordinate with cationic antimony(III) and bismuth(III) centers. Mono- and di- cationic compounds: [LSbCl(2) ][CF(3) SO(3) ] 1, [LBiCl(2) ][CF(3) SO(3) ] 2, [LSbCl(2) …
Bis(alpha-iminopyridine) L has been employed as the redox non-innocent Schiff-base ligand to coordinate with cationic antimony(III) a …
505 results