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Synlett. 2015 Jul 1;26(11):1533-1536. Epub 2015 Feb 27.

Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes.

Author information

1
Department of Chemistry, Yale University, New Haven, CT 06520, USA.
2
Lawrence Berkeley National Laboratory and Department of Chemistry, University of California, Berkeley, CA, USA.

Abstract

A new and unexpected Rh(I)-catalyzed cycloisomerization of 1,6-enynes is reported. Several different alkyne substitution patterns were evaluated under the reaction conditions, including a deuterated derivative that provides some insight into the reaction mechanism.

KEYWORDS:

enones; homogeneous catalysis; isomerization; rhodium; ring closure

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