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J Am Chem Soc. 2014 May 14;136(19):6884-7. doi: 10.1021/ja502885c. Epub 2014 Apr 30.

A method for the selective hydrogenation of alkenyl halides to alkyl halides.

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1
Department of Chemistry, Yale University , New Haven, Connecticut 06520, United States.

Abstract

A general method for the selective hydrogenation of alkenyl halides to alkyl halides is described. Fluoro, chloro, bromo, iodo, and gem-dihaloalkenes are viable substrates for the transformation. The selectivity of the hydrogenation is consistent with reduction by a hydrogen atom transfer pathway.

PMID:
24824195
DOI:
10.1021/ja502885c

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