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Items: 1 to 20 of 100

1.

Biocatalytic Carbon-Hydrogen and Carbon-Fluorine Bond Cleavage through Hydroxylation Promoted by a Histidyl-Ligated Heme Enzyme.

Wang Y, Davis I, Shin I, Wherritt DJ, Griffith WP, Dornevil K, Colabroy KL, Liu A.

ACS Catal. 2019 Jun 7;9(6):4764-4776. doi: 10.1021/acscatal.9b00231. Epub 2019 Apr 11.

2.

A heme peroxidase with a functional role as an L-tyrosine hydroxylase in the biosynthesis of anthramycin.

Connor KL, Colabroy KL, Gerratana B.

Biochemistry. 2011 Oct 18;50(41):8926-36. doi: 10.1021/bi201148a. Epub 2011 Sep 23.

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Bioinspired Nonheme Iron Catalysts for C-H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants.

Oloo WN, Que L Jr.

Acc Chem Res. 2015 Sep 15;48(9):2612-21. doi: 10.1021/acs.accounts.5b00053. Epub 2015 Aug 17.

PMID:
26280131
5.

C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales.

Clot E, Eisenstein O, Jasim N, Macgregor SA, McGrady JE, Perutz RN.

Acc Chem Res. 2011 May 17;44(5):333-48. doi: 10.1021/ar100136x. Epub 2011 Mar 16.

PMID:
21410234
6.

Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphere.

Faponle AS, Quesne MG, Sastri CV, Banse F, de Visser SP.

Chemistry. 2015 Jan 12;21(3):1221-36. doi: 10.1002/chem.201404918. Epub 2014 Nov 14.

7.

Manganese Catalyzed C-H Halogenation.

Liu W, Groves JT.

Acc Chem Res. 2015 Jun 16;48(6):1727-35. doi: 10.1021/acs.accounts.5b00062. Epub 2015 Jun 4.

PMID:
26042637
8.

Lincomycin biosynthesis involves a tyrosine hydroxylating heme protein of an unusual enzyme family.

Novotna J, Olsovska J, Novak P, Mojzes P, Chaloupkova R, Kamenik Z, Spizek J, Kutejova E, Mareckova M, Tichy P, Damborsky J, Janata J.

PLoS One. 2013 Dec 4;8(12):e79974. doi: 10.1371/journal.pone.0079974. eCollection 2013.

11.

Heme oxygenase reveals its strategy for catalyzing three successive oxygenation reactions.

Matsui T, Unno M, Ikeda-Saito M.

Acc Chem Res. 2010 Feb 16;43(2):240-7. doi: 10.1021/ar9001685.

PMID:
19827796
12.

The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.

Prat I, Company A, Postils V, Ribas X, Que L Jr, Luis JM, Costas M.

Chemistry. 2013 May 17;19(21):6724-38. doi: 10.1002/chem.201300110. Epub 2013 Mar 27.

PMID:
23536410
13.

A proton-shuttle mechanism mediated by the porphyrin in benzene hydroxylation by cytochrome p450 enzymes.

de Visser SP, Shaik S.

J Am Chem Soc. 2003 Jun 18;125(24):7413-24.

PMID:
12797816
14.

Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center. Evidence for an Fe(IV)=O oxidant.

Jensen MP, Lange SJ, Mehn MP, Que EL, Que L Jr.

J Am Chem Soc. 2003 Feb 26;125(8):2113-28.

PMID:
12590539
15.

Aromatic hydroxylation at a non-heme iron center: observed intermediates and insights into the nature of the active species.

Makhlynets OV, Rybak-Akimova EV.

Chemistry. 2010 Dec 17;16(47):13995-4006. doi: 10.1002/chem.201002577.

PMID:
21117047
16.

ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?

Ansari A, Rajaraman G.

Phys Chem Chem Phys. 2014 Jul 28;16(28):14601-13. doi: 10.1039/c3cp55430a.

PMID:
24812659
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19.

Olefin cis-Dihydroxylation and Aliphatic C-H Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant.

Chatterjee S, Paine TK.

Angew Chem Int Ed Engl. 2015 Aug 3;54(32):9338-42. doi: 10.1002/anie.201502229. Epub 2015 Jun 18.

PMID:
26088714
20.

Tuning the regio- and stereoselectivity of C-H activation in n-octanes by cytochrome P450 BM-3 with fluorine substituents: evidence for interactions between a C-F bond and aromatic π systems.

Wu LL, Yang CL, Lo FC, Chiang CH, Chang CW, Ng KY, Chou HH, Hung HY, Chan SI, Yu SS.

Chemistry. 2011 Apr 18;17(17):4774-87. doi: 10.1002/chem.201003631. Epub 2011 Mar 11.

PMID:
21400620

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