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Items: 1 to 20 of 107

1.

Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex.

Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S.

J Am Chem Soc. 2013 Mar 13;135(10):4018-26. doi: 10.1021/ja312256u. Epub 2013 Feb 26.

2.

Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid.

Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S.

J Am Chem Soc. 2013 Feb 20;135(7):2825-34. doi: 10.1021/ja312523u. Epub 2013 Feb 8.

3.

Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes.

Fukuzumi S, Tahsini L, Lee YM, Ohkubo K, Nam W, Karlin KD.

J Am Chem Soc. 2012 Apr 25;134(16):7025-35. doi: 10.1021/ja211656g. Epub 2012 Apr 12.

4.

Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.

Tahsini L, Kotani H, Lee YM, Cho J, Nam W, Karlin KD, Fukuzumi S.

Chemistry. 2012 Jan 23;18(4):1084-93. doi: 10.1002/chem.201103215. Epub 2012 Jan 3.

5.

Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.

Kakuda S, Peterson RL, Ohkubo K, Karlin KD, Fukuzumi S.

J Am Chem Soc. 2013 May 1;135(17):6513-22. doi: 10.1021/ja3125977. Epub 2013 Apr 16.

6.

Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate.

Kakuda S, Rolle CJ, Ohkubo K, Siegler MA, Karlin KD, Fukuzumi S.

J Am Chem Soc. 2015 Mar 11;137(9):3330-7. doi: 10.1021/ja512584r. Epub 2015 Feb 26.

8.

Mononuclear copper complex-catalyzed four-electron reduction of oxygen.

Fukuzumi S, Kotani H, Lucas HR, Doi K, Suenobu T, Peterson RL, Karlin KD.

J Am Chem Soc. 2010 May 26;132(20):6874-5. doi: 10.1021/ja100538x.

9.

Proton-coupled electron-transfer reduction of dioxygen catalyzed by a saddle-distorted cobalt phthalocyanine.

Honda T, Kojima T, Fukuzumi S.

J Am Chem Soc. 2012 Mar 7;134(9):4196-206. doi: 10.1021/ja209978q. Epub 2012 Feb 21.

PMID:
22299646
10.
11.

Redox properties of a mononuclear copper(II)-superoxide complex.

Tano T, Okubo Y, Kunishita A, Kubo M, Sugimoto H, Fujieda N, Ogura T, Itoh S.

Inorg Chem. 2013 Sep 16;52(18):10431-7. doi: 10.1021/ic401261z. Epub 2013 Sep 5.

PMID:
24004030
12.

Efficient two-electron reduction of dioxygen to hydrogen peroxide with one-electron reductants with a small overpotential catalyzed by a cobalt chlorin complex.

Mase K, Ohkubo K, Fukuzumi S.

J Am Chem Soc. 2013 Feb 20;135(7):2800-8. doi: 10.1021/ja312199h. Epub 2013 Feb 6.

PMID:
23343346
13.

Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands.

Schatz M, Becker M, Thaler F, Hampel F, Schindler S, Jacobson RR, Tyeklár Z, Murthy NN, Ghosh P, Chen Q, Zubieta J, Karlin KD.

Inorg Chem. 2001 May 7;40(10):2312-22.

PMID:
11327908
14.
15.

Dioxygen activation of a trinuclear Cu(I)Cu(I)Cu(I) cluster capable of mediating facile oxidation of organic substrates: competition between O-atom transfer and abortive intercomplex reduction.

Maji S, Lee JC, Lu YJ, Chen CL, Hung MC, Chen PP, Yu SS, Chan SI.

Chemistry. 2012 Mar 26;18(13):3955-68. doi: 10.1002/chem.201103075. Epub 2012 Feb 22.

PMID:
22354807
16.

Brønsted acid-promoted C-H bond cleavage via electron transfer from toluene derivatives to a protonated nonheme iron(IV)-oxo complex with no kinetic isotope effect.

Park J, Lee YM, Nam W, Fukuzumi S.

J Am Chem Soc. 2013 Apr 3;135(13):5052-61. doi: 10.1021/ja311662w. Epub 2013 Mar 25.

PMID:
23528016
17.

Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals.

Sprakel VS, Feiters MC, Meyer-Klaucke W, Klopstra M, Brinksma J, Feringa BL, Karlin KD, Nolte RJ.

Dalton Trans. 2005 Nov 7;(21):3522-34. Epub 2005 Sep 23.

PMID:
16234934
18.

[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis?

Gagnon N, Tolman WB.

Acc Chem Res. 2015 Jul 21;48(7):2126-31. doi: 10.1021/acs.accounts.5b00169. Epub 2015 Jun 15. Review.

19.
20.

Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects.

Hatcher LQ, Vance MA, Narducci Sarjeant AA, Solomon EI, Karlin KD.

Inorg Chem. 2006 Apr 3;45(7):3004-13.

PMID:
16562956

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