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Items: 1 to 20 of 104

1.

Parallel and competitive pathways for substrate desaturation, hydroxylation, and radical rearrangement by the non-heme diiron hydroxylase AlkB.

Cooper HL, Mishra G, Huang X, Pender-Cudlip M, Austin RN, Shanklin J, Groves JT.

J Am Chem Soc. 2012 Dec 19;134(50):20365-75. doi: 10.1021/ja3059149. Epub 2012 Dec 10.

3.

Reaction mechanisms of non-heme diiron hydroxylases characterized in whole cells.

Bertrand E, Sakai R, Rozhkova-Novosad E, Moe L, Fox BG, Groves JT, Austin RN.

J Inorg Biochem. 2005 Oct;99(10):1998-2006.

PMID:
16084596
4.

Intermediate Q from soluble methane monooxygenase hydroxylates the mechanistic substrate probe norcarane: evidence for a stepwise reaction.

Brazeau BJ, Austin RN, Tarr C, Groves JT, Lipscomb JD.

J Am Chem Soc. 2001 Dec 5;123(48):11831-7.

PMID:
11724588
5.

A non-heme iron protein with heme tendencies: an investigation of the substrate specificity of thymine hydroxylase.

Thornburg LD, Lai MT, Wishnok JS, Stubbe J.

Biochemistry. 1993 Dec 21;32(50):14023-33.

PMID:
8268181
6.

Desaturase reactions complicate the use of norcarane as a mechanistic probe. Unraveling the mixture of twenty-plus products formed in enzyme-catalyzed oxidations of norcarane.

Newcomb M, Chandrasena RE, Lansakara-P DS, Kim HY, Lippard SJ, Beauvais LG, Murray LJ, Izzo V, Hollenberg PF, Coon MJ.

J Org Chem. 2007 Feb 16;72(4):1121-7.

7.

Products from enzyme-catalyzed oxidations of norcarenes.

Newcomb M, Lansakara-P DS, Kim HY, Chandrasena RE, Lippard SJ, Beauvais LG, Murray LJ, Izzo V, Hollenberg PF, Coon MJ.

J Org Chem. 2007 Feb 16;72(4):1128-33.

9.

Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways.

Hull JF, Balcells D, Sauer EL, Raynaud C, Brudvig GW, Crabtree RH, Eisenstein O.

J Am Chem Soc. 2010 Jun 9;132(22):7605-16. doi: 10.1021/ja908744w.

10.
11.

Structural and mechanistic studies on anthocyanidin synthase catalysed oxidation of flavanone substrates: the effect of C-2 stereochemistry on product selectivity and mechanism.

Welford RW, Clifton IJ, Turnbull JJ, Wilson SC, Schofield CJ.

Org Biomol Chem. 2005 Sep 7;3(17):3117-26. Epub 2005 Aug 1.

PMID:
16106293
12.

Dioxygen activation at non-heme diiron centers: oxidation of a proximal residue in the I100W variant of toluene/o-xylene monooxygenase hydroxylase.

Murray LJ, García-Serres R, McCormick MS, Davydov R, Naik SG, Kim SH, Hoffman BM, Huynh BH, Lippard SJ.

Biochemistry. 2007 Dec 25;46(51):14795-809. Epub 2007 Nov 29.

14.

Evaluation of norcarane as a probe for radicals in cytochome p450- and soluble methane monooxygenase-catalyzed hydroxylation reactions.

Newcomb M, Shen R, Lu Y, Coon MJ, Hollenberg PF, Kopp DA, Lippard SJ.

J Am Chem Soc. 2002 Jun 19;124(24):6879-86. Erratum in: J Am Chem Soc. 2006 Feb 1;128(4):1394.

PMID:
12059209
15.

Non-heme Fe(IV)-oxo intermediates.

Krebs C, Galonić Fujimori D, Walsh CT, Bollinger JM Jr.

Acc Chem Res. 2007 Jul;40(7):484-92. Epub 2007 Jun 2. Review.

16.
17.

Desaturation reactions catalyzed by soluble methane monooxygenase.

Jin Y, Lipscomb JD.

J Biol Inorg Chem. 2001 Sep;6(7):717-25.

PMID:
11681705
18.

Human mitochondrial cytochrome P450 27C1 is localized in skin and preferentially desaturates trans-retinol to 3,4-dehydroretinol.

Johnson KM, Phan TTN, Albertolle ME, Guengerich FP.

J Biol Chem. 2017 Aug 18;292(33):13672-13687. doi: 10.1074/jbc.M116.773937. Epub 2017 Jul 12.

PMID:
28701464
19.

A proton-shuttle mechanism mediated by the porphyrin in benzene hydroxylation by cytochrome p450 enzymes.

de Visser SP, Shaik S.

J Am Chem Soc. 2003 Jun 18;125(24):7413-24.

PMID:
12797816
20.

Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.

Huang X, Groves JT.

J Biol Inorg Chem. 2017 Apr;22(2-3):185-207. doi: 10.1007/s00775-016-1414-3. Epub 2016 Dec 1. Review.

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