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Items: 1 to 20 of 102

1.

MgCl2·4((CH3)2CHCH2OH): a new molecular adduct for the preparation of TiCl(x)/MgCl2 catalyst for olefin polymerization.

Thushara KS, Gnanakumar ES, Mathew R, Ajithkumar TG, Rajamohanan PR, Bhaduri S, Gopinath CS.

Dalton Trans. 2012 Oct 7;41(37):11311-8. doi: 10.1039/c2dt31211e. Epub 2012 Aug 10.

PMID:
22886043
2.

MgCl(2).6PhCH2OH--a new molecular adduct as support material for Ziegler-Natta catalyst: synthesis, characterization and catalytic activity.

Gnanakumar ES, Thushara KS, Bhange DS, Mathew R, Ajithkumar TG, Rajamohanan PR, Bhaduri S, Gopinath CS.

Dalton Trans. 2011 Nov 7;40(41):10936-44. doi: 10.1039/c1dt10786k. Epub 2011 Sep 12.

PMID:
21909567
3.

9-fluorenemethanol: an internal electron donor to fine tune olefin polymerization activity.

Gnanakumar ES, Rao Chokkapu E, Kunjir S, Ajithkumar TG, Rajamohanan PR, Chakraborty D, Gopinath CS.

Dalton Trans. 2014 Jun 28;43(24):9143-51. doi: 10.1039/c4dt00793j.

PMID:
24810354
4.

Solid-State NMR investigations of a MgCl2·4(CH3)2CHCH2OH molecular adduct: a peculiar case of reversible equilibrium between two phases.

Thushara KS, Ajithkumar TG, Rajamohanan PR, Gopinath CS.

J Phys Chem A. 2014 Feb 20;118(7):1213-9. doi: 10.1021/jp412331s. Epub 2014 Feb 7.

PMID:
24476423
5.

Effect of EtOH/MgCl(2) molar ratios on the catalytic properties of MgCl(2)-SiO(2)/TiCl(4) Ziegler-Natta catalyst for ethylene polymerization.

Patthamasang S, Jongsomjit B, Praserthdam P.

Molecules. 2011 Sep 29;16(10):8332-42. doi: 10.3390/molecules16108332.

6.

Propylene Polymerization Performance of Isolated and Aggregated Ti Species Studied Using a Well-Designed TiCl(3) /MgCl(2) Ziegler-Natta Model Catalyst.

Wada T, Taniike T, Kouzai I, Takahashi S, Terano M.

Macromol Rapid Commun. 2009 Jun 2;30(11):887-91. doi: 10.1002/marc.200900015. Epub 2009 Mar 17.

PMID:
21706543
7.

Study on the distribution of active centers in novel low Ti-loading MgCl2-supported Ziegler-Natta catalyst.

Wang JF, Wang L, Zhao ZR, Wang WQ, Chen T.

J Zhejiang Univ Sci. 2004 Aug;5(8):912-7.

PMID:
15236474
8.

Spectroscopic investigation of heterogeneous Ziegler-Natta catalysts: Ti and Mg chloride tetrahydrofuranates, their interaction compound, and the role of the activator.

Seenivasan K, Sommazzi A, Bonino F, Bordiga S, Groppo E.

Chemistry. 2011 Jul 25;17(31):8648-56. doi: 10.1002/chem.201100804. Epub 2011 Jun 16.

PMID:
21681840
9.

Quadrupolar nutation NMR to discriminate central and satellite transitions: Spectral assignments for a Ziegler-Natta catalyst.

Blaakmeer ESM, Franssen WMJ, Kentgens APM.

J Magn Reson. 2017 Aug;281:199-208. doi: 10.1016/j.jmr.2017.06.002. Epub 2017 Jun 7.

10.

In situ ATR-FTIR studies on MgCl2-diisobutyl phthalate interactions in thin film Ziegler-Natta catalysts.

Cheruvathur AV, Langner EH, Niemantsverdriet JW, Thüne PC.

Langmuir. 2012 Feb 7;28(5):2643-51. doi: 10.1021/la203972k. Epub 2012 Jan 23.

PMID:
22216939
11.

Mechanism of activation of a hafnium pyridyl-amide olefin polymerization catalyst: ligand modification by monomer.

Froese RD, Hustad PD, Kuhlman RL, Wenzel TT.

J Am Chem Soc. 2007 Jun 27;129(25):7831-40. Epub 2007 Jun 2.

PMID:
17542583
12.

Development and application of FI catalysts for olefin polymerization: unique catalysis and distinctive polymer formation.

Makio H, Fujita T.

Acc Chem Res. 2009 Oct 20;42(10):1532-44. doi: 10.1021/ar900030a.

PMID:
19588950
13.

Preparation and morphology of polyethylene/clay nanocomposite with novel MgCl2/montmorillonite (MMT) bi-supported Ziegler-Natta catalyst.

Cai HG, Zhang CY, Chen B, Zhang XQ, Zhang HX.

J Nanosci Nanotechnol. 2012 Sep;12(9):7296-300.

PMID:
23035467
14.

Surface and bulk aspects of mixed oxide catalytic nanoparticles: oxidation and dehydration of CH(3)OH by polyoxometallates.

Nakka L, Molinari JE, Wachs IE.

J Am Chem Soc. 2009 Oct 28;131(42):15544-54. doi: 10.1021/ja904957d.

PMID:
19807071
15.

Iridium Ziegler-type hydrogenation catalysts made from [(1,5-COD)Ir(mu-O2C8H15)](2) and AlEt3: spectroscopic and kinetic evidence for the Ir(n) species present and for nanoparticles as the fastest catalyst.

Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Ozkar S, Johnson KA, Finke RG.

Inorg Chem. 2010 Sep 6;49(17):8131-47. doi: 10.1021/ic101237c.

PMID:
20681520
16.

Crystal structures of Ziegler-Natta catalyst supports.

Malizia F, Fait A, Cruciani G.

Chemistry. 2011 Dec 2;17(49):13892-7. doi: 10.1002/chem.201101900. Epub 2011 Nov 3.

PMID:
22052708
17.

Probing the coordinative unsaturation and local environment of Ti³⁺ sites in an activated high-yield Ziegler-Natta catalyst.

Morra E, Giamello E, Van Doorslaer S, Antinucci G, D'Amore M, Busico V, Chiesa M.

Angew Chem Int Ed Engl. 2015 Apr 13;54(16):4857-60. doi: 10.1002/anie.201412052. Epub 2015 Feb 23.

18.

Surface science of single-site heterogeneous olefin polymerization catalysts.

Kim SH, Somorjai GA.

Proc Natl Acad Sci U S A. 2006 Oct 17;103(42):15289-94. Epub 2006 Oct 10.

19.

Investigation of the Ti/MgCl2 interface on a Si(111) 7 × 7 substrate.

Karakalos S, Skala T, Plekan O, Ladas S, Prince K, Matolin V, Chab V, Siokou A.

J Chem Phys. 2012 Jun 14;136(22):224703. doi: 10.1063/1.4727760.

PMID:
22713065
20.

MgCl2/R'nAl(OR)3-n: an excellent activator/support for transition-metal complexes for olefin polymerization.

Nakayama Y, Saito J, Bando H, Fujita T.

Chemistry. 2006 Oct 10;12(29):7546-56.

PMID:
16900544

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