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19397274,21130763,19634879,17722921,19435321,14753812,20018187,25369169,21930709,23578101,18041829,28919500,25025613,19480942,18500479,26091969,22443530,15548012,21618994,18826265,28647463,25613229,18783833,21204519,15643882,16108354,25579778,27232385,15998021,18307282,19805068,22860512,18461194,20340124,22612846,28884175,21443182,15382935,28075576,19639134,18653896,33147959,15667268,30106575,29792026,19507910,18597449,19438209,18354800,19166853,20221539,22591027,22084023,17304591,28295776,18540595,19809728,19860458,23145835,16060601,17698202,17845059,16323019,19378958,32420744,12691553,19722671,19317477,17566128,27776209,21682274,17705475,19824734,20726841,32661785,27973768,20302340,16323916,21152555,12974636,20536241,16051223,21167156,20041643,10413472,23446996,19860376,14674777,16608357,17715982,19630410,20873759,17546685,21524099,19888734,20119989,17676838,18439002,20845347,19480944,21271703,23307026,25605932,21643991,10529166,21942468,25286239,19601586,20077533,20418861,15062773,17602468,20547420,21983599,17321121,17660315,19162018,17497786,16513746,21704584,21365080,25316302,19664823,17712440,22563793,19580299,22891965,25871921,17927160,18801156,17610956,11935356,29987246,12823545,34043346,34668697,22911248,15703741,17256930,28348243,35041427,20837009,16323020,29251926,16981725,16060624,20221540,21793493,19320470,19947649,11456963,24878200,22177948,21953555,27432985,16386249,30545220,24757087,18262276,15667277,20883039,19904421,11846805,16287273,15382953,23507618,20596574,26073322,19303144,18324814,12517165,12515509,12001165,20593098,30632592,17957282,28910086,22985598,18710214,18665586,16571021,20830399,16234917,33326230,19737003,20544787,16137685,23873755,18461189,15612726,15378625,20565074,19009086,18506239,16297868,19759926,18205358,26230977,11862539,16391746,19350595,17295467,17216401,30802044,22107366,17606299,18398538,18563582,11400057,15479062,24001095,20665653,23560849,17941631,22223148,18585737,32620553,11896710,12844300,26703931,19209363,22895256,17824672,17256840,19333494,25504963,12132916,23793236,15474481,21058656,23846321,23049878,23249091,22757742,18501709,21539357,19855833,20536125,17198418,18341276,20221544,20953495,17850165,21284939,18646798,19845323,21393052,15968378,17417837,21827941,30001117,16524912,24458644,15654733,12692334,23143609,17275940,17886832,31580662,20131914,15578644,20469832,24651202,26699472,21537507,15023070,17894491,19011912,19173074,27443604,11827551,15157115,33629081,26364994,17372642,17676736,10482784,18633545,32488975,20230002,16841968,26324916,30628136,29177350,16730357,21947059,19662312,23374093,21105038,29334424,24159045,21863186,19662302,24158139,15293248,18620387,19904420,16270973,15667259,15134933,20026074,15581586,12560990,26359661,16028957,31570604,28291336,24328345,20221541,15257585,26010059,26352172,28972933,2173950,22080303,15606156,20878321,9836629,1396719,11925039,18067109,22110126,12870970,31493152,16540118,20225804,17712448,17297518,25633077,25978307,21082840,26362685,25297065,15082711,27344601,22887644,16676950,20521790,29054130,24059526,28635269,29726568,21673792,16730831,18202004,25461840,19053348,30314343,15762706,18188555,15764814,21274947,22218815,15869280,22955116,23788433,22260087,23133586,29632334,23700296,25654171,24846692,28802265,16271886,25436832,29746248,23934246,23597401,16471966,23596151,21547984,12296727,22407945,27723153,12586941,10858294,15667273,26749450,16599558,21124800,24972661,19694480,10049702,18355437,35729755,28553946,19938018,16999394,17126592,26764535,11096090,17150028,21290530,35736652,23398301,24405487,9874225,24115635,17611542,19007207,27104487,25244613,11538123,21701763,25867218,15893671,16432569,35102895,19088963,29595965,19117946,12642671,17924153,15757669,24127299,11713686,25624102,31820961,15252784,26393426,27976835,15504408,23109267,15907101,17177431,22314336,21114298,27241847,12605255,12532305,23041346,19146390,19662307,15157116,20557131,17888908,19341307,18700771,17597615,15225075,24564271,26482707,17195059,27071219,15506791,28825810,1649830,31669490,16358786,20108298,29179539,17222178,27754505,12459907,15147187,12637732,18048692,16061234,29577535,26919691,21905140,18723024,32434327,21384925,19101555,21768339,26405810,17845060,12444758,9849942,26587715,24422466,28537598,19621919,20669037,19623593,15667271,10937481,18998627,11741415,23803769,17888007,12203028,25494798,27396836,30413719,20405080,19025569,16076208,19006383,18654711,17463285,31823008,17031433,11582571,21728321,16185064,23318679,23362993,24921710,17469805,20696493,27702473,20922263,28067774,22482905,23015459,14730999,25061635,18928519,19503862,15571403,24028060,18266760,17563784,19003843,22810230,23505629,17318945,8612797,16389612,32796105,17016571,18406335,17579741,16893172,24817512,17660945,34048236,30053346,18072944,22772838,20922264,22786574,24931373,18209804,22539196,21444783,15870373,17315869,20527808,29923293,29888350,12084580,23484958,22389497,17460905,17285558,16953641,31539235,20845342,8513797,18245276,25851509,16287271,36464641,1761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The structure of the active site H-cluster of [FeFe] hydrogenase from the green alga Chlamydomonas reinhardtii studied by X-ray absorption spectroscopy.

Stripp S, Sanganas O, Happe T, Haumann M. Stripp S, et al. Biochemistry. 2009 Jun 9;48(22):5042-9. doi: 10.1021/bi900010b. Biochemistry. 2009. PMID: 19397274

The [FeFe]-hydrogenase maturation protein HydF contains a H-cluster like [4Fe4S]-2Fe site.

Czech I, Stripp S, Sanganas O, Leidel N, Happe T, Haumann M. Czech I, et al. FEBS Lett. 2011 Jan 3;585(1):225-30. doi: 10.1016/j.febslet.2010.11.052. Epub 2010 Dec 3. FEBS Lett. 2011. PMID: 21130763 Free article.

Spectroelectrochemical characterization of the active site of the [FeFe] hydrogenase HydA1 from Chlamydomonas reinhardtii.

Silakov A, Kamp C, Reijerse E, Happe T, Lubitz W. Silakov A, et al. Biochemistry. 2009 Aug 25;48(33):7780-6. doi: 10.1021/bi9009105. Biochemistry. 2009. PMID: 19634879 Free article.

The electronic structure of the H-cluster in the [FeFe]-hydrogenase from Desulfovibrio desulfuricans: a Q-band 57Fe-ENDOR and HYSCORE study.

Silakov A, Reijerse EJ, Albracht SP, Hatchikian EC, Lubitz W. Silakov A, et al. J Am Chem Soc. 2007 Sep 19;129(37):11447-58. doi: 10.1021/ja072592s. Epub 2007 Aug 28. J Am Chem Soc. 2007. PMID: 17722921

Activation of HydA(DeltaEFG) requires a preformed [4Fe-4S] cluster.

Mulder DW, Ortillo DO, Gardenghi DJ, Naumov AV, Ruebush SS, Szilagyi RK, Huynh B, Broderick JB, Peters JW. Mulder DW, et al. Biochemistry. 2009 Jul 7;48(26):6240-8. doi: 10.1021/bi9000563. Biochemistry. 2009. PMID: 19435321

Enzymatic mechanism of Fe-only hydrogenase: density functional study on H-H making/breaking at the diiron cluster with concerted proton and electron transfers.

Zhou T, Mo Y, Liu A, Zhou Z, Tsai KR. Zhou T, et al. Inorg Chem. 2004 Feb 9;43(3):923-30. doi: 10.1021/ic0342301. Inorg Chem. 2004. PMID: 14753812

The [FeFe]-hydrogenase maturase HydF from Clostridium acetobutylicum contains a CO and CN- ligated iron cofactor.

Czech I, Silakov A, Lubitz W, Happe T. Czech I, et al. FEBS Lett. 2010 Feb 5;584(3):638-42. doi: 10.1016/j.febslet.2009.12.016. Epub 2009 Dec 14. FEBS Lett. 2010. PMID: 20018187 Free article.

Hydride binding to the active site of [FeFe]-hydrogenase.

Chernev P, Lambertz C, Brünje A, Leidel N, Sigfridsson KG, Kositzki R, Hsieh CH, Yao S, Schiwon R, Driess M, Limberg C, Happe T, Haumann M. Chernev P, et al. Inorg Chem. 2014 Nov 17;53(22):12164-77. doi: 10.1021/ic502047q. Epub 2014 Nov 4. Inorg Chem. 2014. PMID: 25369169

O2 reactions at the six-iron active site (H-cluster) in [FeFe]-hydrogenase.

Lambertz C, Leidel N, Havelius KG, Noth J, Chernev P, Winkler M, Happe T, Haumann M. Lambertz C, et al. J Biol Chem. 2011 Nov 25;286(47):40614-23. doi: 10.1074/jbc.M111.283648. Epub 2011 Sep 19. J Biol Chem. 2011. PMID: 21930709 Free PMC article.

EPR and FTIR analysis of the mechanism of H2 activation by [FeFe]-hydrogenase HydA1 from Chlamydomonas reinhardtii.

Mulder DW, Ratzloff MW, Shepard EM, Byer AS, Noone SM, Peters JW, Broderick JB, King PW. Mulder DW, et al. J Am Chem Soc. 2013 May 8;135(18):6921-9. doi: 10.1021/ja4000257. Epub 2013 Apr 24. J Am Chem Soc. 2013. PMID: 23578101

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