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Transforming Triplet Vinylnitrene into Triplet Alkylnitrene at Cryogenic Temperatures.
Shields DJ, Sarkar SK, Sriyarathne HDM, Brown JR, Wentrup C, Abe M, Gudmundsdottir AD.
Org Lett. 2019 Sep 20;21(18):7194-7198. doi: 10.1021/acs.orglett.9b01950. Epub 2019 Jul 26.
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Rearrangements of Nitrile Imines: Ring Expansion of Benzonitrile Imines to Cycloheptatetraenes and Ring Closure to 3-Phenyl-3 H-diazirines.
Bégué D, Dargelos A, Wentrup C.
J Org Chem. 2019 Jul 5;84(13):8668-8673. doi: 10.1021/acs.joc.9b01183. Epub 2019 Jun 19.
Fulminating Gold and Silver.
Wentrup C.
Angew Chem Int Ed Engl. 2019 Oct 14;58(42):14800-14808. doi: 10.1002/anie.201906356. Epub 2019 Aug 13. Review.
Symbiont-Mediated Defense against Legionella pneumophila in Amoebae.
König L, Wentrup C, Schulz F, Wascher F, Escola S, Swanson MS, Buchrieser C, Horn M.
MBio. 2019 May 14;10(3). pii: e00333-19. doi: 10.1128/mBio.00333-19.
Spectroscopic Characterization of Nicotinoyl and Isonicotinoyl Nitrenes and the Photointerconversion of 4-Pyridylnitrene with Diazacycloheptatetraene.
Liu Q, Qin Y, Lu Y, Wentrup C, Zeng X.
J Phys Chem A. 2019 May 2;123(17):3793-3801. doi: 10.1021/acs.jpca.9b01680. Epub 2019 Apr 23.
Heteroarylcarbene-Arylnitrene Radical Cation Isomerizations.
Bégué D, Dargelos A, Braybrook C, Wentrup C.
J Phys Chem A. 2019 Mar 14;123(10):2073-2079. doi: 10.1021/acs.jpca.9b00309. Epub 2019 Feb 28.
Phenylnitrene Radical Cation and Its Isomers from Tetrazoles, Nitrile Imines, Indazole, and Benzimidazole.
J Phys Chem A. 2019 Feb 21;123(7):1410-1422. doi: 10.1021/acs.jpca.8b11858. Epub 2019 Feb 11.
Phenylnitrene Radical Cation Rearrangements.
J Phys Chem A. 2018 Nov 1;122(43):8490-8496. doi: 10.1021/acs.jpca.8b08480. Epub 2018 Oct 18.
Triplet States of Tetrazoles, Nitrenes, and Carbenes from Matrix Photolysis of Tetrazoles, and Phenylcyanamide as a Source of Phenylnitrene.
Abe M, Bégué D, Silva HS, Dargelos A, Wentrup C.
J Phys Chem A. 2018 Sep 20;122(37):7276-7283. doi: 10.1021/acs.jpca.8b06960. Epub 2018 Sep 6.
Trimethylsilylnitrene and Its Surprising Rearrangement to N-(Dimethylsilyl)methanimine via Silaziridine and Silaazomethine Ylide.
Wentrup C, Lüerssen H, Silva HS, Dargelos A, Bégué D.
Chemistry. 2018 Sep 25;24(54):14547-14553. doi: 10.1002/chem.201803245. Epub 2018 Aug 31.
Carbenes and Nitrenes: Recent Developments in Fundamental Chemistry.
Angew Chem Int Ed Engl. 2018 Sep 3;57(36):11508-11521. doi: 10.1002/anie.201804863. Epub 2018 Aug 10. Review.
Peatland Acidobacteria with a dissimilatory sulfur metabolism.
Hausmann B, Pelikan C, Herbold CW, Köstlbacher S, Albertsen M, Eichorst SA, Glavina Del Rio T, Huemer M, Nielsen PH, Rattei T, Stingl U, Tringe SG, Trojan D, Wentrup C, Woebken D, Pester M, Loy A.
ISME J. 2018 Jun;12(7):1729-1742. doi: 10.1038/s41396-018-0077-1. Epub 2018 Feb 23.
Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole.
Abe M, Bégué D, Santos-Silva H, Dargelos A, Wentrup C.
Angew Chem Int Ed Engl. 2018 Mar 12;57(12):3212-3216. doi: 10.1002/anie.201712689. Epub 2018 Feb 21.
From dipivaloylketene to tetraoxaadamantanes.
Kollenz G, Wentrup C.
Beilstein J Org Chem. 2018 Jan 2;14:1-10. doi: 10.3762/bjoc.14.1. eCollection 2018. Review.
Acquisition of a Novel Sulfur-Oxidizing Symbiont in the Gutless Marine Worm Inanidrilus exumae.
Bergin C, Wentrup C, Brewig N, Blazejak A, Erséus C, Giere O, Schmid M, De Wit P, Dubilier N.
Appl Environ Microbiol. 2018 Mar 19;84(7). pii: e02267-17. doi: 10.1128/AEM.02267-17. Print 2018 Apr 1.
Imidoylnitrenes R'C(═NR)-N, Nitrile Imines, 1H-Diazirines, and Carbodiimides: Interconversions and Rearrangements, Structures, and Energies at DFT and CASPT2 Levels of Theory.
Bégué D, Santos-Silva H, Dargelos A, Wentrup C.
J Phys Chem A. 2017 Nov 2;121(43):8227-8235. doi: 10.1021/acs.jpca.7b08445. Epub 2017 Oct 19.
Iminocyclohexadienylidenes: Carbenes or Diradicals? The Hetero-Wolff Rearrangement of Benzotriazoles to Cyanocyclopentadienes and 1H-Benzo[b]azirines.
J Phys Chem A. 2017 Aug 17;121(32):5998-6003. doi: 10.1021/acs.jpca.7b05325. Epub 2017 Aug 2.
Flash Vacuum Pyrolysis: Techniques and Reactions.
Angew Chem Int Ed Engl. 2017 Nov 20;56(47):14808-14835. doi: 10.1002/anie.201705118. Epub 2017 Oct 25. Review.
Biphasic Metabolism and Host Interaction of a Chlamydial Symbiont.
König L, Siegl A, Penz T, Haider S, Wentrup C, Polzin J, Mann E, Schmitz-Esser S, Domman D, Horn M.
mSystems. 2017 May 30;2(3). pii: e00202-16. doi: 10.1128/mSystems.00202-16. eCollection 2017 May-Jun.
Flash Vacuum Pyrolysis of Azides, Triazoles, and Tetrazoles.
Chem Rev. 2017 Mar 8;117(5):4562-4623. doi: 10.1021/acs.chemrev.6b00738. Epub 2017 Feb 24.
A Thermally Populated, Perpendicularly Twisted Alkene Triplet Diradical.
Wentrup C, Regimbald-Krnel MJ, Müller D, Comba P.
Angew Chem Int Ed Engl. 2016 Nov 14;55(47):14600-14605. doi: 10.1002/anie.201607415. Epub 2016 Oct 20.
Azulene-Naphthalene-Type Rearrangements in Benz[a]azulene and Cyclohepta[b]indole.
Wentrup C, Becker J.
Chemistry. 2016 Sep 19;22(39):13835-13839. doi: 10.1002/chem.201603389. Epub 2016 Aug 18.
Ring Contraction in Arylcarbenes and Arylnitrenes; Rearrangements of 1- and 3-Isoquinolylcarbenes and 2-Naphthylnitrene to Cyanoindenes.
Wentrup C, Thétaz C, Lüerssen H, Aylward N, Kvaskoff D.
J Org Chem. 2016 Jun 3;81(11):4601-8. doi: 10.1021/acs.joc.6b00442. Epub 2016 May 13.
Rearrangements of 4-Quinolylcarbene, 3-Quinolylcarbene, and 2-Quinolylcarbene to 1-Naphthylnitrene and Cyanoindenes by Falling Solid Flash Vacuum Pyrolysis.
Aylward N, Kvaskoff D, Becker J, Wentrup C.
J Org Chem. 2016 Jun 3;81(11):4609-15. doi: 10.1021/acs.joc.6b00444. Epub 2016 May 13.
Direct Observation of Carbamoylnitrenes.
Li H, Wan H, Wu Z, Li D, Bégué D, Wentrup C, Zeng X.
Chemistry. 2016 Jun 1;22(23):7856-62. doi: 10.1002/chem.201600824. Epub 2016 Apr 23.
Closely coupled evolutionary history of ecto- and endosymbionts from two distantly related animal phyla.
Zimmermann J, Wentrup C, Sadowski M, Blazejak A, Gruber-Vodicka HR, Kleiner M, Ott JA, Cronholm B, De Wit P, Erséus C, Dubilier N.
Mol Ecol. 2016 Jul;25(13):3203-23. doi: 10.1111/mec.13554. Epub 2016 Mar 15.
Triazoloazine-Diazomethylazine Valence Isomerization. [1,2,3]Triazolo[1,5-a]pyridines and 2-Diazomethylpyridines.
Aylward N, Winter HW, Eckhardt U, Wentrup C.
J Org Chem. 2016 Jan 15;81(2):667-72. doi: 10.1021/acs.joc.5b02639. Epub 2015 Dec 24.
Bond-shift isomers: the co-existence of allenic and propargylic phenylnitrile imines.
Nunes CM, Reva I, Fausto R, Bégué D, Wentrup C.
Chem Commun (Camb). 2015 Oct 11;51(79):14712-5. doi: 10.1039/c5cc03518j.
Comment on "The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation".
J Phys Chem A. 2015 Jul 23;119(29):8256-7. doi: 10.1021/acs.jpca.5b04198. Epub 2015 Jul 10. No abstract available.
C15H10 and C15H12 Thermal Chemistry: Phenanthrylcarbene Isomers and Phenylindenes by Falling Solid Flash Vacuum Pyrolysis of Tetrazoles.
Wentrup C, Becker J, Diehl M.
J Org Chem. 2015 Jul 17;80(14):7144-9. doi: 10.1021/acs.joc.5b01007. Epub 2015 Jun 26.
C9H8 Pyrolysis. o-Tolylacetylene, Indene, 1-Indenyl, and Biindenyls and the Mechanism of Indene Pyrolysis.
Wentrup C, Winter HW, Kvaskoff D.
J Phys Chem A. 2015 Jun 18;119(24):6370-6. doi: 10.1021/acs.jpca.5b03453. Epub 2015 Jun 5.
Use of carbon monoxide and hydrogen by a bacteria-animal symbiosis from seagrass sediments.
Kleiner M, Wentrup C, Holler T, Lavik G, Harder J, Lott C, Littmann S, Kuypers MM, Dubilier N.
Environ Microbiol. 2015 Dec;17(12):5023-35. doi: 10.1111/1462-2920.12912. Epub 2015 Jul 23.
Azulenylcarbene and naphthylcarbene isomerizations. Falling solid flash vacuum pyrolysis.
Kvaskoff D, Becker J, Wentrup C.
J Org Chem. 2015 May 15;80(10):5030-4. doi: 10.1021/acs.joc.5b00412. Epub 2015 May 7.
Falling-solid flash vacuum pyrolysis: an efficient preparation of arylacetylenes.
Wentrup C, Becker J, Winter HW.
Angew Chem Int Ed Engl. 2015 May 4;54(19):5702-4. doi: 10.1002/anie.201412431. Epub 2015 Mar 12.
Direct detection of a triplet vinylnitrene, 1,4-naphthoquinone-2-ylnitrene, in solution and cryogenic matrices.
Sarkar SK, Sawai A, Kanahara K, Wentrup C, Abe M, Gudmundsdottir AD.
J Am Chem Soc. 2015 Apr 1;137(12):4207-14. doi: 10.1021/jacs.5b00998. Epub 2015 Mar 23.
Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride.
Kollenz G, Smounig R, Belaj F, Kvaskoff D, Wentrup C.
Beilstein J Org Chem. 2015 Jan 2;11:1-8. doi: 10.3762/bjoc.11.1. eCollection 2015.
Phenylnitrene, phenylcarbene, and pyridylcarbenes. Rearrangements to cyanocyclopentadiene and fulvenallene.
Kvaskoff D, Lüerssen H, Bednarek P, Wentrup C.
J Am Chem Soc. 2014 Oct 29;136(43):15203-14. doi: 10.1021/ja506151p. Epub 2014 Oct 17.
Forever competent: deep-sea bivalves are colonized by their chemosynthetic symbionts throughout their lifetime.
Wentrup C, Wendeberg A, Schimak M, Borowski C, Dubilier N.
Environ Microbiol. 2014 Dec;16(12):3699-713. doi: 10.1111/1462-2920.12597. Epub 2014 Dec 11.
Ketene-ketene interconversion. 6-Carbonylcyclohexa-2,4-dienone-hepta-1,2,4,6-tetraene-1,7-dione-6-oxocyclohexa-2,4-dienylidene and Wolff rearrangement to fulven-6-one.
Koch R, Blanch RJ, Wentrup C.
J Org Chem. 2014 Aug 1;79(15):6978-86. doi: 10.1021/jo5011087. Epub 2014 Jul 11.
Comment on "computational study on the vinyl azide decomposition".
Wentrup C, Nunes CM, Reva I.
J Phys Chem A. 2014 Jul 10;118(27):5122-3. doi: 10.1021/jp503958z. Epub 2014 Jun 26. No abstract available.
Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization.
Bégué D, Addicott C, Burgard R, Bednarek P, Guille E, Baraille I, Wentrup C.
J Org Chem. 2014 Mar 7;79(5):2148-55. doi: 10.1021/jo500002r. Epub 2014 Feb 20.
3-Pyridazinylnitrenes and 2-pyrimidinylnitrenes.
Torker S, Kvaskoff D, Wentrup C.
J Org Chem. 2014 Feb 21;79(4):1758-70. doi: 10.1021/jo4027897. Epub 2014 Feb 5.
Carbenic nitrile imines: properties and reactivity.
Bégué D, Wentrup C.
J Org Chem. 2014 Feb 7;79(3):1418-26.
Nitrile imines and nitrile ylides: rearrangements of benzonitrile N-methylimine and benzonitrile dimethylmethylide to azabutadienes, carbodiimides, and ketenimines. Chemical activation in thermolysis of azirenes, tetrazoles, oxazolones, isoxazolones, and oxadiazolones.
Bégué D, Dargelos A, Berstermann HM, Netsch KP, Bednarek P, Wentrup C.
J Org Chem. 2014 Feb 7;79(3):1247-53. doi: 10.1021/jo402667y. Epub 2014 Jan 14.
Formation of allenyl ketones, 3-ethynylcoumarins, and arylfurans, furylfurans, and furylthiophenes by flash vacuum thermolysis of 3-methylidenefuran-2(3H)-ones.
Koch R, Berstermann HM, Wentrup C.
J Org Chem. 2014 Jan 3;79(1):65-71. doi: 10.1021/jo402139a. Epub 2013 Dec 19.
Nitrene-carbene-carbene rearrangement. Photolysis and thermolysis of tetrazolo[5,1-a]phthalazine with formation of 1-phthalazinylnitrene, o-cyanophenylcarbene, and phenylcyanocarbene.
Høj M, Kvaskoff D, Wentrup C.
J Org Chem. 2014 Jan 3;79(1):307-13. doi: 10.1021/jo402448u. Epub 2013 Dec 12.
Photolysis of dimethylcarbamoyl azide in an argon matrix: spectroscopic identification of dimethylamino isocyanate and 1,1-dimethyldiazene.
Pasinszki T, Krebsz M, Tarczay G, Wentrup C.
J Org Chem. 2013 Dec 6;78(23):11985-91. doi: 10.1021/jo402023m. Epub 2013 Nov 12.
Iminopropadienones RN=C=C=C=O and bisiminopropadienes RN=C=C=C=NR: matrix infrared spectra and anharmonic frequency calculations.
Bégué D, Baraille I, Andersen HG, Wentrup C.
J Chem Phys. 2013 Oct 28;139(16):164314. doi: 10.1063/1.4826647.
New reactions of N-tert-butylimines; formation of N-heterocycles by methyl radical elimination on flash vacuum thermolysis of N-benzylidene- and N-(2-pyridylmethylidene)-tert-butylamines.
Vu TY, Chrostowska A, Huynh TK, Khayar S, Dargelos A, Justyna K, Pasternak B, Leśniak S, Wentrup C.
Chemistry. 2013 Oct 25;19(44):14983-8. doi: 10.1002/chem.201301663. Epub 2013 Sep 20.
Matrix-IR spectroscopic investigations of the thermolysis and photolysis of diazoamides.
Wentrup C, Bibas H, Kuhn A, Mitschke U, McMills MC.
J Org Chem. 2013 Nov 1;78(21):10705-17. doi: 10.1021/jo401695x. Epub 2013 Oct 24.
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