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Trimethylsilylnitrene and its Surprising Rearrangement to N-(Dimethylsilyl)methanimine via Silaziridine and Silaazomethine Ylide.
Wentrup C, Lüerssen H, Silva HS, Dargelos A, Bégué D.
Chemistry. 2018 Jul 24. doi: 10.1002/chem.201803245. [Epub ahead of print]
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Acquisition of a Novel Sulfur-Oxidizing Symbiont in the Gutless Marine Worm Inanidrilus exumae.
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Imidoylnitrenes R'C(═NR)-N, Nitrile Imines, 1H-Diazirines, and Carbodiimides: Interconversions and Rearrangements, Structures, and Energies at DFT and CASPT2 Levels of Theory.
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Iminocyclohexadienylidenes: Carbenes or Diradicals? The Hetero-Wolff Rearrangement of Benzotriazoles to Cyanocyclopentadienes and 1H-Benzo[b]azirines.
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Flash Vacuum Pyrolysis: Techniques and Reactions.
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Biphasic Metabolism and Host Interaction of a Chlamydial Symbiont.
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A Thermally Populated, Perpendicularly Twisted Alkene Triplet Diradical.
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Azulene-Naphthalene-Type Rearrangements in Benz[a]azulene and Cyclohepta[b]indole.
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Ring Contraction in Arylcarbenes and Arylnitrenes; Rearrangements of 1- and 3-Isoquinolylcarbenes and 2-Naphthylnitrene to Cyanoindenes.
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J Org Chem. 2016 Jun 3;81(11):4601-8. doi: 10.1021/acs.joc.6b00442. Epub 2016 May 13.
Rearrangements of 4-Quinolylcarbene, 3-Quinolylcarbene, and 2-Quinolylcarbene to 1-Naphthylnitrene and Cyanoindenes by Falling Solid Flash Vacuum Pyrolysis.
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J Org Chem. 2016 Jun 3;81(11):4609-15. doi: 10.1021/acs.joc.6b00444. Epub 2016 May 13.
Direct Observation of Carbamoylnitrenes.
Li H, Wan H, Wu Z, Li D, Bégué D, Wentrup C, Zeng X.
Chemistry. 2016 Jun 1;22(23):7856-62. doi: 10.1002/chem.201600824. Epub 2016 Apr 23.
Closely coupled evolutionary history of ecto- and endosymbionts from two distantly related animal phyla.
Zimmermann J, Wentrup C, Sadowski M, Blazejak A, Gruber-Vodicka HR, Kleiner M, Ott JA, Cronholm B, De Wit P, Erséus C, Dubilier N.
Mol Ecol. 2016 Jul;25(13):3203-23. doi: 10.1111/mec.13554. Epub 2016 Mar 15.
Triazoloazine-Diazomethylazine Valence Isomerization. [1,2,3]Triazolo[1,5-a]pyridines and 2-Diazomethylpyridines.
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J Org Chem. 2016 Jan 15;81(2):667-72. doi: 10.1021/acs.joc.5b02639. Epub 2015 Dec 24.
Bond-shift isomers: the co-existence of allenic and propargylic phenylnitrile imines.
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Chem Commun (Camb). 2015 Oct 11;51(79):14712-5. doi: 10.1039/c5cc03518j.
Comment on "The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation".
J Phys Chem A. 2015 Jul 23;119(29):8256-7. doi: 10.1021/acs.jpca.5b04198. Epub 2015 Jul 10. No abstract available.
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J Org Chem. 2015 Jul 17;80(14):7144-9. doi: 10.1021/acs.joc.5b01007. Epub 2015 Jun 26.
C9H8 Pyrolysis. o-Tolylacetylene, Indene, 1-Indenyl, and Biindenyls and the Mechanism of Indene Pyrolysis.
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J Phys Chem A. 2015 Jun 18;119(24):6370-6. doi: 10.1021/acs.jpca.5b03453. Epub 2015 Jun 5.
Use of carbon monoxide and hydrogen by a bacteria-animal symbiosis from seagrass sediments.
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Azulenylcarbene and naphthylcarbene isomerizations. Falling solid flash vacuum pyrolysis.
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J Org Chem. 2015 May 15;80(10):5030-4. doi: 10.1021/acs.joc.5b00412. Epub 2015 May 7.
Falling-solid flash vacuum pyrolysis: an efficient preparation of arylacetylenes.
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Angew Chem Int Ed Engl. 2015 May 4;54(19):5702-4. doi: 10.1002/anie.201412431. Epub 2015 Mar 12.
Direct detection of a triplet vinylnitrene, 1,4-naphthoquinone-2-ylnitrene, in solution and cryogenic matrices.
Sarkar SK, Sawai A, Kanahara K, Wentrup C, Abe M, Gudmundsdottir AD.
J Am Chem Soc. 2015 Apr 1;137(12):4207-14. doi: 10.1021/jacs.5b00998. Epub 2015 Mar 23.
Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride.
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Phenylnitrene, phenylcarbene, and pyridylcarbenes. Rearrangements to cyanocyclopentadiene and fulvenallene.
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Comment on "computational study on the vinyl azide decomposition".
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Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization.
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J Org Chem. 2014 Mar 7;79(5):2148-55. doi: 10.1021/jo500002r. Epub 2014 Feb 20.
3-Pyridazinylnitrenes and 2-pyrimidinylnitrenes.
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J Org Chem. 2014 Feb 21;79(4):1758-70. doi: 10.1021/jo4027897. Epub 2014 Feb 5.
Carbenic nitrile imines: properties and reactivity.
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J Org Chem. 2014 Feb 7;79(3):1418-26.
Nitrile imines and nitrile ylides: rearrangements of benzonitrile N-methylimine and benzonitrile dimethylmethylide to azabutadienes, carbodiimides, and ketenimines. Chemical activation in thermolysis of azirenes, tetrazoles, oxazolones, isoxazolones, and oxadiazolones.
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J Org Chem. 2014 Feb 7;79(3):1247-53. doi: 10.1021/jo402667y. Epub 2014 Jan 14.
Formation of allenyl ketones, 3-ethynylcoumarins, and arylfurans, furylfurans, and furylthiophenes by flash vacuum thermolysis of 3-methylidenefuran-2(3H)-ones.
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J Org Chem. 2014 Jan 3;79(1):65-71. doi: 10.1021/jo402139a. Epub 2013 Dec 19.
Nitrene-carbene-carbene rearrangement. Photolysis and thermolysis of tetrazolo[5,1-a]phthalazine with formation of 1-phthalazinylnitrene, o-cyanophenylcarbene, and phenylcyanocarbene.
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J Org Chem. 2014 Jan 3;79(1):307-13. doi: 10.1021/jo402448u. Epub 2013 Dec 12.
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Pasinszki T, Krebsz M, Tarczay G, Wentrup C.
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Iminopropadienones RN=C=C=C=O and bisiminopropadienes RN=C=C=C=NR: matrix infrared spectra and anharmonic frequency calculations.
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Vu TY, Chrostowska A, Huynh TK, Khayar S, Dargelos A, Justyna K, Pasternak B, Leśniak S, Wentrup C.
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4-Pyridylnitrene and 2-pyrazinylcarbene.
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Beilstein J Org Chem. 2013 Apr 17;9:754-60. doi: 10.3762/bjoc.9.85. Print 2013.
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Beilstein J Org Chem. 2013 Apr 17;9:743-53. doi: 10.3762/bjoc.9.84. Print 2013.
Shift from widespread symbiont infection of host tissues to specific colonization of gills in juvenile deep-sea mussels.
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ISME J. 2013 Jun;7(6):1244-7. doi: 10.1038/ismej.2013.5. Epub 2013 Feb 7.
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Leber S, Kollenz G, Wentrup C.
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Origins and evolutionary flexibility of chemosynthetic symbionts from deep-sea animals.
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Koch R, Wentrup C.
J Org Chem. 2013 Mar 1;78(5):1802-10. doi: 10.1021/jo3013786. Epub 2012 Sep 20.
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Chrostowska A, Dargelos A, Khayar S, Wentrup C.
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