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Items: 1 to 50 of 100

1.

Trimethylsilylnitrene and its Surprising Rearrangement to N-(Dimethylsilyl)methanimine via Silaziridine and Silaazomethine Ylide.

Wentrup C, Lüerssen H, Silva HS, Dargelos A, Bégué D.

Chemistry. 2018 Jul 24. doi: 10.1002/chem.201803245. [Epub ahead of print]

PMID:
30040164
2.

Carbenes and Nitrenes: Recent Developments in Fundamental Chemistry.

Wentrup C.

Angew Chem Int Ed Engl. 2018 May 29. doi: 10.1002/anie.201804863. [Epub ahead of print] Review.

PMID:
29808956
3.

Peatland Acidobacteria with a dissimilatory sulfur metabolism.

Hausmann B, Pelikan C, Herbold CW, Köstlbacher S, Albertsen M, Eichorst SA, Glavina Del Rio T, Huemer M, Nielsen PH, Rattei T, Stingl U, Tringe SG, Trojan D, Wentrup C, Woebken D, Pester M, Loy A.

ISME J. 2018 Jun;12(7):1729-1742. doi: 10.1038/s41396-018-0077-1. Epub 2018 Feb 23.

4.

Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole.

Abe M, Bégué D, Santos-Silva H, Dargelos A, Wentrup C.

Angew Chem Int Ed Engl. 2018 Mar 12;57(12):3212-3216. doi: 10.1002/anie.201712689. Epub 2018 Feb 21.

PMID:
29390171
5.

From dipivaloylketene to tetraoxaadamantanes.

Kollenz G, Wentrup C.

Beilstein J Org Chem. 2018 Jan 2;14:1-10. doi: 10.3762/bjoc.14.1. eCollection 2018. Review.

6.

Acquisition of a Novel Sulfur-Oxidizing Symbiont in the Gutless Marine Worm Inanidrilus exumae.

Bergin C, Wentrup C, Brewig N, Blazejak A, Erséus C, Giere O, Schmid M, De Wit P, Dubilier N.

Appl Environ Microbiol. 2018 Mar 19;84(7). pii: e02267-17. doi: 10.1128/AEM.02267-17. Print 2018 Apr 1.

7.

Imidoylnitrenes R'C(═NR)-N, Nitrile Imines, 1H-Diazirines, and Carbodiimides: Interconversions and Rearrangements, Structures, and Energies at DFT and CASPT2 Levels of Theory.

Bégué D, Santos-Silva H, Dargelos A, Wentrup C.

J Phys Chem A. 2017 Nov 2;121(43):8227-8235. doi: 10.1021/acs.jpca.7b08445. Epub 2017 Oct 19.

PMID:
28982241
8.

Iminocyclohexadienylidenes: Carbenes or Diradicals? The Hetero-Wolff Rearrangement of Benzotriazoles to Cyanocyclopentadienes and 1H-Benzo[b]azirines.

Bégué D, Santos-Silva H, Dargelos A, Wentrup C.

J Phys Chem A. 2017 Aug 17;121(32):5998-6003. doi: 10.1021/acs.jpca.7b05325. Epub 2017 Aug 2.

PMID:
28718288
9.

Flash Vacuum Pyrolysis: Techniques and Reactions.

Wentrup C.

Angew Chem Int Ed Engl. 2017 Nov 20;56(47):14808-14835. doi: 10.1002/anie.201705118. Epub 2017 Oct 25. Review.

PMID:
28675675
10.

Biphasic Metabolism and Host Interaction of a Chlamydial Symbiont.

König L, Siegl A, Penz T, Haider S, Wentrup C, Polzin J, Mann E, Schmitz-Esser S, Domman D, Horn M.

mSystems. 2017 May 30;2(3). pii: e00202-16. doi: 10.1128/mSystems.00202-16. eCollection 2017 May-Jun.

11.

Flash Vacuum Pyrolysis of Azides, Triazoles, and Tetrazoles.

Wentrup C.

Chem Rev. 2017 Mar 8;117(5):4562-4623. doi: 10.1021/acs.chemrev.6b00738. Epub 2017 Feb 24.

12.

A Thermally Populated, Perpendicularly Twisted Alkene Triplet Diradical.

Wentrup C, Regimbald-Krnel MJ, Müller D, Comba P.

Angew Chem Int Ed Engl. 2016 Nov 14;55(47):14600-14605. doi: 10.1002/anie.201607415. Epub 2016 Oct 20.

PMID:
27763735
13.

Azulene-Naphthalene-Type Rearrangements in Benz[a]azulene and Cyclohepta[b]indole.

Wentrup C, Becker J.

Chemistry. 2016 Sep 19;22(39):13835-13839. doi: 10.1002/chem.201603389. Epub 2016 Aug 18.

PMID:
27535491
14.

Ring Contraction in Arylcarbenes and Arylnitrenes; Rearrangements of 1- and 3-Isoquinolylcarbenes and 2-Naphthylnitrene to Cyanoindenes.

Wentrup C, Thétaz C, Lüerssen H, Aylward N, Kvaskoff D.

J Org Chem. 2016 Jun 3;81(11):4601-8. doi: 10.1021/acs.joc.6b00442. Epub 2016 May 13.

PMID:
27152672
15.

Rearrangements of 4-Quinolylcarbene, 3-Quinolylcarbene, and 2-Quinolylcarbene to 1-Naphthylnitrene and Cyanoindenes by Falling Solid Flash Vacuum Pyrolysis.

Aylward N, Kvaskoff D, Becker J, Wentrup C.

J Org Chem. 2016 Jun 3;81(11):4609-15. doi: 10.1021/acs.joc.6b00444. Epub 2016 May 13.

PMID:
27152548
16.

Direct Observation of Carbamoylnitrenes.

Li H, Wan H, Wu Z, Li D, Bégué D, Wentrup C, Zeng X.

Chemistry. 2016 Jun 1;22(23):7856-62. doi: 10.1002/chem.201600824. Epub 2016 Apr 23.

PMID:
27105905
17.

Closely coupled evolutionary history of ecto- and endosymbionts from two distantly related animal phyla.

Zimmermann J, Wentrup C, Sadowski M, Blazejak A, Gruber-Vodicka HR, Kleiner M, Ott JA, Cronholm B, De Wit P, Erséus C, Dubilier N.

Mol Ecol. 2016 Jul;25(13):3203-23. doi: 10.1111/mec.13554. Epub 2016 Mar 15.

PMID:
26826340
18.

Triazoloazine-Diazomethylazine Valence Isomerization. [1,2,3]Triazolo[1,5-a]pyridines and 2-Diazomethylpyridines.

Aylward N, Winter HW, Eckhardt U, Wentrup C.

J Org Chem. 2016 Jan 15;81(2):667-72. doi: 10.1021/acs.joc.5b02639. Epub 2015 Dec 24.

PMID:
26672395
19.

Bond-shift isomers: the co-existence of allenic and propargylic phenylnitrile imines.

Nunes CM, Reva I, Fausto R, Bégué D, Wentrup C.

Chem Commun (Camb). 2015 Oct 11;51(79):14712-5. doi: 10.1039/c5cc03518j.

PMID:
26244172
20.

Comment on "The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation".

Wentrup C.

J Phys Chem A. 2015 Jul 23;119(29):8256-7. doi: 10.1021/acs.jpca.5b04198. Epub 2015 Jul 10. No abstract available.

PMID:
26139074
21.

C15H10 and C15H12 Thermal Chemistry: Phenanthrylcarbene Isomers and Phenylindenes by Falling Solid Flash Vacuum Pyrolysis of Tetrazoles.

Wentrup C, Becker J, Diehl M.

J Org Chem. 2015 Jul 17;80(14):7144-9. doi: 10.1021/acs.joc.5b01007. Epub 2015 Jun 26.

PMID:
26086716
22.

C9H8 Pyrolysis. o-Tolylacetylene, Indene, 1-Indenyl, and Biindenyls and the Mechanism of Indene Pyrolysis.

Wentrup C, Winter HW, Kvaskoff D.

J Phys Chem A. 2015 Jun 18;119(24):6370-6. doi: 10.1021/acs.jpca.5b03453. Epub 2015 Jun 5.

PMID:
26014897
23.

Use of carbon monoxide and hydrogen by a bacteria-animal symbiosis from seagrass sediments.

Kleiner M, Wentrup C, Holler T, Lavik G, Harder J, Lott C, Littmann S, Kuypers MM, Dubilier N.

Environ Microbiol. 2015 Dec;17(12):5023-35. doi: 10.1111/1462-2920.12912. Epub 2015 Jul 23.

24.

Azulenylcarbene and naphthylcarbene isomerizations. Falling solid flash vacuum pyrolysis.

Kvaskoff D, Becker J, Wentrup C.

J Org Chem. 2015 May 15;80(10):5030-4. doi: 10.1021/acs.joc.5b00412. Epub 2015 May 7.

PMID:
25927156
25.

Falling-solid flash vacuum pyrolysis: an efficient preparation of arylacetylenes.

Wentrup C, Becker J, Winter HW.

Angew Chem Int Ed Engl. 2015 May 4;54(19):5702-4. doi: 10.1002/anie.201412431. Epub 2015 Mar 12.

PMID:
25765562
26.

Direct detection of a triplet vinylnitrene, 1,4-naphthoquinone-2-ylnitrene, in solution and cryogenic matrices.

Sarkar SK, Sawai A, Kanahara K, Wentrup C, Abe M, Gudmundsdottir AD.

J Am Chem Soc. 2015 Apr 1;137(12):4207-14. doi: 10.1021/jacs.5b00998. Epub 2015 Mar 23.

PMID:
25760227
27.

Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride.

Kollenz G, Smounig R, Belaj F, Kvaskoff D, Wentrup C.

Beilstein J Org Chem. 2015 Jan 2;11:1-8. doi: 10.3762/bjoc.11.1. eCollection 2015.

28.

Phenylnitrene, phenylcarbene, and pyridylcarbenes. Rearrangements to cyanocyclopentadiene and fulvenallene.

Kvaskoff D, Lüerssen H, Bednarek P, Wentrup C.

J Am Chem Soc. 2014 Oct 29;136(43):15203-14. doi: 10.1021/ja506151p. Epub 2014 Oct 17.

PMID:
25322946
29.

Forever competent: deep-sea bivalves are colonized by their chemosynthetic symbionts throughout their lifetime.

Wentrup C, Wendeberg A, Schimak M, Borowski C, Dubilier N.

Environ Microbiol. 2014 Dec;16(12):3699-713. doi: 10.1111/1462-2920.12597. Epub 2014 Dec 11.

PMID:
25142549
30.

Ketene-ketene interconversion. 6-Carbonylcyclohexa-2,4-dienone-hepta-1,2,4,6-tetraene-1,7-dione-6-oxocyclohexa-2,4-dienylidene and Wolff rearrangement to fulven-6-one.

Koch R, Blanch RJ, Wentrup C.

J Org Chem. 2014 Aug 1;79(15):6978-86. doi: 10.1021/jo5011087. Epub 2014 Jul 11.

PMID:
24988224
31.

Comment on "computational study on the vinyl azide decomposition".

Wentrup C, Nunes CM, Reva I.

J Phys Chem A. 2014 Jul 10;118(27):5122-3. doi: 10.1021/jp503958z. Epub 2014 Jun 26. No abstract available.

PMID:
24941133
32.

Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization.

Bégué D, Addicott C, Burgard R, Bednarek P, Guille E, Baraille I, Wentrup C.

J Org Chem. 2014 Mar 7;79(5):2148-55. doi: 10.1021/jo500002r. Epub 2014 Feb 20.

PMID:
24517550
33.

3-Pyridazinylnitrenes and 2-pyrimidinylnitrenes.

Torker S, Kvaskoff D, Wentrup C.

J Org Chem. 2014 Feb 21;79(4):1758-70. doi: 10.1021/jo4027897. Epub 2014 Feb 5.

PMID:
24456188
34.

Carbenic nitrile imines: properties and reactivity.

Bégué D, Wentrup C.

J Org Chem. 2014 Feb 7;79(3):1418-26.

PMID:
24400935
35.
36.

Formation of allenyl ketones, 3-ethynylcoumarins, and arylfurans, furylfurans, and furylthiophenes by flash vacuum thermolysis of 3-methylidenefuran-2(3H)-ones.

Koch R, Berstermann HM, Wentrup C.

J Org Chem. 2014 Jan 3;79(1):65-71. doi: 10.1021/jo402139a. Epub 2013 Dec 19.

PMID:
24328255
37.
38.

Photolysis of dimethylcarbamoyl azide in an argon matrix: spectroscopic identification of dimethylamino isocyanate and 1,1-dimethyldiazene.

Pasinszki T, Krebsz M, Tarczay G, Wentrup C.

J Org Chem. 2013 Dec 6;78(23):11985-91. doi: 10.1021/jo402023m. Epub 2013 Nov 12.

PMID:
24191697
39.

Iminopropadienones RN=C=C=C=O and bisiminopropadienes RN=C=C=C=NR: matrix infrared spectra and anharmonic frequency calculations.

Bégué D, Baraille I, Andersen HG, Wentrup C.

J Chem Phys. 2013 Oct 28;139(16):164314. doi: 10.1063/1.4826647.

PMID:
24182036
40.

New reactions of N-tert-butylimines; formation of N-heterocycles by methyl radical elimination on flash vacuum thermolysis of N-benzylidene- and N-(2-pyridylmethylidene)-tert-butylamines.

Vu TY, Chrostowska A, Huynh TK, Khayar S, Dargelos A, Justyna K, Pasternak B, Leśniak S, Wentrup C.

Chemistry. 2013 Oct 25;19(44):14983-8. doi: 10.1002/chem.201301663. Epub 2013 Sep 20.

PMID:
24108670
41.

Matrix-IR spectroscopic investigations of the thermolysis and photolysis of diazoamides.

Wentrup C, Bibas H, Kuhn A, Mitschke U, McMills MC.

J Org Chem. 2013 Nov 1;78(21):10705-17. doi: 10.1021/jo401695x. Epub 2013 Oct 24.

PMID:
24102481
42.

Laser-induced carbene-carbene rearrangement in solution: the diphenylcarbene-fluorene rearrangement.

Régimbald-Krnel MJ, Wentrup C.

J Org Chem. 2013 Sep 6;78(17):8789-95. doi: 10.1021/jo401607m. Epub 2013 Aug 13.

PMID:
23941300
43.

Mechanistic diversity in thermal fragmentation reactions: a computational exploration of CO and CO₂ extrusions from five-membered rings.

Rzepa HS, Wentrup C.

J Org Chem. 2013 Aug 2;78(15):7565-74. doi: 10.1021/jo401146k. Epub 2013 Jul 16.

PMID:
23795601
44.

4-Pyridylnitrene and 2-pyrazinylcarbene.

Wentrup C, Reisinger A, Kvaskoff D.

Beilstein J Org Chem. 2013 Apr 17;9:754-60. doi: 10.3762/bjoc.9.85. Print 2013.

46.

Shift from widespread symbiont infection of host tissues to specific colonization of gills in juvenile deep-sea mussels.

Wentrup C, Wendeberg A, Huang JY, Borowski C, Dubilier N.

ISME J. 2013 Jun;7(6):1244-7. doi: 10.1038/ismej.2013.5. Epub 2013 Feb 7.

47.

Synthesis of functionalized macrocyclic derivatives of trioxabicyclo[3.3.0]nonadiene.

Leber S, Kollenz G, Wentrup C.

Beilstein J Org Chem. 2012;8:738-43. Epub 2012 May 15.

48.

Origins and evolutionary flexibility of chemosynthetic symbionts from deep-sea animals.

Petersen JM, Wentrup C, Verna C, Knittel K, Dubilier N.

Biol Bull. 2012 Aug;223(1):123-37. Erratum in: Biol Bull. 2012 Dec;223(3):x.

PMID:
22983038
50.

Methyliminopropadienone CH3-N═C═C═C═O: photoelectron spectrum and electronic structure.

Chrostowska A, Dargelos A, Khayar S, Wentrup C.

J Phys Chem A. 2012 Sep 20;116(37):9315-20. Epub 2012 Sep 10.

PMID:
22934652

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