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Flexible NO2-Functionalized N-Heterocyclic Carbene Monolayers on Au (111) Surface.

Dery S, Kim S, Tomaschun G, Haddad D, Cossaro A, Verdini A, Floreano L, Klüner T, Toste FD, Gross E.

Chemistry. 2019 Aug 8. doi: 10.1002/chem.201903434. [Epub ahead of print]


Elucidating the Influence of Anchoring Geometry on the Reactivity of NO2-Functionalized N-Heterocyclic Carbene Monolayers.

Dery S, Kim S, Tomaschun G, Berg I, Feferman D, Cossaro A, Verdini A, Floreano L, Kluener T, Toste FD, Gross E.

J Phys Chem Lett. 2019 Aug 6. doi: 10.1021/acs.jpclett.9b01808. [Epub ahead of print]


A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation.

Christian AH, Jia S, Cao W, Zhang P, Meza AT, Sigman MS, Chang CJ, Toste FD.

J Am Chem Soc. 2019 Aug 14;141(32):12657-12662. doi: 10.1021/jacs.9b04744. Epub 2019 Jul 30.


A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.

Bender TA, Bergman RG, Raymond KN, Toste FD.

J Am Chem Soc. 2019 Jul 31;141(30):11806-11810. doi: 10.1021/jacs.9b05604. Epub 2019 Jul 16.


Enantioselective construction of remote tertiary carbon-fluorine bonds.

Liu J, Yuan Q, Toste FD, Sigman MS.

Nat Chem. 2019 Aug;11(8):710-715. doi: 10.1038/s41557-019-0289-7. Epub 2019 Jul 15.


Synthesis of Biomass-Derived Ethers for Use as Fuels and Lubricants.

Rorrer JE, Bell AT, Toste FD.

ChemSusChem. 2019 Jul 5;12(13):2835-2858. doi: 10.1002/cssc.201900535. Epub 2019 Jun 24. Review.


A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization.

Zhukhovitskiy AV, Kobylianskii IJ, Thomas AA, Evans AM, Delaney CP, Flanders NC, Denmark SE, Dichtel WR, Toste FD.

J Am Chem Soc. 2019 Apr 24;141(16):6473-6478. doi: 10.1021/jacs.9b01532. Epub 2019 Apr 9.


Electrocatalysis at Organic-Metal Interfaces: Identification of Structure-Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces.

Buckley AK, Lee M, Cheng T, Kazantsev RV, Larson DM, Goddard Iii WA, Toste FD, Toma FM.

J Am Chem Soc. 2019 May 8;141(18):7355-7364. doi: 10.1021/jacs.8b13655. Epub 2019 Apr 29.


Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration.

Kwon Y, Li J, Reid JP, Crawford JM, Jacob R, Sigman MS, Toste FD, Miller SJ.

J Am Chem Soc. 2019 Apr 24;141(16):6698-6705. doi: 10.1021/jacs.9b01911. Epub 2019 Apr 10.


Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics.

Bender TA, Morimoto M, Bergman RG, Raymond KN, Toste FD.

J Am Chem Soc. 2019 Jan 30;141(4):1701-1706. doi: 10.1021/jacs.8b11842. Epub 2019 Jan 22.


Mechanism of Photoredox-Initiated C-C and C-N Bond Formation by Arylation of IPrAu(I)-CF3 and IPrAu(I)-Succinimide.

Kim S, Toste FD.

J Am Chem Soc. 2019 Mar 13;141(10):4308-4315. doi: 10.1021/jacs.8b11273. Epub 2019 Jan 17.


Harnessing Noncovalent Interactions in Dual-Catalytic Enantioselective Heck-Matsuda Arylation.

Reddi Y, Tsai CC, Avila CM, Toste FD, Sunoj RB.

J Am Chem Soc. 2019 Jan 16;141(2):998-1009. doi: 10.1021/jacs.8b11062. Epub 2018 Dec 28.


Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions.

Coelho JAS, Matsumoto A, Orlandi M, Hilton MJ, Sigman MS, Toste FD.

Chem Sci. 2018 Aug 3;9(35):7153-7158. doi: 10.1039/c8sc02223b. eCollection 2018 Sep 21.


Identifying site-dependent reactivity in oxidation reactions on single Pt particles.

Dery S, Kim S, Haddad D, Cossaro A, Verdini A, Floreano L, Toste FD, Gross E.

Chem Sci. 2018 Jul 3;9(31):6523-6531. doi: 10.1039/c8sc01956h. eCollection 2018 Aug 21.


Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts.

Hong CM, Bergman RG, Raymond KN, Toste FD.

Acc Chem Res. 2018 Oct 16;51(10):2447-2455. doi: 10.1021/acs.accounts.8b00328. Epub 2018 Oct 1.


Effect of Alcohol Structure on the Kinetics of Etherification and Dehydration over Tungstated Zirconia.

Rorrer J, Pindi S, Toste FD, Bell AT.

ChemSusChem. 2018 Sep 21;11(18):3104-3111. doi: 10.1002/cssc.201801067. Epub 2018 Aug 23.


Chiral Diaryliodonium Phosphate Enables Light Driven Diastereoselective α-C(sp3)-H Acetalization.

Ye B, Zhao J, Zhao K, McKenna JM, Toste FD.

J Am Chem Soc. 2018 Jul 5;140(26):8350-8356. doi: 10.1021/jacs.8b05962. Epub 2018 Jun 25.


Deconvoluting the Role of Charge in a Supramolecular Catalyst.

Hong CM, Morimoto M, Kapustin EA, Alzakhem N, Bergman RG, Raymond KN, Toste FD.

J Am Chem Soc. 2018 May 30;140(21):6591-6595. doi: 10.1021/jacs.8b01701. Epub 2018 May 16.


Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis.

Christian AH, Niemeyer ZL, Sigman MS, Toste FD.

ACS Catal. 2017 Jun 2;7(6):3973-3978. doi: 10.1021/acscatal.7b00757. Epub 2017 May 10.


Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs.

Zhu Y, Han J, Wang J, Shibata N, Sodeoka M, Soloshonok VA, Coelho JAS, Toste FD.

Chem Rev. 2018 Apr 11;118(7):3887-3964. doi: 10.1021/acs.chemrev.7b00778. Epub 2018 Apr 2. Review.


Supported Au Nanoparticles with N-Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization.

Ye R, Zhukhovitskiy AV, Kazantsev RV, Fakra SC, Wickemeyer BB, Toste FD, Somorjai GA.

J Am Chem Soc. 2018 Mar 21;140(11):4144-4149. doi: 10.1021/jacs.8b01017. Epub 2018 Mar 9.


Migratory Insertion of Carbenes into Au(III)-C Bonds.

Zhukhovitskiy AV, Kobylianskii IJ, Wu CY, Toste FD.

J Am Chem Soc. 2018 Jan 10;140(1):466-474. doi: 10.1021/jacs.7b11435. Epub 2017 Dec 20.


Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis.

Biswas S, Kubota K, Orlandi M, Turberg M, Miles DH, Sigman MS, Toste FD.

Angew Chem Int Ed Engl. 2018 Jan 8;57(2):589-593. doi: 10.1002/anie.201711277. Epub 2017 Dec 12.


Dendrimer-Stabilized Metal Nanoparticles as Efficient Catalysts for Reversible Dehydrogenation/Hydrogenation of N-Heterocycles.

Deraedt C, Ye R, Ralston WT, Toste FD, Somorjai GA.

J Am Chem Soc. 2017 Dec 13;139(49):18084-18092. doi: 10.1021/jacs.7b10768. Epub 2017 Nov 30.


Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates.

Larson RT, Samant A, Chen J, Lee W, Bohn MA, Ohlmann DM, Zuend SJ, Toste FD.

J Am Chem Soc. 2017 Oct 11;139(40):14001-14004. doi: 10.1021/jacs.7b07801. Epub 2017 Oct 3.


Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis.

Toste FD, Sigman MS, Miller SJ.

Acc Chem Res. 2017 Mar 21;50(3):609-615. doi: 10.1021/acs.accounts.6b00613.


Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.

Orlandi M, Toste FD, Sigman MS.

Angew Chem Int Ed Engl. 2017 Nov 6;56(45):14080-14084. doi: 10.1002/anie.201707644. Epub 2017 Oct 4.


Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

Niemeyer ZL, Pindi S, Khrakovsky DA, Kuzniewski CN, Hong CM, Joyce LA, Sigman MS, Toste FD.

J Am Chem Soc. 2017 Sep 20;139(37):12943-12946. doi: 10.1021/jacs.7b08791. Epub 2017 Sep 8.


Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates.

Orlandi M, Hilton MJ, Yamamoto E, Toste FD, Sigman MS.

J Am Chem Soc. 2017 Sep 13;139(36):12688-12695. doi: 10.1021/jacs.7b06917. Epub 2017 Aug 30.


Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes.

Bohan PT, Toste FD.

J Am Chem Soc. 2017 Aug 16;139(32):11016-11019. doi: 10.1021/jacs.7b06025. Epub 2017 Aug 3.


Supported Dendrimer-Encapsulated Metal Clusters: Toward Heterogenizing Homogeneous Catalysts.

Ye R, Zhukhovitskiy AV, Deraedt CV, Toste FD, Somorjai GA.

Acc Chem Res. 2017 Aug 15;50(8):1894-1901. doi: 10.1021/acs.accounts.7b00232. Epub 2017 Jul 13.


A catalytic fluoride-rebound mechanism for C(sp3)-CF3 bond formation.

Levin MD, Chen TQ, Neubig ME, Hong CM, Theulier CA, Kobylianskii IJ, Janabi M, O'Neil JP, Toste FD.

Science. 2017 Jun 23;356(6344):1272-1276. doi: 10.1126/science.aan1411.


Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host.

Hong CM, Kaphan DM, Bergman RG, Raymond KN, Toste FD.

J Am Chem Soc. 2017 Jun 14;139(23):8013-8021. doi: 10.1021/jacs.7b03812. Epub 2017 Jun 5.


A Comparison of Photocatalytic Activities of Gold Nanoparticles Following Plasmonic and Interband Excitation and a Strategy for Harnessing Interband Hot Carriers for Solution Phase Photocatalysis.

Zhao J, Nguyen SC, Ye R, Ye B, Weller H, Somorjai GA, Alivisatos AP, Toste FD.

ACS Cent Sci. 2017 May 24;3(5):482-488. doi: 10.1021/acscentsci.7b00122. Epub 2017 May 15.


Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.

Orlandi M, Coelho JAS, Hilton MJ, Toste FD, Sigman MS.

J Am Chem Soc. 2017 May 24;139(20):6803-6806. doi: 10.1021/jacs.7b02311. Epub 2017 May 11.


The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.

Thornbury RT, Saini V, Fernandes TA, Santiago CB, Talbot EPA, Sigman MS, McKenna JM, Toste FD.

Chem Sci. 2017 Apr 1;8(4):2890-2897. doi: 10.1039/c6sc05102b. Epub 2017 Feb 9.


Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-Transfer of Aryl Diazonium Salts.

Avila CM, Patel JS, Reddi Y, Saito M, Nelson HM, Shunatona HP, Sigman MS, Sunoj RB, Toste FD.

Angew Chem Int Ed Engl. 2017 May 15;56(21):5806-5811. doi: 10.1002/anie.201702107. Epub 2017 Apr 18.


Exploiting non-covalent π interactions for catalyst design.

Neel AJ, Hilton MJ, Sigman MS, Toste FD.

Nature. 2017 Mar 29;543(7647):637-646. doi: 10.1038/nature21701. Review.


Redox-based reagents for chemoselective methionine bioconjugation.

Lin S, Yang X, Jia S, Weeks AM, Hornsby M, Lee PS, Nichiporuk RV, Iavarone AT, Wells JA, Toste FD, Chang CJ.

Science. 2017 Feb 10;355(6325):597-602. doi: 10.1126/science.aal3316.


High-spatial-resolution mapping of catalytic reactions on single particles.

Wu CY, Wolf WJ, Levartovsky Y, Bechtel HA, Martin MC, Toste FD, Gross E.

Nature. 2017 Jan 26;541(7638):511-515. doi: 10.1038/nature20795. Epub 2017 Jan 11.


New Insights into Aldol Reactions of Methyl Isocyanoacetate Catalyzed by Heterogenized Homogeneous Catalysts.

Ye R, Zhao J, Yuan B, Liu WC, Rodrigues De Araujo J, Faucher FF, Chang M, Deraedt CV, Toste FD, Somorjai GA.

Nano Lett. 2017 Jan 11;17(1):584-589. doi: 10.1021/acs.nanolett.6b04827. Epub 2016 Dec 16.


Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer.

Yamamoto E, Hilton MJ, Orlandi M, Saini V, Toste FD, Sigman MS.

J Am Chem Soc. 2016 Dec 14;138(49):15877-15880. Epub 2016 Nov 30.


Enantioselective Oxidative Homocoupling and Cross-Coupling of 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes.

Narute S, Parnes R, Toste FD, Pappo D.

J Am Chem Soc. 2016 Dec 21;138(50):16553-16560. doi: 10.1021/jacs.6b11198. Epub 2016 Dec 13.


Palladium-Catalyzed Defluorinative Coupling of 1-Aryl-2,2-Difluoroalkenes and Boronic Acids: Stereoselective Synthesis of Monofluorostilbenes.

Thornbury RT, Toste FD.

Angew Chem Int Ed Engl. 2016 Sep 12;55(38):11629-32. doi: 10.1002/anie.201605651. Epub 2016 Aug 11.


Biomimetic Approach to the Catalytic Enantioselective Synthesis of Flavonoids.

Yang Z, He Y, Toste FD.

J Am Chem Soc. 2016 Aug 10;138(31):9775-8. doi: 10.1021/jacs.6b05939. Epub 2016 Jul 29.


Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis.

Levin MD, Kaphan DM, Hong CM, Bergman RG, Raymond KN, Toste FD.

J Am Chem Soc. 2016 Aug 3;138(30):9682-93. doi: 10.1021/jacs.6b05442. Epub 2016 Jul 26.


Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal-Organic Framework Crystals.

Fracaroli AM, Siman P, Nagib DA, Suzuki M, Furukawa H, Toste FD, Yaghi OM.

J Am Chem Soc. 2016 Jul 13;138(27):8352-5. doi: 10.1021/jacs.6b04204. Epub 2016 Jul 1.


Metal Nanoparticles Catalyzed Selective Carbon-Carbon Bond Activation in the Liquid Phase.

Ye R, Yuan B, Zhao J, Ralston WT, Wu CY, Unel Barin E, Toste FD, Somorjai GA.

J Am Chem Soc. 2016 Jul 13;138(27):8533-7. doi: 10.1021/jacs.6b03977. Epub 2016 Jun 29.


Isolation and Reactivity of Trifluoromethyl Iodonium Salts.

Brantley JN, Samant AV, Toste FD.

ACS Cent Sci. 2016 May 25;2(5):341-50. doi: 10.1021/acscentsci.6b00119. Epub 2016 May 13.

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