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Items: 1 to 50 of 103

1.

Mechanistic insights of anionic ligand exchange and fullerene reduction with magnesium(i) compounds.

Lawrence SR, Cordes DB, Slawin AMZ, Stasch A.

Dalton Trans. 2019 Dec 7;48(45):16936-16942. doi: 10.1039/c9dt03976g. Epub 2019 Nov 5.

PMID:
31687713
2.

Anion stabilised hypercloso-hexaalane Al6H6.

Bonyhady SJ, Collis D, Holzmann N, Edwards AJ, Piltz RO, Frenking G, Stasch A, Jones C.

Nat Commun. 2018 Aug 6;9(1):3079. doi: 10.1038/s41467-018-05504-x.

3.

Normal and abnormal NHC coordination in cationic hydride iodide complexes of aluminium.

Trose M, Burnett S, Bonyhady SJ, Jones C, Cordes DB, Slawin AMZ, Stasch A.

Dalton Trans. 2018 Jul 31;47(30):10281-10287. doi: 10.1039/c8dt01798k.

PMID:
30019047
4.

Reversible Insertion of a C═C Bond into Magnesium(I) Dimers: Generation of Highly Active 1,2-Dimagnesioethane Compounds.

Boutland AJ, Carroll A, Alvarez Lamsfus C, Stasch A, Maron L, Jones C.

J Am Chem Soc. 2017 Dec 20;139(50):18190-18193. doi: 10.1021/jacs.7b11368. Epub 2017 Dec 8.

PMID:
29206455
5.

PNacPNacE: (E = Ga, In, Tl) - monomeric group 13 metal(i) heterocycles stabilized by a sterically demanding bis(iminophosphoranyl)methanide.

Sindlinger CP, Lawrence SR, Acharya S, Ohlin CA, Stasch A.

Dalton Trans. 2017 Dec 12;46(48):16872-16877. doi: 10.1039/c7dt04048b.

PMID:
29188251
6.

Accessing Stable Magnesium Acyl Compounds: Reductive Cleavage of Esters by Magnesium(I) Dimers.

Boutland AJ, Lamsfus CA, Maitland B, Maron L, Stasch A, Jones C.

Chemistry. 2017 Oct 9;23(56):14049-14055. doi: 10.1002/chem.201703061. Epub 2017 Sep 6.

PMID:
28876495
7.

Highly Electron-Rich β-Diketiminato Systems: Synthesis and Coordination Chemistry of Amino-Functionalized "N-nacnac" Ligands.

Do DCH, Keyser A, Protchenko AV, Maitland B, Pernik I, Niu H, Kolychev EL, Rit A, Vidovic D, Stasch A, Jones C, Aldridge S.

Chemistry. 2017 Apr 27;23(24):5830-5841. doi: 10.1002/chem.201700757. Epub 2017 Apr 5.

PMID:
28256015
8.

Synthesis, Characterization, and Computational Analysis of the Dialanate Dianion, [H3 Al-AlH3 ]2- : A Valence Isoelectronic Analogue of Ethane.

Bonyhady SJ, Holzmann N, Frenking G, Stasch A, Jones C.

Angew Chem Int Ed Engl. 2017 Jul 10;56(29):8527-8531. doi: 10.1002/anie.201610601. Epub 2016 Dec 9.

PMID:
27936312
9.

Heavier Group 13 Metal(I) Heterocycles Stabilized by Sterically Demanding Diiminophosphinates: A Structurally Characterized Monomer-Dimer Pair For Gallium.

Hawley AL, Ohlin CA, Fohlmeister L, Stasch A.

Chemistry. 2017 Jan 5;23(2):447-455. doi: 10.1002/chem.201604495. Epub 2016 Dec 2.

PMID:
27813169
10.

Two-Coordinate Magnesium(I) Dimers Stabilized by Super Bulky Amido Ligands.

Boutland AJ, Dange D, Stasch A, Maron L, Jones C.

Angew Chem Int Ed Engl. 2016 Aug 1;55(32):9239-43. doi: 10.1002/anie.201604362. Epub 2016 Jun 15.

PMID:
27303934
11.

Ring-Shaped Phosphinoamido-Magnesium-Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis.

Fohlmeister L, Stasch A.

Chemistry. 2016 Jul 11;22(29):10235-46. doi: 10.1002/chem.201601623. Epub 2016 Jun 8.

PMID:
27271460
12.

Magnesium(I) Dimers Bearing Tripodal Diimine-Enolate Ligands: Proficient Reagents for the Controlled Reductive Activation of CO2 and SO2.

Boutland AJ, Pernik I, Stasch A, Jones C.

Chemistry. 2015 Oct 26;21(44):15749-58. doi: 10.1002/chem.201502755. Epub 2015 Sep 11.

PMID:
26358928
13.

A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination.

Sindlinger CP, Stasch A, Bettinger HF, Wesemann L.

Chem Sci. 2015 Aug 1;6(8):4737-4751. doi: 10.1039/c5sc01561h. Epub 2015 May 22.

14.

Activation of CO by Hydrogenated Magnesium(I) Dimers: Sterically Controlled Formation of Ethenediolate and Cyclopropanetriolate Complexes.

Lalrempuia R, Kefalidis CE, Bonyhady SJ, Schwarze B, Maron L, Stasch A, Jones C.

J Am Chem Soc. 2015 Jul 22;137(28):8944-7. doi: 10.1021/jacs.5b06439. Epub 2015 Jul 9.

PMID:
26135846
15.

A pyrazolate-stabilized sodium hydride complex.

Stasch A.

Chem Commun (Camb). 2015 Mar 25;51(24):5056-8. doi: 10.1039/c5cc00996k.

PMID:
25707859
16.

An extremely bulky tris(pyrazolyl)methanide: a tridentate ligand for the synthesis of heteroleptic magnesium(II) and ytterbium(II) alkyl, hydride, and iodide complexes.

Lalrempuia R, Stasch A, Jones C.

Chem Asian J. 2015 Feb;10(2):447-54. doi: 10.1002/asia.201403089. Epub 2014 Nov 12.

PMID:
25393525
17.

Platinum complexes containing pyramidalized germanium and tin dihalide ligands bound through σ,σ M=E multiple bonds.

Hupp F, Ma M, Kroll F, Jimenez-Halla JO, Dewhurst RD, Radacki K, Stasch A, Jones C, Braunschweig H.

Chemistry. 2014 Dec 15;20(51):16888-98. doi: 10.1002/chem.201404342. Epub 2014 Oct 30.

PMID:
25358255
18.

Mononuclear three-coordinate magnesium complexes of a highly sterically encumbered β-diketiminate ligand.

Arrowsmith M, Maitland B, Kociok-Köhn G, Stasch A, Jones C, Hill MS.

Inorg Chem. 2014 Oct 6;53(19):10543-52. doi: 10.1021/ic501638v. Epub 2014 Sep 9.

PMID:
25203490
19.

On the mechanism of the reaction of a magnesium(I) complex with CO₂: a concerted type of pathway.

Kefalidis CE, Stasch A, Jones C, Maron L.

Chem Commun (Camb). 2014 Oct 21;50(82):12318-21. doi: 10.1039/c4cc04984e.

PMID:
25182965
20.

Expanded ring N-heterocyclic carbene adducts of group 15 element trichlorides: synthesis and reduction studies.

Sidiropoulos A, Osborne B, Simonov AN, Dange D, Bond AM, Stasch A, Jones C.

Dalton Trans. 2014 Oct 21;43(39):14858-64. doi: 10.1039/c4dt02074j.

PMID:
25166429
21.

Synthesis of a dimeric magnesium(I) compound by an Mg(I)/Mg(II) redox reaction.

Stasch A.

Angew Chem Int Ed Engl. 2014 Sep 15;53(38):10200-3. doi: 10.1002/anie.201404284. Epub 2014 Jul 22.

PMID:
25047459
22.

Syntheses, structures and flexible coordination of sterically demanding di- and "tri"-lithiated methandiides.

Sindlinger CP, Stasch A.

Dalton Trans. 2014 Oct 14;43(38):14334-45. doi: 10.1039/c4dt01185f.

PMID:
24898367
23.

Reactivity studies of a soluble LiH-complex and non-spectator behaviour of its stabilising phosphinoamide ligand.

Stasch A.

Dalton Trans. 2014 May 21;43(19):7078-86. doi: 10.1039/c3dt52140k. Epub 2014 Mar 25.

PMID:
24668322
24.

Well-defined, nanometer-sized LiH cluster compounds stabilized by pyrazolate ligands.

Stasch A.

Angew Chem Int Ed Engl. 2014 Jan 27;53(5):1338-41. doi: 10.1002/anie.201308935. Epub 2013 Dec 13.

PMID:
24338951
25.

The facile assembly of bis-, tris- and poly(triazaphosphole) systems using "click" chemistry.

Choong SL, Nafady A, Stasch A, Bond AM, Jones C.

Dalton Trans. 2013 Jun 7;42(21):7775-80. doi: 10.1039/c3dt50505g.

PMID:
23549302
26.

Comparative study of phosphine and N-heterocyclic carbene stabilized Group 13 adducts [L(EH3)] and [L2(E2H(n))].

Holzmann N, Stasch A, Jones C, Frenking G.

Chemistry. 2013 May 10;19(20):6467-79. doi: 10.1002/chem.201203679. Epub 2013 Mar 19.

PMID:
23512819
27.

Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds.

Ma M, Sidiropoulos A, Ralte L, Stasch A, Jones C.

Chem Commun (Camb). 2013 Jan 4;49(1):48-50. doi: 10.1039/c2cc37442k. Epub 2012 Nov 14.

PMID:
23149548
28.

Synthesis, structure, and reactivity of a dimeric zinc(I) compound stabilized by a sterically demanding diiminophosphinate ligand.

Stasch A.

Chemistry. 2012 Nov 19;18(47):15105-12. doi: 10.1002/chem.201202560. Epub 2012 Oct 5.

PMID:
23042426
29.

An N-heterocyclic carbene adduct of diatomic tin, :Sn=Sn:.

Jones C, Sidiropoulos A, Holzmann N, Frenking G, Stasch A.

Chem Commun (Camb). 2012 Oct 11;48(79):9855-7. doi: 10.1039/c2cc35228a. Epub 2012 Aug 29.

PMID:
22933046
30.

Magnesium(I) dimers as reagents for the reductive coupling of isonitriles and nitriles.

Ma M, Stasch A, Jones C.

Chemistry. 2012 Aug 20;18(34):10669-76. doi: 10.1002/chem.201201030. Epub 2012 Jul 11.

PMID:
22786624
31.

Low-coordinate iron(I) and manganese(I) dimers: kinetic stabilization of an exceptionally short Fe-Fe multiple bond.

Fohlmeister L, Liu S, Schulten C, Moubaraki B, Stasch A, Cashion JD, Murray KS, Gagliardi L, Jones C.

Angew Chem Int Ed Engl. 2012 Aug 13;51(33):8294-8. doi: 10.1002/anie.201203711. Epub 2012 Jul 9. No abstract available.

PMID:
22778063
32.

Synthesis and characterisation of anionic and neutral gallium(I) N-heterocyclic carbene analogues.

Dange D, Choong SL, Schenk C, Stasch A, Jones C.

Dalton Trans. 2012 Aug 21;41(31):9304-15. doi: 10.1039/c2dt30299c. Epub 2012 Apr 26.

PMID:
22539449
33.

Contrasting reductions of group 14 metal(II) chloride complexes: synthesis of a β-diketiminato tin(I) dimer.

Choong SL, Schenk C, Stasch A, Dange D, Jones C.

Chem Commun (Camb). 2012 Mar 4;48(19):2504-6. doi: 10.1039/c2cc18086c. Epub 2012 Jan 26.

PMID:
22281528
34.

A hydrocarbon-soluble lithium hydride complex.

Stasch A.

Angew Chem Int Ed Engl. 2012 Feb 20;51(8):1930-3. doi: 10.1002/anie.201108134. Epub 2012 Jan 13. No abstract available.

PMID:
22241821
35.

Synthetic and quantum mechanical studies into the N-heterocyclic carbene catalyzed (4 + 2) cycloaddition.

Ryan SJ, Stasch A, Paddon-Row MN, Lupton DW.

J Org Chem. 2012 Jan 20;77(2):1113-24. doi: 10.1021/jo202500k. Epub 2012 Jan 6.

PMID:
22148247
36.
37.

Extremely bulky amido-group 14 element chloride complexes: potential synthons for low oxidation state main group chemistry.

Li J, Stasch A, Schenk C, Jones C.

Dalton Trans. 2011 Oct 28;40(40):10448-56. doi: 10.1039/c1dt10678c. Epub 2011 Jul 4.

PMID:
21725555
38.

A neutral, monomeric germanium(I) radical.

Woodul WD, Carter E, Müller R, Richards AF, Stasch A, Kaupp M, Murphy DM, Driess M, Jones C.

J Am Chem Soc. 2011 Jul 6;133(26):10074-7. doi: 10.1021/ja204344e. Epub 2011 Jun 15.

PMID:
21662245
39.

Preparation, characterization, and theoretical analysis of group 14 element(I) dimers: a case study of magnesium(I) compounds as reducing agents in inorganic synthesis.

Jones C, Bonyhady SJ, Holzmann N, Frenking G, Stasch A.

Inorg Chem. 2011 Dec 19;50(24):12315-25. doi: 10.1021/ic200682p. Epub 2011 May 6.

PMID:
21548564
40.

Stable dimeric magnesium(I) compounds: from chemical landmarks to versatile reagents.

Stasch A, Jones C.

Dalton Trans. 2011 Jun 7;40(21):5659-72. doi: 10.1039/c0dt01831g. Epub 2011 Mar 9.

PMID:
21390353
41.

A CW-EPR, ENDOR and special TRIPLE resonance study of a novel magnesium ketyl radical.

Murphy DM, McDyre LE, Carter E, Stasch A, Jones C.

Magn Reson Chem. 2011 Apr;49(4):159-63. doi: 10.1002/mrc.2721. Epub 2011 Jan 18.

PMID:
21243724
42.

Bulky guanidinato nickel(I) complexes: synthesis, characterization, isomerization, and reactivity studies.

Jones C, Schulten C, Fohlmeister L, Stasch A, Murray KS, Moubaraki B, Kohl S, Ertem MZ, Gagliardi L, Cramer CJ.

Chemistry. 2011 Jan 24;17(4):1294-303. doi: 10.1002/chem.201002388. Epub 2010 Nov 30.

PMID:
21243697
43.

First experimental characterization of a non-nuclear attractor in a dimeric magnesium(I) compound.

Platts JA, Overgaard J, Jones C, Iversen BB, Stasch A.

J Phys Chem A. 2011 Jan 20;115(2):194-200. doi: 10.1021/jp109547w. Epub 2010 Dec 15.

PMID:
21158464
44.

Synthesis of a stable adduct of dialane(4) (Al2H4) via hydrogenation of a magnesium(I) dimer.

Bonyhady SJ, Collis D, Frenking G, Holzmann N, Jones C, Stasch A.

Nat Chem. 2010 Oct;2(10):865-9. doi: 10.1038/nchem.762. Epub 2010 Aug 1.

PMID:
20861903
45.

Bulky guanidinato and amidinato zinc complexes and their comparative stabilities.

Jones C, Furness L, Nembenna S, Rose RP, Aldridge S, Stasch A.

Dalton Trans. 2010 Oct 7;39(37):8788-95. doi: 10.1039/c0dt00589d. Epub 2010 Aug 12.

PMID:
20714636
46.

Low coordinate lanthanide(II) complexes supported by bulky guanidinato and amidinato ligands.

Heitmann D, Jones C, Mills DP, Stasch A.

Dalton Trans. 2010 Feb 21;39(7):1877-82. doi: 10.1039/b924367d. Epub 2010 Jan 7.

PMID:
20449435
47.

Using "click" chemistry to access a new class of tripodal P3-ligand containing P=C bonds.

Choong SL, Jones C, Stasch A.

Dalton Trans. 2010 Jul 7;39(25):5774-6. doi: 10.1039/c002940h. Epub 2010 Apr 8.

PMID:
20379598
48.

Magnesium(I) reduction of benzophenone and anthracene: first structural characterisation of a magnesium ketyl.

Jones C, McDyre L, Murphy DM, Stasch A.

Chem Commun (Camb). 2010 Mar 7;46(9):1511-3. doi: 10.1039/b922002j. Epub 2009 Dec 23.

PMID:
20162165
49.

Beta-diketiminate-stabilized magnesium(I) dimers and magnesium(II) hydride complexes: synthesis, characterization, adduct formation, and reactivity studies.

Bonyhady SJ, Jones C, Nembenna S, Stasch A, Edwards AJ, McIntyre GJ.

Chemistry. 2010 Jan 18;16(3):938-55. doi: 10.1002/chem.200902425.

PMID:
19950340
50.

N-heterocyclic carbene stabilized digermanium(0).

Sidiropoulos A, Jones C, Stasch A, Klein S, Frenking G.

Angew Chem Int Ed Engl. 2009;48(51):9701-4. doi: 10.1002/anie.200905495. No abstract available.

PMID:
19921732

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