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Items: 1 to 50 of 52

1.

Multivalent Cluster Nanomolecules for Inhibiting Protein-Protein Interactions.

Qian EA, Han Y, Messina MS, Maynard HD, Král P, Spokoyny AM.

Bioconjug Chem. 2019 Sep 9. doi: 10.1021/acs.bioconjchem.9b00526. [Epub ahead of print]

PMID:
31498600
2.

Improved synthesis of icosahedral carboranes containing exopolyhedral B-C and C-C bonds.

Anderson KP, Mills HA, Mao C, Kirlikovali KO, Axtell JC, Rheingold AL, Spokoyny AM.

Tetrahedron. 2019 Jan 11;75(2):187-191. doi: 10.1016/j.tet.2018.11.040. Epub 2018 Nov 28.

PMID:
31303685
3.

Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions.

Axtell JC, Messina MS, Liu JY, Galaktionova D, Schwan J, Porter TM, Savage MD, Wixtrom AI, Rheingold AL, Kubiak CP, Winkler JR, Gray HB, Král P, Alexandrova AN, Spokoyny AM.

Inorg Chem. 2019 Aug 19;58(16):10516-10526. doi: 10.1021/acs.inorgchem.9b00935. Epub 2019 Jun 25.

PMID:
31247818
4.

Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents.

Jung D, Raffan-Montoya F, Ramachandran R, Zhang Y, Islamoglu T, Marin G, Qian EA, Dziedzic RM, Farha OK, Stoliarov SI, Spokoyny AM.

Chem Commun (Camb). 2019 Jul 23;55(60):8852-8855. doi: 10.1039/c9cc03350e.

PMID:
31187812
5.

"Mr. Boron", an Inorganic Chemistry Icon, Turns 90.

Spokoyny AM, Chiu CW, Bosley BD, Schubert DM.

Inorg Chem. 2019 May 6;58(9):5369-5374. doi: 10.1021/acs.inorgchem.9b00913. Epub 2019 Apr 22. No abstract available.

PMID:
31007023
6.

Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1'-bis(o-carborane) backbone.

Yruegas S, Axtell JC, Kirlikovali KO, Spokoyny AM, Martin CD.

Chem Commun (Camb). 2019 Mar 5;55(20):2892-2895. doi: 10.1039/c8cc10087j.

PMID:
30706915
7.

Dodecaborane-Based Dopants Designed to Shield Anion Electrostatics Lead to Increased Carrier Mobility in a Doped Conjugated Polymer.

Aubry TJ, Axtell JC, Basile VM, Winchell KJ, Lindemuth JR, Porter TM, Liu JY, Alexandrova AN, Kubiak CP, Tolbert SH, Spokoyny AM, Schwartz BJ.

Adv Mater. 2019 Mar;31(11):e1805647. doi: 10.1002/adma.201805647. Epub 2019 Jan 23.

PMID:
30672037
8.

Metal-catalyzed cross-coupling chemistry with polyhedral boranes.

Dziedzic RM, Spokoyny AM.

Chem Commun (Camb). 2019 Jan 3;55(4):430-442. doi: 10.1039/c8cc08693a.

PMID:
30525176
9.

Arylation Chemistry for Bioconjugation.

Zhang C, Vinogradova EV, Spokoyny AM, Buchwald SL, Pentelute BL.

Angew Chem Int Ed Engl. 2019 Apr 1;58(15):4810-4839. doi: 10.1002/anie.201806009. Epub 2019 Feb 15. Review.

PMID:
30399206
10.

Sonochemical Synthesis of Small Boron Oxide Nanoparticles.

Ramachandran R, Jung D, Bernier NA, Logan JK, Waddington MA, Spokoyny AM.

Inorg Chem. 2018 Jul 16;57(14):8037-8041. doi: 10.1021/acs.inorgchem.8b01189. Epub 2018 Jun 25.

11.

Organometallic Gold(III) Reagents for Cysteine Arylation.

Messina MS, Stauber JM, Waddington MA, Rheingold AL, Maynard HD, Spokoyny AM.

J Am Chem Soc. 2018 Jun 13;140(23):7065-7069. doi: 10.1021/jacs.8b04115. Epub 2018 May 30.

12.

Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation.

Wixtrom AI, Parvez ZA, Savage MD, Qian EA, Jung D, Khan SI, Rheingold AL, Spokoyny AM.

Chem Commun (Camb). 2018 Jun 5;54(46):5867-5870. doi: 10.1039/c8cc03477j.

13.

Publisher Correction: A molecular cross-linking approach for hybrid metal oxides.

Jung D, Saleh LMA, Berkson ZJ, El-Kady MF, Hwang JY, Mohamed N, Wixtrom AI, Titarenko E, Shao Y, McCarthy K, Guo J, Martini IB, Kraemer S, Wegener EC, Saint-Cricq P, Ruehle B, Langeslay RR, Delferro M, Brosmer JL, Hendon CH, Gallagher-Jones M, Rodriguez J, Chapman KW, Miller JT, Duan X, Kaner RB, Zink JI, Chmelka BF, Spokoyny AM.

Nat Mater. 2018 Apr;17(4):369. doi: 10.1038/s41563-018-0054-0.

PMID:
29549301
14.

A molecular cross-linking approach for hybrid metal oxides.

Jung D, Saleh LMA, Berkson ZJ, El-Kady MF, Hwang JY, Mohamed N, Wixtrom AI, Titarenko E, Shao Y, McCarthy K, Guo J, Martini IB, Kraemer S, Wegener EC, Saint-Cricq P, Ruehle B, Langeslay RR, Delferro M, Brosmer JL, Hendon CH, Gallagher-Jones M, Rodriguez J, Chapman KW, Miller JT, Duan X, Kaner RB, Zink JI, Chmelka BF, Spokoyny AM.

Nat Mater. 2018 Apr;17(4):341-348. doi: 10.1038/s41563-018-0021-9. Epub 2018 Mar 5. Erratum in: Nat Mater. 2018 Mar 16;:.

PMID:
29507417
15.

Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests.

Kung CW, Otake K, Buru CT, Goswami S, Cui Y, Hupp JT, Spokoyny AM, Farha OK.

J Am Chem Soc. 2018 Mar 21;140(11):3871-3875. doi: 10.1021/jacs.8b00605. Epub 2018 Mar 12.

PMID:
29502408
16.

Synthesis and Applications of Perfunctionalized Boron Clusters.

Axtell JC, Saleh LMA, Qian EA, Wixtrom AI, Spokoyny AM.

Inorg Chem. 2018 Mar 5;57(5):2333-2350. doi: 10.1021/acs.inorgchem.7b02912. Epub 2018 Feb 21.

17.

Buchwald-Hartwig amination using Pd(i) dimer precatalysts supported by biaryl phosphine ligands.

Kirlikovali KO, Cho E, Downard TJ, Grigoryan L, Han Z, Hong S, Jung D, Quintana JC, Reynoso V, Ro S, Shen Y, Swartz K, Ter Sahakyan E, Wixtrom AI, Yoshida B, Rheingold AL, Spokoyny AM.

Dalton Trans. 2018 Mar 12;47(11):3684-3688. doi: 10.1039/c8dt00119g.

PMID:
29464254
18.

Reversible Silver Electrodeposition from Boron Cluster Ionic Liquid (BCIL) Electrolytes.

Dziedzic RM, Waddington MA, Lee SE, Kleinsasser J, Plumley JB, Ewing WC, Bosley BD, Lavallo V, Peng TL, Spokoyny AM.

ACS Appl Mater Interfaces. 2018 Feb 28;10(8):6825-6830. doi: 10.1021/acsami.7b19302. Epub 2018 Feb 16.

PMID:
29405694
19.

Work Function Control of Germanium through Carborane-Carboxylic Acid Surface Passivation.

Serino AC, Anderson ME, Saleh LMA, Dziedzic RM, Mills H, Heidenreich LK, Spokoyny AM, Weiss PS.

ACS Appl Mater Interfaces. 2017 Oct 11;9(40):34592-34596. doi: 10.1021/acsami.7b10596. Epub 2017 Oct 2.

PMID:
28920673
20.

Cage-Walking: Vertex Differentiation by Palladium-Catalyzed Isomerization of B(9)-Bromo-meta-Carborane.

Dziedzic RM, Martin JL, Axtell JC, Saleh LMA, Ong TC, Yang YF, Messina MS, Rheingold AL, Houk KN, Spokoyny AM.

J Am Chem Soc. 2017 Jun 14;139(23):7729-7732. doi: 10.1021/jacs.7b04080. Epub 2017 Jun 1.

PMID:
28541671
21.

Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistry.

Qian EA, Wixtrom AI, Axtell JC, Saebi A, Jung D, Rehak P, Han Y, Moully EH, Mosallaei D, Chow S, Messina MS, Wang JY, Royappa AT, Rheingold AL, Maynard HD, Král P, Spokoyny AM.

Nat Chem. 2017 Apr;9(4):333-340. doi: 10.1038/nchem.2686. Epub 2016 Dec 19.

22.

Luminescent Metal Complexes Featuring Photophysically Innocent Boron Cluster Ligands.

Kirlikovali KO, Axtell JC, Gonzalez A, Phung AC, Khan SI, Spokoyny AM.

Chem Sci. 2016 Aug 1;7(8):5132-5138. doi: 10.1039/C6SC01146B. Epub 2016 Apr 27.

23.

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands.

Axtell JC, Kirlikovali KO, Djurovich PI, Jung D, Nguyen VT, Munekiyo B, Royappa AT, Rheingold AL, Spokoyny AM.

J Am Chem Soc. 2016 Dec 7;138(48):15758-15765. Epub 2016 Nov 22.

PMID:
27934013
24.

Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions.

Wixtrom AI, Shao Y, Jung D, Machan CW, Kevork SN, Qian EA, Axtell JC, Khan SI, Kubiak CP, Spokoyny AM.

Inorg Chem Front. 2016 May 1;3(5):711-717. Epub 2016 Mar 3.

25.

An Inorganic Twist in Nanomaterials: Making an Atomically Precise Double Helix.

Saleh LM, Dziedzic R, Spokoyny AM.

ACS Cent Sci. 2016 Oct 26;2(10):685-686. Epub 2016 Oct 18. No abstract available.

26.

B-N, B-O, and B-CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B-Bromo-Carboranes.

Dziedzic RM, Saleh LM, Axtell JC, Martin JL, Stevens SL, Royappa AT, Rheingold AL, Spokoyny AM.

J Am Chem Soc. 2016 Jul 27;138(29):9081-4. doi: 10.1021/jacs.6b05505. Epub 2016 Jul 13.

PMID:
27384544
27.

Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants.

Messina MS, Axtell JC, Wang Y, Chong P, Wixtrom AI, Kirlikovali KO, Upton BM, Hunter BM, Shafaat OS, Khan SI, Winkler JR, Gray HB, Alexandrova AN, Maynard HD, Spokoyny AM.

J Am Chem Soc. 2016 Jun 8;138(22):6952-5. doi: 10.1021/jacs.6b03568. Epub 2016 May 26.

28.

Surface Dipole Control of Liquid Crystal Alignment.

Schwartz JJ, Mendoza AM, Wattanatorn N, Zhao Y, Nguyen VT, Spokoyny AM, Mirkin CA, Baše T, Weiss PS.

J Am Chem Soc. 2016 May 11;138(18):5957-67. doi: 10.1021/jacs.6b02026. Epub 2016 May 2.

29.

Forging Unsupported Metal-Boryl Bonds with Icosahedral Carboranes.

Saleh LM, Dziedzic RM, Khan SI, Spokoyny AM.

Chemistry. 2016 Jun 13;22(25):8466-70. doi: 10.1002/chem.201601292. Epub 2016 May 9.

PMID:
27017293
30.

Organometallic palladium reagents for cysteine bioconjugation.

Vinogradova EV, Zhang C, Spokoyny AM, Pentelute BL, Buchwald SL.

Nature. 2015 Oct 29;526(7575):687-91. doi: 10.1038/nature15739.

31.

Defect-Tolerant Aligned Dipoles within Two-Dimensional Plastic Lattices.

Thomas JC, Schwartz JJ, Hohman JN, Claridge SA, Auluck HS, Serino AC, Spokoyny AM, Tran G, Kelly KF, Mirkin CA, Gilles J, Osher SJ, Weiss PS.

ACS Nano. 2015 May 26;9(5):4734-42. doi: 10.1021/acsnano.5b01329. Epub 2015 Apr 17.

32.

Enzyme-catalyzed macrocyclization of long unprotected peptides.

Zhang C, Dai P, Spokoyny AM, Pentelute BL.

Org Lett. 2014 Jul 18;16(14):3652-5. doi: 10.1021/ol501609y. Epub 2014 Jul 8.

33.

Rapid flow-based peptide synthesis.

Simon MD, Heider PL, Adamo A, Vinogradov AA, Mong SK, Li X, Berger T, Policarpo RL, Zhang C, Zou Y, Liao X, Spokoyny AM, Jensen KF, Pentelute BL.

Chembiochem. 2014 Mar 21;15(5):713-20. doi: 10.1002/cbic.201300796. Epub 2014 Mar 11.

34.

New ligand platforms featuring boron-rich clusters as organomimetic substituents.

Spokoyny AM.

Pure Appl Chem. 2013 May;85(5). doi: 10.1351/PAC-CON-13-01-13.

35.

Convergent diversity-oriented side-chain macrocyclization scan for unprotected polypeptides.

Zou Y, Spokoyny AM, Zhang C, Simon MD, Yu H, Lin YS, Pentelute BL.

Org Biomol Chem. 2014 Jan 28;12(4):566-73. doi: 10.1039/c3ob42168f.

36.

Enzymatic "click" ligation: selective cysteine modification in polypeptides enabled by promiscuous glutathione S-transferase.

Zhang C, Spokoyny AM, Zou Y, Simon MD, Pentelute BL.

Angew Chem Int Ed Engl. 2013 Dec 23;52(52):14001-5. doi: 10.1002/anie.201306430. Epub 2013 Nov 12. No abstract available.

37.

Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes.

Spokoyny AM, Lewis CD, Teverovskiy G, Buchwald SL.

Organometallics. 2012 Dec 24;31(24):8478-8481.

38.

Boron-dipyrromethene-functionalized hemilabile ligands as "turn-on" fluorescent probes for coordination changes in weak-link approach complexes.

Lifschitz AM, Shade CM, Spokoyny AM, Mendez-Arroyo J, Stern CL, Sarjeant AA, Mirkin CA.

Inorg Chem. 2013 May 6;52(9):5484-92. doi: 10.1021/ic400383t. Epub 2013 Apr 9.

PMID:
23570551
39.

A perfluoroaryl-cysteine S(N)Ar chemistry approach to unprotected peptide stapling.

Spokoyny AM, Zou Y, Ling JJ, Yu H, Lin YS, Pentelute BL.

J Am Chem Soc. 2013 Apr 24;135(16):5946-9. doi: 10.1021/ja400119t. Epub 2013 Apr 16.

40.

A coordination chemistry dichotomy for icosahedral carborane-based ligands.

Spokoyny AM, Machan CW, Clingerman DJ, Rosen MS, Wiester MJ, Kennedy RD, Stern CL, Sarjeant AA, Mirkin CA.

Nat Chem. 2011 Jul 22;3(8):590-6. doi: 10.1038/nchem.1088.

PMID:
21778977
41.

Plasticity of the nickel(II) coordination environment in complexes with hemilabile phosphino thioether ligands.

Machan CW, Spokoyny AM, Jones MR, Sarjeant AA, Stern CL, Mirkin CA.

J Am Chem Soc. 2011 Mar 9;133(9):3023-33. doi: 10.1021/ja109624m. Epub 2011 Feb 14.

PMID:
21319748
42.

Chelating effect as a driving force for the selective formation of heteroligated Pt(II) complexes with bidentate phosphino-chalcoether ligands.

Rosen MS, Spokoyny AM, Machan CW, Stern C, Sarjeant A, Mirkin CA.

Inorg Chem. 2011 Feb 21;50(4):1411-9. doi: 10.1021/ic101973s. Epub 2010 Dec 28.

43.

Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells.

Spokoyny AM, Li TC, Farha OK, Machan CW, She C, Stern CL, Marks TJ, Hupp JT, Mirkin CA.

Angew Chem Int Ed Engl. 2010 Jul 19;49(31):5339-43. doi: 10.1002/anie.201002181. No abstract available.

PMID:
20586090
44.

Separation of gas mixtures using Co(II) carborane-based porous coordination polymers.

Bae YS, Spokoyny AM, Farha OK, Snurr RQ, Hupp JT, Mirkin CA.

Chem Commun (Camb). 2010 May 28;46(20):3478-80. doi: 10.1039/b927499e. Epub 2010 Apr 19.

PMID:
20405064
45.

Ni(III)/(IV) bis(dicarbollide) as a fast, noncorrosive redox shuttle for dye-sensitized solar cells.

Li TC, Spokoyny AM, She C, Farha OK, Mirkin CA, Marks TJ, Hupp JT.

J Am Chem Soc. 2010 Apr 7;132(13):4580-2. doi: 10.1021/ja100396n. Erratum in: J Am Chem Soc. 2011 Apr 13;133(14):5620.

PMID:
20230034
46.

Chemical reduction of a diimide based porous polymer for selective uptake of carbon dioxide versus methane.

Farha OK, Bae YS, Hauser BG, Spokoyny AM, Snurr RQ, Mirkin CA, Hupp JT.

Chem Commun (Camb). 2010 Feb 21;46(7):1056-8. doi: 10.1039/b922554d. Epub 2010 Jan 15.

PMID:
20126711
47.
48.

Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes.

Spokoyny AM, Reuter MG, Stern CL, Ratner MA, Seideman T, Mirkin CA.

J Am Chem Soc. 2009 Jul 15;131(27):9482-3. doi: 10.1021/ja902526k.

49.

Infinite coordination polymer nano- and microparticle structures.

Spokoyny AM, Kim D, Sumrein A, Mirkin CA.

Chem Soc Rev. 2009 May;38(5):1218-27. doi: 10.1039/b807085g. Epub 2009 Feb 27.

PMID:
19384433
50.

Gas-sorption properties of cobalt(II)--carborane-based coordination polymers as a function of morphology.

Farha OK, Spokoyny AM, Mulfort KL, Galli S, Hupp JT, Mirkin CA.

Small. 2009 Aug 3;5(15):1727-31. doi: 10.1002/smll.200900085. No abstract available.

PMID:
19367598

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