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Items: 12

1.

Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear PdI Catalysis.

Chen XY, Pu M, Cheng HG, Sperger T, Schoenebeck F.

Angew Chem Int Ed Engl. 2019 Jun 13. doi: 10.1002/anie.201906063. [Epub ahead of print]

PMID:
31190467
2.

E-Olefins through intramolecular radical relocation.

Kapat A, Sperger T, Guven S, Schoenebeck F.

Science. 2019 Jan 25;363(6425):391-396. doi: 10.1126/science.aav1610.

PMID:
30679370
3.

Chemoselective Pd-Catalyzed C-TeCF3 Coupling of Aryl Iodides.

Sperger T, Guven S, Schoenebeck F.

Angew Chem Int Ed Engl. 2018 Dec 17;57(51):16903-16906. doi: 10.1002/anie.201810950. Epub 2018 Nov 20.

PMID:
30346648
4.

Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air.

Kalvet I, Sperger T, Scattolin T, Magnin G, Schoenebeck F.

Angew Chem Int Ed Engl. 2017 Jun 12;56(25):7078-7082. doi: 10.1002/anie.201701691. Epub 2017 May 16.

5.

Mechanistic insights on the Pd-catalyzed addition of C-X bonds across alkynes - a combined experimental and computational study.

Sperger T, Le CM, Lautens M, Schoenebeck F.

Chem Sci. 2017 Apr 1;8(4):2914-2922. doi: 10.1039/c6sc05001h. Epub 2017 Jan 27.

6.

Remote C-H alkylation and C-C bond cleavage enabled by an in situ generated palladacycle.

Ye J, Shi Z, Sperger T, Yasukawa Y, Kingston C, Schoenebeck F, Lautens M.

Nat Chem. 2017 Apr;9(4):361-368. doi: 10.1038/nchem.2631. Epub 2016 Oct 17.

PMID:
28338687
7.

Understanding the Unusual Reduction Mechanism of Pd(II) to Pd(I): Uncovering Hidden Species and Implications in Catalytic Cross-Coupling Reactions.

Johansson Seechurn CCC, Sperger T, Scrase TG, Schoenebeck F, Colacot TJ.

J Am Chem Soc. 2017 Apr 12;139(14):5194-5200. doi: 10.1021/jacs.7b01110. Epub 2017 Apr 3.

PMID:
28300400
8.

Stereoselective Synthesis of Methylene Oxindoles via Palladium(II)-Catalyzed Intramolecular Cross-Coupling of Carbamoyl Chlorides.

Le CM, Sperger T, Fu R, Hou X, Lim YH, Schoenebeck F, Lautens M.

J Am Chem Soc. 2016 Nov 2;138(43):14441-14448. Epub 2016 Oct 20.

PMID:
27700076
9.

Computation and Experiment: A Powerful Combination to Understand and Predict Reactivities.

Sperger T, Sanhueza IA, Schoenebeck F.

Acc Chem Res. 2016 Jun 21;49(6):1311-9. doi: 10.1021/acs.accounts.6b00068. Epub 2016 May 12.

PMID:
27171796
10.

An Exclusively trans-Selective Chlorocarbamoylation of Alkynes Enabled by a Palladium/Phosphaadamantane Catalyst.

Le CM, Hou X, Sperger T, Schoenebeck F, Lautens M.

Angew Chem Int Ed Engl. 2015 Dec 21;54(52):15897-900. doi: 10.1002/anie.201507883. Epub 2015 Nov 20.

PMID:
26585593
11.

Computational Studies of Synthetically Relevant Homogeneous Organometallic Catalysis Involving Ni, Pd, Ir, and Rh: An Overview of Commonly Employed DFT Methods and Mechanistic Insights.

Sperger T, Sanhueza IA, Kalvet I, Schoenebeck F.

Chem Rev. 2015 Sep 9;115(17):9532-86. doi: 10.1021/acs.chemrev.5b00163. Epub 2015 Jul 24. No abstract available.

PMID:
26207572
12.

Highly Efficient C-SeCF3 Coupling of Aryl Iodides Enabled by an Air-Stable Dinuclear Pd(I) Catalyst.

Aufiero M, Sperger T, Tsang AS, Schoenebeck F.

Angew Chem Int Ed Engl. 2015 Aug 24;54(35):10322-6. doi: 10.1002/anie.201503388. Epub 2015 Jun 26.

PMID:
26118426

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