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Items: 1 to 50 of 166

1.

Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates".

Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD.

J Am Chem Soc. 2019 Sep 17. doi: 10.1021/jacs.9b09747. [Epub ahead of print] No abstract available.

PMID:
31525919
2.

Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery.

Yan Y, Robinson SG, Sigman MS, Sanford MS.

J Am Chem Soc. 2019 Sep 10. doi: 10.1021/jacs.9b07345. [Epub ahead of print]

PMID:
31503480
3.

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms.

Sandford C, Edwards MA, Klunder KJ, Hickey DP, Li M, Barman K, Sigman MS, White HS, Minteer SD.

Chem Sci. 2019 May 23;10(26):6404-6422. doi: 10.1039/c9sc01545k. eCollection 2019 Jul 14. Review.

4.

A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation.

Christian AH, Jia S, Cao W, Zhang P, Meza AT, Sigman MS, Chang CJ, Toste FD.

J Am Chem Soc. 2019 Aug 14;141(32):12657-12662. doi: 10.1021/jacs.9b04744. Epub 2019 Jul 30.

PMID:
31361488
5.

Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction".

Allen JR, Bahamonde A, Furukawa Y, Sigman MS.

J Am Chem Soc. 2019 Aug 7;141(31):12420. doi: 10.1021/jacs.9b07380. Epub 2019 Jul 26. No abstract available.

PMID:
31347841
6.

Holistic prediction of enantioselectivity in asymmetric catalysis.

Reid JP, Sigman MS.

Nature. 2019 Jul;571(7765):343-348. doi: 10.1038/s41586-019-1384-z. Epub 2019 Jul 17.

PMID:
31316193
7.

Enantioselective construction of remote tertiary carbon-fluorine bonds.

Liu J, Yuan Q, Toste FD, Sigman MS.

Nat Chem. 2019 Aug;11(8):710-715. doi: 10.1038/s41557-019-0289-7. Epub 2019 Jul 15.

PMID:
31308495
8.

Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

Crawford JM, Sigman MS.

Synthesis (Stuttg). 2019 Mar;51(5):1021-1036. doi: 10.1055/s-0037-1611636. Epub 2019 Jan 8.

9.

Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy.

Yuan Q, Sigman MS.

Chemistry. 2019 Aug 14;25(46):10823-10827. doi: 10.1002/chem.201902813. Epub 2019 Jul 26.

10.

Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes.

Robinson SG, Yan Y, Hendriks KH, Sanford MS, Sigman MS.

J Am Chem Soc. 2019 Jul 3;141(26):10171-10176. doi: 10.1021/jacs.9b04270. Epub 2019 Jun 20.

PMID:
31203608
11.

Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis.

Ferreira MAB, De Jesus Silva J, Grosslight S, Fedorov A, Sigman MS, Copéret C.

J Am Chem Soc. 2019 Jul 10;141(27):10788-10800. doi: 10.1021/jacs.9b04367. Epub 2019 Jun 27.

PMID:
31180674
12.

Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines.

Bahamonde A, Al Rifaie B, Martín-Heras V, Allen JR, Sigman MS.

J Am Chem Soc. 2019 Jun 5;141(22):8708-8711. doi: 10.1021/jacs.9b03438. Epub 2019 May 24.

13.

Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction.

Allen JR, Bahamonde A, Furukawa Y, Sigman MS.

J Am Chem Soc. 2019 Jun 5;141(22):8670-8674. doi: 10.1021/jacs.9b01476. Epub 2019 May 24. Erratum in: J Am Chem Soc. 2019 Aug 7;141(31):12420.

14.

Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration.

Kwon Y, Li J, Reid JP, Crawford JM, Jacob R, Sigman MS, Toste FD, Miller SJ.

J Am Chem Soc. 2019 Apr 24;141(16):6698-6705. doi: 10.1021/jacs.9b01911. Epub 2019 Apr 10.

PMID:
30920223
15.

Rapid chemiexcitation of phenoxy-dioxetane luminophores yields ultrasensitive chemiluminescence assays.

Hananya N, Reid JP, Green O, Sigman MS, Shabat D.

Chem Sci. 2018 Nov 19;10(5):1380-1385. doi: 10.1039/c8sc04280b. eCollection 2019 Feb 7.

16.

Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest.

Mack JBC, Walker KL, Robinson SG, Zare RN, Sigman MS, Waymouth RM, Du Bois J.

J Am Chem Soc. 2019 Jan 16;141(2):972-980. doi: 10.1021/jacs.8b10950. Epub 2019 Jan 2.

PMID:
30601662
17.

Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates.

Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD.

J Am Chem Soc. 2019 Jan 23;141(3):1382-1392. doi: 10.1021/jacs.8b12634. Epub 2019 Jan 11. Erratum in: J Am Chem Soc. 2019 Sep 17;:.

PMID:
30599130
18.

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles.

Albright H, Riehl PS, McAtee CC, Reid JP, Ludwig JR, Karp LA, Zimmerman PM, Sigman MS, Schindler CS.

J Am Chem Soc. 2019 Jan 30;141(4):1690-1700. doi: 10.1021/jacs.8b11840. Epub 2019 Jan 16.

PMID:
30596414
19.

A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A.

Vaden RM, Guillen KP, Salvant JM, Santiago CB, Gibbons JB, Pathi SS, Arunachalam S, Sigman MS, Looper RE, Welm BE.

ACS Chem Biol. 2019 Jan 18;14(1):106-117. doi: 10.1021/acschembio.8b00977. Epub 2019 Jan 8.

PMID:
30571086
20.

Correction to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes".

Engl PS, Santiago CB, Gordon CP, Liao WC, Fedorov A, Copéret C, Sigman MS, Togni A.

J Am Chem Soc. 2018 Dec 26;140(51):18227-18228. doi: 10.1021/jacs.8b12730. Epub 2018 Dec 13. No abstract available.

PMID:
30543408
21.

Enantioselective C2-Alkylation of Indoles through a Redox-Relay Heck Reaction of 2-Indole Triflates.

Race NJ, Yuan Q, Sigman MS.

Chemistry. 2019 Jan 7;25(2):512-515. doi: 10.1002/chem.201805416. Epub 2018 Dec 11.

22.

Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions.

Coelho JAS, Matsumoto A, Orlandi M, Hilton MJ, Sigman MS, Toste FD.

Chem Sci. 2018 Aug 3;9(35):7153-7158. doi: 10.1039/c8sc02223b. eCollection 2018 Sep 21.

23.

Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization.

Zhao S, Gensch T, Murray B, Niemeyer ZL, Sigman MS, Biscoe MR.

Science. 2018 Nov 9;362(6415):670-674. doi: 10.1126/science.aat2299. Epub 2018 Sep 20.

24.

Combining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir).

Metsänen TT, Lexa KW, Santiago CB, Chung CK, Xu Y, Liu Z, Humphrey GR, Ruck RT, Sherer EC, Sigman MS.

Chem Sci. 2018 Jul 18;9(34):6922-6927. doi: 10.1039/c8sc02089b. eCollection 2018 Sep 14.

25.

Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines".

Woods BP, Orlandi M, Huang CD, Sigman MS, Doyle AG.

J Am Chem Soc. 2018 Jun 20;140(24):7744-7745. doi: 10.1021/jacs.8b05650. Epub 2018 Jun 11. No abstract available.

PMID:
29889505
26.

Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing α,β-Unsaturated δ-Lactams.

Yuan Q, Sigman MS.

J Am Chem Soc. 2018 May 30;140(21):6527-6530. doi: 10.1021/jacs.8b02752. Epub 2018 May 16.

27.

Predictive and mechanistic multivariate linear regression models for reaction development.

Santiago CB, Guo JY, Sigman MS.

Chem Sci. 2018 Jan 23;9(9):2398-2412. doi: 10.1039/c7sc04679k. eCollection 2018 Mar 7. Review.

28.

Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis.

Christian AH, Niemeyer ZL, Sigman MS, Toste FD.

ACS Catal. 2017 Jun 2;7(6):3973-3978. doi: 10.1021/acscatal.7b00757. Epub 2017 May 10.

29.

Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers.

Patel HH, Prater MB, Squire SO Jr, Sigman MS.

J Am Chem Soc. 2018 May 9;140(18):5895-5898. doi: 10.1021/jacs.8b02751. Epub 2018 Apr 27.

30.

High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries.

Hendriks KH, Robinson SG, Braten MN, Sevov CS, Helms BA, Sigman MS, Minteer SD, Sanford MS.

ACS Cent Sci. 2018 Feb 28;4(2):189-196. doi: 10.1021/acscentsci.7b00544. Epub 2018 Jan 17.

31.

Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones.

Crawford JM, Stone EA, Metrano AJ, Miller SJ, Sigman MS.

J Am Chem Soc. 2018 Jan 24;140(3):868-871. doi: 10.1021/jacs.7b11303. Epub 2018 Jan 10.

32.

Bioinspired design of a hybrid bifunctional enzymatic/organic electrocatalyst for site selective alcohol oxidation.

Lancaster L, Hickey DP, Sigman MS, Minteer SD, Wheeldon I.

Chem Commun (Camb). 2018 Jan 11;54(5):491-494. doi: 10.1039/c7cc08548f.

PMID:
29260808
33.

Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis.

Biswas S, Kubota K, Orlandi M, Turberg M, Miles DH, Sigman MS, Toste FD.

Angew Chem Int Ed Engl. 2018 Jan 8;57(2):589-593. doi: 10.1002/anie.201711277. Epub 2017 Dec 12.

34.

Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates.

Bischoff AJ, Nelson BM, Niemeyer ZL, Sigman MS, Movassaghi M.

J Am Chem Soc. 2017 Nov 1;139(43):15539-15547. doi: 10.1021/jacs.7b09541. Epub 2017 Oct 18.

35.

Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis.

Toste FD, Sigman MS, Miller SJ.

Acc Chem Res. 2017 Mar 21;50(3):609-615. doi: 10.1021/acs.accounts.6b00613.

36.

Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.

Orlandi M, Toste FD, Sigman MS.

Angew Chem Int Ed Engl. 2017 Nov 6;56(45):14080-14084. doi: 10.1002/anie.201707644. Epub 2017 Oct 4.

37.

Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

Niemeyer ZL, Pindi S, Khrakovsky DA, Kuzniewski CN, Hong CM, Joyce LA, Sigman MS, Toste FD.

J Am Chem Soc. 2017 Sep 20;139(37):12943-12946. doi: 10.1021/jacs.7b08791. Epub 2017 Sep 8.

38.

Polymer-immobilized, hybrid multi-catalyst architecture for enhanced electrochemical oxidation of glycerol.

Macazo FC, Hickey DP, Abdellaoui S, Sigman MS, Minteer SD.

Chem Commun (Camb). 2017 Sep 14;53(74):10310-10313. doi: 10.1039/c7cc05724e.

PMID:
28871300
39.

Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes.

Engl PS, Santiago CB, Gordon CP, Liao WC, Fedorov A, Copéret C, Sigman MS, Togni A.

J Am Chem Soc. 2017 Sep 20;139(37):13117-13125. doi: 10.1021/jacs.7b06947. Epub 2017 Sep 11. Erratum in: J Am Chem Soc. 2018 Dec 26;140(51):18227-18228.

PMID:
28820588
40.

Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates.

Orlandi M, Hilton MJ, Yamamoto E, Toste FD, Sigman MS.

J Am Chem Soc. 2017 Sep 13;139(36):12688-12695. doi: 10.1021/jacs.7b06917. Epub 2017 Aug 30.

41.

Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines.

Keylor MH, Niemeyer ZL, Sigman MS, Tan KL.

J Am Chem Soc. 2017 Aug 9;139(31):10613-10616. doi: 10.1021/jacs.7b05409. Epub 2017 Jul 27.

PMID:
28715180
42.

Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives.

Mack JBC, Gipson JD, Du Bois J, Sigman MS.

J Am Chem Soc. 2017 Jul 19;139(28):9503-9506. doi: 10.1021/jacs.7b05469. Epub 2017 Jun 29.

PMID:
28660763
43.

A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions.

Plata RE, Hill DE, Haines BE, Musaev DG, Chu L, Hickey DP, Sigman MS, Yu JQ, Blackmond DG.

J Am Chem Soc. 2017 Jul 12;139(27):9238-9245. doi: 10.1021/jacs.7b03716. Epub 2017 Jun 27.

PMID:
28605190
44.

Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.

Orlandi M, Coelho JAS, Hilton MJ, Toste FD, Sigman MS.

J Am Chem Soc. 2017 May 24;139(20):6803-6806. doi: 10.1021/jacs.7b02311. Epub 2017 May 11.

45.

Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters.

Chen ZM, Nervig CS, DeLuca RJ, Sigman MS.

Angew Chem Int Ed Engl. 2017 Jun 1;56(23):6651-6654. doi: 10.1002/anie.201703089. Epub 2017 May 3.

46.

The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.

Thornbury RT, Saini V, Fernandes TA, Santiago CB, Talbot EPA, Sigman MS, McKenna JM, Toste FD.

Chem Sci. 2017 Apr 1;8(4):2890-2897. doi: 10.1039/c6sc05102b. Epub 2017 Feb 9.

47.

Palladium-Catalyzed Enantioselective Heck Alkenylation of Trisubstituted Allylic Alkenols: A Redox-Relay Strategy to Construct Vicinal Stereocenters.

Zhang C, Tutkowski B, DeLuca RJ, Joyce LA, Wiest O, Sigman MS.

Chem Sci. 2017 Mar 1;8(3):2277-2282. doi: 10.1039/C6SC04585E. Epub 2016 Dec 9.

48.

Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-Transfer of Aryl Diazonium Salts.

Avila CM, Patel JS, Reddi Y, Saito M, Nelson HM, Shunatona HP, Sigman MS, Sunoj RB, Toste FD.

Angew Chem Int Ed Engl. 2017 May 15;56(21):5806-5811. doi: 10.1002/anie.201702107. Epub 2017 Apr 18.

49.

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines.

Woods BP, Orlandi M, Huang CY, Sigman MS, Doyle AG.

J Am Chem Soc. 2017 Apr 26;139(16):5688-5691. doi: 10.1021/jacs.7b03448. Epub 2017 Apr 13. Erratum in: J Am Chem Soc. 2018 Jun 20;140(24):7744-7745.

PMID:
28406622
50.

Exploiting non-covalent π interactions for catalyst design.

Neel AJ, Hilton MJ, Sigman MS, Toste FD.

Nature. 2017 Mar 29;543(7647):637-646. doi: 10.1038/nature21701. Review.

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