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Items: 1 to 50 of 657

1.

Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives.

Chen ZM, Liu J, Guo JY, Loch M, DeLuca RJ, Sigman MS.

Chem Sci. 2019 Jun 17;10(30):7246-7250. doi: 10.1039/c9sc02380a. eCollection 2019 Aug 14.

2.

Explicit and implicit monitoring in neurodegeneration and stroke.

Garcia-Cordero I, Sedeño L, Babino A, Dottori M, Melloni M, Martorell Caro M, Sigman M, Herrera E, Manes F, García AM, Ibáñez A.

Sci Rep. 2019 Oct 1;9(1):14032. doi: 10.1038/s41598-019-50599-x.

3.

Fading of collective attention shapes the evolution of linguistic variants.

Shalom DE, Sigman M, Mindlin G, Trevisan MA.

Phys Rev E. 2019 Aug;100(2-1):020102. doi: 10.1103/PhysRevE.100.020102.

PMID:
31574671
4.

Addressing patient gender bias toward trainees in the field of andrology.

Rotker K, Thavaseelan S, Sigman M.

Fertil Steril. 2019 Oct;112(4):640-641. doi: 10.1016/j.fertnstert.2019.08.003. No abstract available.

PMID:
31561867
5.

Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates".

Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD.

J Am Chem Soc. 2019 Sep 25;141(38):15464. doi: 10.1021/jacs.9b09747. Epub 2019 Sep 17. No abstract available.

PMID:
31525919
6.

Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery.

Yan Y, Robinson SG, Sigman MS, Sanford MS.

J Am Chem Soc. 2019 Sep 25;141(38):15301-15306. doi: 10.1021/jacs.9b07345. Epub 2019 Sep 10.

PMID:
31503480
7.

Social interaction and conceptual change pave the way away from children's misconceptions about the Earth.

de la Hera DP, Sigman M, Calero CI.

NPJ Sci Learn. 2019 Aug 28;4:12. doi: 10.1038/s41539-019-0051-3. eCollection 2019.

8.

Statistical inference of body representation in the macaque brain.

Fang W, Li J, Qi G, Li S, Sigman M, Wang L.

Proc Natl Acad Sci U S A. 2019 Oct 1;116(40):20151-20157. doi: 10.1073/pnas.1902334116. Epub 2019 Sep 3.

9.

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms.

Sandford C, Edwards MA, Klunder KJ, Hickey DP, Li M, Barman K, Sigman MS, White HS, Minteer SD.

Chem Sci. 2019 May 23;10(26):6404-6422. doi: 10.1039/c9sc01545k. eCollection 2019 Jul 14. Review.

10.

A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation.

Christian AH, Jia S, Cao W, Zhang P, Meza AT, Sigman MS, Chang CJ, Toste FD.

J Am Chem Soc. 2019 Aug 14;141(32):12657-12662. doi: 10.1021/jacs.9b04744. Epub 2019 Jul 30.

11.

Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction".

Allen JR, Bahamonde A, Furukawa Y, Sigman MS.

J Am Chem Soc. 2019 Aug 7;141(31):12420. doi: 10.1021/jacs.9b07380. Epub 2019 Jul 26. No abstract available.

PMID:
31347841
12.

Holistic prediction of enantioselectivity in asymmetric catalysis.

Reid JP, Sigman MS.

Nature. 2019 Jul;571(7765):343-348. doi: 10.1038/s41586-019-1384-z. Epub 2019 Jul 17.

PMID:
31316193
13.

Enantioselective construction of remote tertiary carbon-fluorine bonds.

Liu J, Yuan Q, Toste FD, Sigman MS.

Nat Chem. 2019 Aug;11(8):710-715. doi: 10.1038/s41557-019-0289-7. Epub 2019 Jul 15.

PMID:
31308495
14.

Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

Crawford JM, Sigman MS.

Synthesis (Stuttg). 2019 Mar;51(5):1021-1036. doi: 10.1055/s-0037-1611636. Epub 2019 Jan 8.

15.

Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy.

Yuan Q, Sigman MS.

Chemistry. 2019 Aug 14;25(46):10823-10827. doi: 10.1002/chem.201902813. Epub 2019 Jul 26.

16.

Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes.

Robinson SG, Yan Y, Hendriks KH, Sanford MS, Sigman MS.

J Am Chem Soc. 2019 Jul 3;141(26):10171-10176. doi: 10.1021/jacs.9b04270. Epub 2019 Jun 20.

PMID:
31203608
17.

Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis.

Ferreira MAB, De Jesus Silva J, Grosslight S, Fedorov A, Sigman MS, Copéret C.

J Am Chem Soc. 2019 Jul 10;141(27):10788-10800. doi: 10.1021/jacs.9b04367. Epub 2019 Jun 27.

PMID:
31180674
18.

Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines.

Bahamonde A, Al Rifaie B, Martín-Heras V, Allen JR, Sigman MS.

J Am Chem Soc. 2019 Jun 5;141(22):8708-8711. doi: 10.1021/jacs.9b03438. Epub 2019 May 24.

19.

Spermatozoal large RNA content is associated with semen characteristics, sociodemographic and lifestyle factors.

Bianchi E, Boekelheide K, Sigman M, Braun JM, Eliot M, Hall SJ, Dere E, Hwang K.

PLoS One. 2019 May 23;14(5):e0216584. doi: 10.1371/journal.pone.0216584. eCollection 2019.

20.

Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction.

Allen JR, Bahamonde A, Furukawa Y, Sigman MS.

J Am Chem Soc. 2019 Jun 5;141(22):8670-8674. doi: 10.1021/jacs.9b01476. Epub 2019 May 24. Erratum in: J Am Chem Soc. 2019 Aug 7;141(31):12420.

21.

Analysing the Impact of Music on the Perception of Red Wine via Temporal Dominance of Sensations.

Wang QJ, Mesz B, Riera P, Trevisan M, Sigman M, Guha A, Spence C.

Multisens Res. 2019 Jan 1;32(4-5):455-472. doi: 10.1163/22134808-20191401.

PMID:
31117045
22.

How the Brain Transitions from Conscious to Subliminal Perception.

Arese Lucini F, Del Ferraro G, Sigman M, Makse HA.

Neuroscience. 2019 Jul 15;411:280-290. doi: 10.1016/j.neuroscience.2019.03.047. Epub 2019 May 1.

PMID:
31051216
23.

Introduction: Male fertility testing: the past, present, and future.

Sigman M.

Fertil Steril. 2019 May;111(5):833-834. doi: 10.1016/j.fertnstert.2019.03.008. Epub 2019 Apr 5.

PMID:
30955843
24.

Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration.

Kwon Y, Li J, Reid JP, Crawford JM, Jacob R, Sigman MS, Toste FD, Miller SJ.

J Am Chem Soc. 2019 Apr 24;141(16):6698-6705. doi: 10.1021/jacs.9b01911. Epub 2019 Apr 10.

PMID:
30920223
25.

Transurethral resection of the ejaculatory ducts: etiology of obstruction and surgical treatment options.

Avellino GJ, Lipshultz LI, Sigman M, Hwang K.

Fertil Steril. 2019 Mar;111(3):427-443. doi: 10.1016/j.fertnstert.2019.01.001. Review.

PMID:
30827517
26.

The RNA Export Factor ALY1 Enables Genome-Wide RNA-Directed DNA Methylation.

Choudury SG, Shahid S, Cuerda-Gil D, Panda K, Cullen A, Ashraf Q, Sigman MJ, McCue AD, Slotkin RK.

Plant Cell. 2019 Apr;31(4):759-774. doi: 10.1105/tpc.18.00624. Epub 2019 Feb 27.

27.

Rapid chemiexcitation of phenoxy-dioxetane luminophores yields ultrasensitive chemiluminescence assays.

Hananya N, Reid JP, Green O, Sigman MS, Shabat D.

Chem Sci. 2018 Nov 19;10(5):1380-1385. doi: 10.1039/c8sc04280b. eCollection 2019 Feb 7.

28.

Risks for Child Cognitive Development in Rural Contexts.

Hermida MJ, Shalom DE, Segretin MS, Goldin AP, Abril MC, Lipina SJ, Sigman M.

Front Psychol. 2019 Jan 9;9:2735. doi: 10.3389/fpsyg.2018.02735. eCollection 2018.

29.

Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest.

Mack JBC, Walker KL, Robinson SG, Zare RN, Sigman MS, Waymouth RM, Du Bois J.

J Am Chem Soc. 2019 Jan 16;141(2):972-980. doi: 10.1021/jacs.8b10950. Epub 2019 Jan 2.

PMID:
30601662
30.

Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates.

Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD.

J Am Chem Soc. 2019 Jan 23;141(3):1382-1392. doi: 10.1021/jacs.8b12634. Epub 2019 Jan 11. Erratum in: J Am Chem Soc. 2019 Sep 25;141(38):15464.

PMID:
30599130
31.

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles.

Albright H, Riehl PS, McAtee CC, Reid JP, Ludwig JR, Karp LA, Zimmerman PM, Sigman MS, Schindler CS.

J Am Chem Soc. 2019 Jan 30;141(4):1690-1700. doi: 10.1021/jacs.8b11840. Epub 2019 Jan 16.

PMID:
30596414
32.

Evidence-based medicine when the evidence is poor.

Sigman M.

Fertil Steril. 2019 Feb;111(2):239. doi: 10.1016/j.fertnstert.2018.11.025. Epub 2018 Dec 24. No abstract available.

PMID:
30591205
33.

A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A.

Vaden RM, Guillen KP, Salvant JM, Santiago CB, Gibbons JB, Pathi SS, Arunachalam S, Sigman MS, Looper RE, Welm BE.

ACS Chem Biol. 2019 Jan 18;14(1):106-117. doi: 10.1021/acschembio.8b00977. Epub 2019 Jan 8.

PMID:
30571086
34.

Correction to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes".

Engl PS, Santiago CB, Gordon CP, Liao WC, Fedorov A, Copéret C, Sigman MS, Togni A.

J Am Chem Soc. 2018 Dec 26;140(51):18227-18228. doi: 10.1021/jacs.8b12730. Epub 2018 Dec 13. No abstract available.

PMID:
30543408
35.

The maturation of speech structure in psychosis is resistant to formal education.

Mota NB, Sigman M, Cecchi G, Copelli M, Ribeiro S.

NPJ Schizophr. 2018 Dec 7;4(1):25. doi: 10.1038/s41537-018-0067-3.

36.

Representation of spatial sequences using nested rules in human prefrontal cortex.

Wang L, Amalric M, Fang W, Jiang X, Pallier C, Figueira S, Sigman M, Dehaene S.

Neuroimage. 2019 Feb 1;186:245-255. doi: 10.1016/j.neuroimage.2018.10.061. Epub 2018 Oct 25.

PMID:
30449729
37.

Enantioselective C2-Alkylation of Indoles through a Redox-Relay Heck Reaction of 2-Indole Triflates.

Race NJ, Yuan Q, Sigman MS.

Chemistry. 2019 Jan 7;25(2):512-515. doi: 10.1002/chem.201805416. Epub 2018 Dec 11.

38.

Pros and cons of robotic microsurgery as an appropriate approach to male reproductive surgery for vasectomy reversal and varicocele repair.

Chan P, Parekattil SJ, Goldstein M, Lipshultz LI, Kavoussi P, McCullough A, Sigman M.

Fertil Steril. 2018 Oct;110(5):816-823. doi: 10.1016/j.fertnstert.2018.08.026. No abstract available.

PMID:
30316417
39.

An improvement in surgical technique or a sham? Value of robotic assistance for male reproductive surgery.

Sigman M.

Fertil Steril. 2018 Oct;110(5):815. doi: 10.1016/j.fertnstert.2018.08.009. No abstract available.

PMID:
30316416
40.

Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions.

Coelho JAS, Matsumoto A, Orlandi M, Hilton MJ, Sigman MS, Toste FD.

Chem Sci. 2018 Aug 3;9(35):7153-7158. doi: 10.1039/c8sc02223b. eCollection 2018 Sep 21.

41.

Schadenfreude is higher in real-life situations compared to hypothetical scenarios.

Gonzalez-Gadea ML, Ibanez A, Sigman M.

PLoS One. 2018 Oct 11;13(10):e0205595. doi: 10.1371/journal.pone.0205595. eCollection 2018.

42.

Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization.

Zhao S, Gensch T, Murray B, Niemeyer ZL, Sigman MS, Biscoe MR.

Science. 2018 Nov 9;362(6415):670-674. doi: 10.1126/science.aat2299. Epub 2018 Sep 20.

43.

Combining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir).

Metsänen TT, Lexa KW, Santiago CB, Chung CK, Xu Y, Liu Z, Humphrey GR, Ruck RT, Sherer EC, Sigman MS.

Chem Sci. 2018 Jul 18;9(34):6922-6927. doi: 10.1039/c8sc02089b. eCollection 2018 Sep 14.

44.

Language, gesture, and judgment: Children's paths to abstract geometry.

Calero CI, Shalom DE, Spelke ES, Sigman M.

J Exp Child Psychol. 2019 Jan;177:70-85. doi: 10.1016/j.jecp.2018.07.015. Epub 2018 Aug 28.

PMID:
30170245
45.

The Importance of Structure and Connection for People Living With Schizophrenia: A 33-Year Outpatient Group Experience.

Rice DB, Zorn A, Sigman M.

Community Ment Health J. 2018 Oct;54(7):992-996. doi: 10.1007/s10597-018-0329-6. Epub 2018 Aug 18.

PMID:
30121902
46.

Maintaining trust when agents can engage in self-deception.

Babino A, Makse HA, DiTella R, Sigman M.

Proc Natl Acad Sci U S A. 2018 Aug 28;115(35):8728-8733. doi: 10.1073/pnas.1803438115. Epub 2018 Aug 13.

47.

Parsing a mental program: Fixation-related brain signatures of unitary operations and routines in natural visual search.

Kamienkowski JE, Varatharajah A, Sigman M, Ison MJ.

Neuroimage. 2018 Dec;183:73-86. doi: 10.1016/j.neuroimage.2018.08.010. Epub 2018 Aug 8.

PMID:
30096368
48.

Forty years of IVF.

Niederberger C, Pellicer A, Cohen J, Gardner DK, Palermo GD, O'Neill CL, Chow S, Rosenwaks Z, Cobo A, Swain JE, Schoolcraft WB, Frydman R, Bishop LA, Aharon D, Gordon C, New E, Decherney A, Tan SL, Paulson RJ, Goldfarb JM, Brännström M, Donnez J, Silber S, Dolmans MM, Simpson JL, Handyside AH, Munné S, Eguizabal C, Montserrat N, Izpisua Belmonte JC, Trounson A, Simon C, Tulandi T, Giudice LC, Norman RJ, Hsueh AJ, Sun Y, Laufer N, Kochman R, Eldar-Geva T, Lunenfeld B, Ezcurra D, D'Hooghe T, Fauser BCJM, Tarlatzis BC, Meldrum DR, Casper RF, Fatemi HM, Devroey P, Galliano D, Wikland M, Sigman M, Schoor RA, Goldstein M, Lipshultz LI, Schlegel PN, Hussein A, Oates RD, Brannigan RE, Ross HE, Pennings G, Klock SC, Brown S, Van Steirteghem A, Rebar RW, LaBarbera AR.

Fertil Steril. 2018 Jul 15;110(2):185-324.e5. doi: 10.1016/j.fertnstert.2018.06.005. Review.

PMID:
30053940
49.
50.

Unconscious Repetition of a Patient's Dynamics on an Inpatient Unit: Treatment Challenges.

Ma D, Sigman M.

Am J Psychother. 2018 Oct 1;71(2):70-73. doi: 10.1176/appi.psychotherapy.20180012. Epub 2018 Jul 17.

PMID:
30016127

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