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Items: 1 to 50 of 668

1.

Transition State Force Field for the Asymmetric Redox Relay Heck Reaction.

Rosales A, Ross SP, Helquist P, Norrby PO, Sigman MS, Wiest O.

J Am Chem Soc. 2020 Apr 5. doi: 10.1021/jacs.0c01979. [Epub ahead of print]

PMID:
32249569
2.

Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts.

Miró J, Gensch T, Ellwart M, Han SJ, Lin HH, Sigman MS, Toste FD.

J Am Chem Soc. 2020 Apr 1;142(13):6390-6399. doi: 10.1021/jacs.0c01637. Epub 2020 Mar 23.

PMID:
32182422
3.

Realization of an Asymmetric Non-Aqueous Redox Flow Battery Through Molecular Design to Minimize Active Species Crossover and Decomposition.

Sanford M, Shrestha A, Hendriks K, Sigman M, Minteer S.

Chemistry. 2020 Feb 12. doi: 10.1002/chem.202000749. [Epub ahead of print]

PMID:
32049389
4.

Interplay of chronotype and school timing predicts school performance.

Goldin AP, Sigman M, Braier G, Golombek DA, Leone MJ.

Nat Hum Behav. 2020 Feb 10. doi: 10.1038/s41562-020-0820-2. [Epub ahead of print]

PMID:
32042108
5.

Introduction: Rare and unusual andrologic syndromes that clinicians should be aware of.

Sigman M.

Fertil Steril. 2020 Jan;113(1):4-5. doi: 10.1016/j.fertnstert.2019.11.031.

PMID:
32033721
6.

Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding.

Robinson SG, Sigman MS.

Acc Chem Res. 2020 Feb 18;53(2):289-299. doi: 10.1021/acs.accounts.9b00527. Epub 2020 Jan 10.

PMID:
31920070
7.

Site-selective acylation of natural products with BINOL-derived phosphoric acids.

Li J, Grosslight S, Miller SJ, Sigman MS, Toste FD.

ACS Catal. 2019 Nov 1;9(11):9794-9799. doi: 10.1021/acscatal.9b03535. Epub 2019 Oct 1.

PMID:
31827975
8.

Reaching Consensus in Polarized Moral Debates.

Navajas J, Álvarez Heduan F, Garrido JM, Gonzalez PA, Garbulsky G, Ariely D, Sigman M.

Curr Biol. 2019 Dec 2;29(23):4124-4129.e6. doi: 10.1016/j.cub.2019.10.018. Epub 2019 Nov 21.

PMID:
31761699
9.

Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines.

Reid JP, Proctor RSJ, Sigman MS, Phipps RJ.

J Am Chem Soc. 2019 Dec 4;141(48):19178-19185. doi: 10.1021/jacs.9b11658. Epub 2019 Nov 21.

10.

Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization.

Sandford C, Fries LR, Ball TE, Minteer SD, Sigman MS.

J Am Chem Soc. 2019 Nov 27;141(47):18877-18889. doi: 10.1021/jacs.9b10771. Epub 2019 Nov 15.

PMID:
31698896
11.

25 historic papers: an ASRM 75th birthday gift from Fertility and Sterility.

Niederberger C, Pellicer A, Simon C, Kathrins M, Goldstein M, Sigman M, Schlegel PN, Munné S, Gardner DK, Cobo A, Coutifaris C, Donnez J, Taylor HS, Giudice LC, Fauser BCJM, Lindheim SR, Rosenwaks Z, Casper RF, de Ziegler D, Gibbons WE, Paulson RJ, Laufer N, Klock SC, Mendola P, Sauer MV.

Fertil Steril. 2019 Oct;112(4S1):e2-e27. doi: 10.1016/j.fertnstert.2019.08.099. No abstract available.

PMID:
31623734
12.

Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives.

Chen ZM, Liu J, Guo JY, Loch M, DeLuca RJ, Sigman MS.

Chem Sci. 2019 Jun 17;10(30):7246-7250. doi: 10.1039/c9sc02380a. eCollection 2019 Aug 14.

13.

Explicit and implicit monitoring in neurodegeneration and stroke.

Garcia-Cordero I, Sedeño L, Babino A, Dottori M, Melloni M, Martorell Caro M, Sigman M, Herrera E, Manes F, García AM, Ibáñez A.

Sci Rep. 2019 Oct 1;9(1):14032. doi: 10.1038/s41598-019-50599-x.

14.

Fading of collective attention shapes the evolution of linguistic variants.

Shalom DE, Sigman M, Mindlin G, Trevisan MA.

Phys Rev E. 2019 Aug;100(2-1):020102. doi: 10.1103/PhysRevE.100.020102.

PMID:
31574671
15.

Addressing patient gender bias toward trainees in the field of andrology.

Rotker K, Thavaseelan S, Sigman M.

Fertil Steril. 2019 Oct;112(4):640-641. doi: 10.1016/j.fertnstert.2019.08.003. No abstract available.

PMID:
31561867
16.

Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates".

Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD.

J Am Chem Soc. 2019 Sep 25;141(38):15464. doi: 10.1021/jacs.9b09747. Epub 2019 Sep 17. No abstract available.

PMID:
31525919
17.

Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery.

Yan Y, Robinson SG, Sigman MS, Sanford MS.

J Am Chem Soc. 2019 Sep 25;141(38):15301-15306. doi: 10.1021/jacs.9b07345. Epub 2019 Sep 10.

PMID:
31503480
18.

Social interaction and conceptual change pave the way away from children's misconceptions about the Earth.

de la Hera DP, Sigman M, Calero CI.

NPJ Sci Learn. 2019 Aug 28;4:12. doi: 10.1038/s41539-019-0051-3. eCollection 2019.

19.

Statistical inference of body representation in the macaque brain.

Fang W, Li J, Qi G, Li S, Sigman M, Wang L.

Proc Natl Acad Sci U S A. 2019 Oct 1;116(40):20151-20157. doi: 10.1073/pnas.1902334116. Epub 2019 Sep 3.

20.

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms.

Sandford C, Edwards MA, Klunder KJ, Hickey DP, Li M, Barman K, Sigman MS, White HS, Minteer SD.

Chem Sci. 2019 May 23;10(26):6404-6422. doi: 10.1039/c9sc01545k. eCollection 2019 Jul 14. Review.

21.

A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation.

Christian AH, Jia S, Cao W, Zhang P, Meza AT, Sigman MS, Chang CJ, Toste FD.

J Am Chem Soc. 2019 Aug 14;141(32):12657-12662. doi: 10.1021/jacs.9b04744. Epub 2019 Jul 30.

22.

Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction".

Allen JR, Bahamonde A, Furukawa Y, Sigman MS.

J Am Chem Soc. 2019 Aug 7;141(31):12420. doi: 10.1021/jacs.9b07380. Epub 2019 Jul 26. No abstract available.

PMID:
31347841
23.

Holistic prediction of enantioselectivity in asymmetric catalysis.

Reid JP, Sigman MS.

Nature. 2019 Jul;571(7765):343-348. doi: 10.1038/s41586-019-1384-z. Epub 2019 Jul 17.

24.

Enantioselective construction of remote tertiary carbon-fluorine bonds.

Liu J, Yuan Q, Toste FD, Sigman MS.

Nat Chem. 2019 Aug;11(8):710-715. doi: 10.1038/s41557-019-0289-7. Epub 2019 Jul 15.

25.

Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

Crawford JM, Sigman MS.

Synthesis (Stuttg). 2019 Mar;51(5):1021-1036. doi: 10.1055/s-0037-1611636. Epub 2019 Jan 8.

26.

Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy.

Yuan Q, Sigman MS.

Chemistry. 2019 Aug 14;25(46):10823-10827. doi: 10.1002/chem.201902813. Epub 2019 Jul 26.

27.

Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes.

Robinson SG, Yan Y, Hendriks KH, Sanford MS, Sigman MS.

J Am Chem Soc. 2019 Jul 3;141(26):10171-10176. doi: 10.1021/jacs.9b04270. Epub 2019 Jun 20.

PMID:
31203608
28.

Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis.

Ferreira MAB, De Jesus Silva J, Grosslight S, Fedorov A, Sigman MS, Copéret C.

J Am Chem Soc. 2019 Jul 10;141(27):10788-10800. doi: 10.1021/jacs.9b04367. Epub 2019 Jun 27.

PMID:
31180674
29.

Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines.

Bahamonde A, Al Rifaie B, Martín-Heras V, Allen JR, Sigman MS.

J Am Chem Soc. 2019 Jun 5;141(22):8708-8711. doi: 10.1021/jacs.9b03438. Epub 2019 May 24.

30.

Spermatozoal large RNA content is associated with semen characteristics, sociodemographic and lifestyle factors.

Bianchi E, Boekelheide K, Sigman M, Braun JM, Eliot M, Hall SJ, Dere E, Hwang K.

PLoS One. 2019 May 23;14(5):e0216584. doi: 10.1371/journal.pone.0216584. eCollection 2019.

31.

Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction.

Allen JR, Bahamonde A, Furukawa Y, Sigman MS.

J Am Chem Soc. 2019 Jun 5;141(22):8670-8674. doi: 10.1021/jacs.9b01476. Epub 2019 May 24. Erratum in: J Am Chem Soc. 2019 Aug 7;141(31):12420.

32.

Analysing the Impact of Music on the Perception of Red Wine via Temporal Dominance of Sensations.

Wang QJ, Mesz B, Riera P, Trevisan M, Sigman M, Guha A, Spence C.

Multisens Res. 2019 Jan 1;32(4-5):455-472. doi: 10.1163/22134808-20191401.

PMID:
31117045
33.

How the Brain Transitions from Conscious to Subliminal Perception.

Arese Lucini F, Del Ferraro G, Sigman M, Makse HA.

Neuroscience. 2019 Jul 15;411:280-290. doi: 10.1016/j.neuroscience.2019.03.047. Epub 2019 May 1.

PMID:
31051216
34.

Introduction: Male fertility testing: the past, present, and future.

Sigman M.

Fertil Steril. 2019 May;111(5):833-834. doi: 10.1016/j.fertnstert.2019.03.008. Epub 2019 Apr 5.

PMID:
30955843
35.

Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration.

Kwon Y, Li J, Reid JP, Crawford JM, Jacob R, Sigman MS, Toste FD, Miller SJ.

J Am Chem Soc. 2019 Apr 24;141(16):6698-6705. doi: 10.1021/jacs.9b01911. Epub 2019 Apr 10.

PMID:
30920223
36.

Transurethral resection of the ejaculatory ducts: etiology of obstruction and surgical treatment options.

Avellino GJ, Lipshultz LI, Sigman M, Hwang K.

Fertil Steril. 2019 Mar;111(3):427-443. doi: 10.1016/j.fertnstert.2019.01.001. Review.

PMID:
30827517
37.

The RNA Export Factor ALY1 Enables Genome-Wide RNA-Directed DNA Methylation.

Choudury SG, Shahid S, Cuerda-Gil D, Panda K, Cullen A, Ashraf Q, Sigman MJ, McCue AD, Slotkin RK.

Plant Cell. 2019 Apr;31(4):759-774. doi: 10.1105/tpc.18.00624. Epub 2019 Feb 27.

38.

Rapid chemiexcitation of phenoxy-dioxetane luminophores yields ultrasensitive chemiluminescence assays.

Hananya N, Reid JP, Green O, Sigman MS, Shabat D.

Chem Sci. 2018 Nov 19;10(5):1380-1385. doi: 10.1039/c8sc04280b. eCollection 2019 Feb 7.

39.

Risks for Child Cognitive Development in Rural Contexts.

Hermida MJ, Shalom DE, Segretin MS, Goldin AP, Abril MC, Lipina SJ, Sigman M.

Front Psychol. 2019 Jan 9;9:2735. doi: 10.3389/fpsyg.2018.02735. eCollection 2018.

40.

Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest.

Mack JBC, Walker KL, Robinson SG, Zare RN, Sigman MS, Waymouth RM, Du Bois J.

J Am Chem Soc. 2019 Jan 16;141(2):972-980. doi: 10.1021/jacs.8b10950. Epub 2019 Jan 2.

PMID:
30601662
41.

Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates.

Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD.

J Am Chem Soc. 2019 Jan 23;141(3):1382-1392. doi: 10.1021/jacs.8b12634. Epub 2019 Jan 11. Erratum in: J Am Chem Soc. 2019 Sep 25;141(38):15464.

PMID:
30599130
42.

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles.

Albright H, Riehl PS, McAtee CC, Reid JP, Ludwig JR, Karp LA, Zimmerman PM, Sigman MS, Schindler CS.

J Am Chem Soc. 2019 Jan 30;141(4):1690-1700. doi: 10.1021/jacs.8b11840. Epub 2019 Jan 16.

43.

Evidence-based medicine when the evidence is poor.

Sigman M.

Fertil Steril. 2019 Feb;111(2):239. doi: 10.1016/j.fertnstert.2018.11.025. Epub 2018 Dec 24. No abstract available.

PMID:
30591205
44.

A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A.

Vaden RM, Guillen KP, Salvant JM, Santiago CB, Gibbons JB, Pathi SS, Arunachalam S, Sigman MS, Looper RE, Welm BE.

ACS Chem Biol. 2019 Jan 18;14(1):106-117. doi: 10.1021/acschembio.8b00977. Epub 2019 Jan 8.

PMID:
30571086
45.

Correction to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes".

Engl PS, Santiago CB, Gordon CP, Liao WC, Fedorov A, Copéret C, Sigman MS, Togni A.

J Am Chem Soc. 2018 Dec 26;140(51):18227-18228. doi: 10.1021/jacs.8b12730. Epub 2018 Dec 13. No abstract available.

PMID:
30543408
46.

The maturation of speech structure in psychosis is resistant to formal education.

Mota NB, Sigman M, Cecchi G, Copelli M, Ribeiro S.

NPJ Schizophr. 2018 Dec 7;4(1):25. doi: 10.1038/s41537-018-0067-3.

47.

Representation of spatial sequences using nested rules in human prefrontal cortex.

Wang L, Amalric M, Fang W, Jiang X, Pallier C, Figueira S, Sigman M, Dehaene S.

Neuroimage. 2019 Feb 1;186:245-255. doi: 10.1016/j.neuroimage.2018.10.061. Epub 2018 Oct 25.

48.

Enantioselective C2-Alkylation of Indoles through a Redox-Relay Heck Reaction of 2-Indole Triflates.

Race NJ, Yuan Q, Sigman MS.

Chemistry. 2019 Jan 7;25(2):512-515. doi: 10.1002/chem.201805416. Epub 2018 Dec 11.

49.

Pros and cons of robotic microsurgery as an appropriate approach to male reproductive surgery for vasectomy reversal and varicocele repair.

Chan P, Parekattil SJ, Goldstein M, Lipshultz LI, Kavoussi P, McCullough A, Sigman M.

Fertil Steril. 2018 Oct;110(5):816-823. doi: 10.1016/j.fertnstert.2018.08.026. No abstract available.

PMID:
30316417
50.

An improvement in surgical technique or a sham? Value of robotic assistance for male reproductive surgery.

Sigman M.

Fertil Steril. 2018 Oct;110(5):815. doi: 10.1016/j.fertnstert.2018.08.009. No abstract available.

PMID:
30316416

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