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Items: 1 to 50 of 199

1.

Spin-Polarized Electron Transmission in DNA-Like Systems.

Sierra MA, Sánchez D, Gutierrez R, Cuniberti G, Domínguez-Adame F, Díaz E.

Biomolecules. 2019 Dec 28;10(1). pii: E49. doi: 10.3390/biom10010049.

2.

Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior.

Merinero AD, Collado A, Casarrubios L, Gómez-Gallego M, Ramírez de Arellano C, Caballero A, Zapata F, Sierra MA.

Inorg Chem. 2019 Dec 2;58(23):16267-16278. doi: 10.1021/acs.inorgchem.9b02813. Epub 2019 Nov 13.

PMID:
31721561
3.

1,2,3-Triazolium-Derived Mesoionic Carbene Ligands Bearing Chiral Sulfur-Based Moieties: Synthesis, Catalytic Properties, and Their Role in Chirality Transfer.

Sierra MA, de la Torre MC.

ACS Omega. 2019 Aug 7;4(8):12983-12994. doi: 10.1021/acsomega.9b01285. eCollection 2019 Aug 20. Review.

4.

Central (S) to Central (M=Ir, Rh) to Planar (Metallocene, M=Fe, Ru) Chirality Transfer Using Sulfoxide-Substituted Mesoionic Carbene Ligands: Synthesis of Bimetallic Planar Chiral Metallocenes.

Avello MG, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

Chemistry. 2019 Oct 17;25(58):13344-13353. doi: 10.1002/chem.201902102. Epub 2019 Sep 13.

PMID:
31397497
5.

Two Types of σ-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes.

Cabeza JA, García-Álvarez P, Gómez-Gallego M, González-Álvarez L, Merinero AD, Sierra MA.

Chemistry. 2019 Jun 26;25(36):8635-8642. doi: 10.1002/chem.201901579. Epub 2019 May 27.

PMID:
31046156
6.

Serum 25-hydroxyvitamin D and mammographic density in premenopausal Spanish women.

Lope V, Toribio MJ, Pérez-Gómez B, Castelló A, Mena-Bravo A, Sierra MÁ, Lucas P, Herrán-Vidaurrázaga MDC, González-Vizcayno C, Pino MN, Cruz-Campos I, Roca-Navarro MJ, Aragonés N, Romieu I, Martínez-Cortés M, Luque de Castro MD, Pollán M.

J Steroid Biochem Mol Biol. 2019 May;189:101-107. doi: 10.1016/j.jsbmb.2019.03.004. Epub 2019 Mar 2.

PMID:
30836177
7.

Bio-Organometallic Derivatives of Antibacterial Drugs.

Sierra MA, Casarrubios L, de la Torre MC.

Chemistry. 2019 May 28;25(30):7232-7242. doi: 10.1002/chem.201805985. Epub 2019 Mar 18. Review.

PMID:
30730065
8.

Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement.

Cabeza JA, García-Álvarez P, Gómez-Gallego M, González-Álvarez L, Merinero AD, Sierra MA.

Chemistry. 2019 Feb 11;25(9):2222-2225. doi: 10.1002/chem.201806275. Epub 2019 Jan 16.

PMID:
30565752
9.

Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes.

Álvarez-Rodríguez L, Cabeza JA, García-Álvarez P, Gómez-Gallego M, González-Álvarez L, Merinero AD, Sierra MA.

Chemistry. 2019 Jan 28;25(6):1588-1594. doi: 10.1002/chem.201805406. Epub 2018 Dec 27.

PMID:
30468272
10.

Thermally Driven Out-of-Equilibrium Two-Impurity Kondo System.

Sierra MA, López R, Lim JS.

Phys Rev Lett. 2018 Aug 31;121(9):096801. doi: 10.1103/PhysRevLett.121.096801.

PMID:
30230870
11.

Unexpected Reaction Pathways Leading to Thiodiglycol During the Degradation of Long-Chain Sulfur Mustards.

Gómez-Caballero E, Martínez-Álvarez R, Sierra MA.

J Org Chem. 2018 Oct 19;83(20):12432-12439. doi: 10.1021/acs.joc.8b01670. Epub 2018 Oct 2.

PMID:
30230837
12.

Triazole vs. triazolium carbene ligands in the site-selective cyclometallation of o-carboranes by M(iii) (M = Ir, Rh) complexes.

Frutos M, Gómez-Gallego M, Giner EA, Sierra MA, Ramírez de Arellano C.

Dalton Trans. 2018 Jul 31;47(30):9975-9979. doi: 10.1039/c8dt02296h.

PMID:
29978177
13.

How to distinguish between interacting and noninteracting molecules in tunnel junctions.

Sierra MA, Sánchez D, Garrigues AR, Del Barco E, Wang L, Nijhuis CA.

Nanoscale. 2018 Feb 22;10(8):3904-3910. doi: 10.1039/c7nr05739c.

PMID:
29423488
14.

Chiral Sulfur Functional Groups as Definers of the Chirality at the Metal in Ir and Rh Half-Sandwich Complexes: A Combined CD/X-ray Study.

Avello MG, Frutos M, de la Torre MC, Viso A, Velado M, de la Pradilla RF, Sierra MA, Gornitzka H, Hemmert C.

Chemistry. 2017 Oct 17;23(58):14523-14531. doi: 10.1002/chem.201702662. Epub 2017 Sep 18.

PMID:
28749583
15.

Gold(I)-Catalyzed Cycloisomerization-Dimerization Cascade of Benzene-Tethered 1,6-Enynes.

Álvarez-Pérez M, Frutos M, Viso A, Fernández de la Pradilla R, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

J Org Chem. 2017 Jul 21;82(14):7546-7554. doi: 10.1021/acs.joc.7b01273. Epub 2017 Jul 5.

PMID:
28650170
16.

Sequential Reactions of Alkynes on an Iridium(III) Single Site.

Giner EA, Gómez-Gallego M, Merinero AD, Casarrubios L, Ramírez de Arellano C, Sierra MA.

Chemistry. 2017 Jul 3;23(37):8941-8948. doi: 10.1002/chem.201701100. Epub 2017 Jun 12.

PMID:
28440592
17.

First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.

Álvarez-Rodríguez L, Cabeza JA, García-Álvarez P, Gómez-Gallego M, Merinero AD, Sierra MA.

Chemistry. 2017 Mar 28;23(18):4287-4291. doi: 10.1002/chem.201700828. Epub 2017 Mar 15.

PMID:
28225557
18.

Sulfur Groups Improve the Performance of Triazole- and Triazolium-Based Interaction Units in Anion Binding.

Álvarez-Pérez M, Velado M, García-Puentes D, Sáez E, Vicent C, Fernández de la Pradilla R, Viso A, de la Torre MC, Sierra MA.

J Org Chem. 2017 Mar 17;82(6):3341-3346. doi: 10.1021/acs.joc.7b00261. Epub 2017 Feb 24.

PMID:
28218535
19.

Effect of a κ1-Bonded-M-1,2,3-triazole (M = Co, Ru) on the Structure and Reactivity of Group 6 Alkoxy (Fischer) Carbenes.

Giner EA, Gómez-Gallego M, Casarrubios L, de la Torre MC, Ramírez de Arellano C, Sierra MA.

Inorg Chem. 2017 Mar 6;56(5):2801-2811. doi: 10.1021/acs.inorgchem.6b02957. Epub 2017 Feb 10.

PMID:
28186419
20.

Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)-1,2,3-Triazole Carbene Complexes.

Frutos M, Ortuño MA, Lledos A, Viso A, Fernández de la Pradilla R, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

Org Lett. 2017 Feb 17;19(4):822-825. doi: 10.1021/acs.orglett.6b03808. Epub 2017 Jan 30.

PMID:
28135109
21.

Relationship between drugs affecting the renin-angiotensin system and colorectal cancer: The MCC-Spain study.

Dierssen-Sotos T, Gómez-Acebo I, Palazuelos C, Rodriguez-Moranta F, Pérez-Gómez B, Fernández Vazquez JP, Amiano P, Barricarte A, Mirón-Pozo B, Tardon A, Capelo R, Peiro Pérez R, Huerta JM, Andreu M, Sierra MÁ, Castañón López C, Ruiz I, Moreno-Iribas C, Olmedo-Requena R, Castaño-Vinyals G, Aragonés N, Kogevinas M, Pollán M, Llorca J.

Prev Med. 2017 Jun;99:178-184. doi: 10.1016/j.ypmed.2017.01.011. Epub 2017 Jan 26.

PMID:
28131779
22.

Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach.

Valderas C, Marzo L, de la Torre MC, García Ruano JL, Alemán J, Casarrubios L, Sierra MA.

Chemistry. 2016 Oct 24;22(44):15645-15649. doi: 10.1002/chem.201603462. Epub 2016 Sep 22.

PMID:
27595563
23.

Muscle Pathology in Free-Ranging Stranded Cetaceans.

Sierra E, Espinosa de Los Monteros A, Fernández A, Díaz-Delgado J, Suárez-Santana C, Arbelo M, Sierra MA, Herráez P.

Vet Pathol. 2017 Mar;54(2):298-311. doi: 10.1177/0300985816660747. Epub 2016 Aug 20.

PMID:
27538973
24.

An Entry to Mixed NHC-Fischer Carbene Complexes and Zwitterionic Group 6 Metal Alkenyls.

Sierra MA, Merinero AD, Giner EA, Gómez-Gallego M, Ramírez de Arellano C.

Chemistry. 2016 Sep 12;22(38):13521-31. doi: 10.1002/chem.201601735. Epub 2016 Jul 26.

PMID:
27459647
25.

Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity.

Frutos M, Avello MG, Viso A, Fernández de la Pradilla R, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

Org Lett. 2016 Aug 5;18(15):3570-3. doi: 10.1021/acs.orglett.6b01555. Epub 2016 Jul 12.

PMID:
27403763
26.

GC-MS Study of Mono- and Bishaloethylphosphonates Related to Schedule 2.B.04 of the Chemical Weapons Convention: The Discovery of a New Intramolecular Halogen Transfer.

Picazas-Márquez N, Sierra M, Nova C, Moreno JM, Aboitiz N, de Rivas G, Sierra MA, Martínez-Álvarez R, Gómez-Caballero E.

J Am Soc Mass Spectrom. 2016 Sep;27(9):1510-9. doi: 10.1007/s13361-016-1430-0. Epub 2016 Jun 14.

PMID:
27300717
27.

Silver(I)-Catalyzed Addition of Phenols to Alkyne Cobalt Cluster Stabilized Carbocations.

Valderas C, Casarrubios L, Lledos A, Ortuño MA, de la Torre MC, Sierra MA.

Chemistry. 2016 Jun 20;22(26):9015-23. doi: 10.1002/chem.201600288. Epub 2016 May 17.

PMID:
27187529
28.

Remote Control by π-Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads.

Chu GM, Guerrero-Martínez A, Ramírez de Arellano C, Fernández I, Sierra MA.

Inorg Chem. 2016 Mar 21;55(6):2737-47. doi: 10.1021/acs.inorgchem.5b02448. Epub 2016 Mar 3.

PMID:
26938956
29.

Steroid Derived Mesoionic Gold and Silver Mono- and Polymetallic Carbenes.

Frutos M, de la Torre MC, Sierra MA.

Inorg Chem. 2015 Dec 7;54(23):11174-85. doi: 10.1021/acs.inorgchem.5b01524. Epub 2015 Nov 24.

PMID:
26600185
30.

2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes.

Casarrubios L, Esteruelas MA, Larramona C, Muntaner JG, Oñate E, Sierra MA.

Inorg Chem. 2015 Nov 16;54(22):10998-1006. doi: 10.1021/acs.inorgchem.5b02138. Epub 2015 Oct 29.

PMID:
26512736
31.

Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance.

Casarrubios L, Esteruelas MA, Larramona C, Lledós A, Muntaner JG, Oñate E, Ortuño MA, Sierra MA.

Chemistry. 2015 Nov 16;21(47):16781-5. doi: 10.1002/chem.201503595. Epub 2015 Oct 6.

PMID:
26437692
32.

Mono- and bimetallic zwitterionic chromium(0) and tungsten(0) allenyls.

Giner EA, Santiago A, Gómez-Gallego M, Ramírez de Arellano C, Poulten RC, Whittlesey MK, Sierra MA.

Inorg Chem. 2015 Jun 1;54(11):5450-61. doi: 10.1021/acs.inorgchem.5b00492. Epub 2015 May 8.

PMID:
25952749
33.

Synthesis of oxaspiranic compounds through [3 + 2] annulation of cyclopropenones and donor–acceptor cyclopropanes.

Rivero AR, Fernández I, de Arellano CR, Sierra MA.

J Org Chem. 2015 Jan 16;80(2):1207-13.

PMID:
25513728
34.

On the use of metal purine derivatives (M=Ir, Rh) for the selective labeling of nucleosides and nucleotides.

Valencia M, Martín-Ortiz M, Gómez-Gallego M, Ramírez de Arellano C, Sierra MA.

Chemistry. 2014 Mar 24;20(13):3831-8.

PMID:
24677547
35.

Tuning the photophysical properties of BODIPY molecules by π-conjugation with Fischer carbene complexes.

Chu GM, Guerrero-Martínez A, Fernández I, Sierra MÁ.

Chemistry. 2014 Jan 27;20(5):1367-75. doi: 10.1002/chem.201303952. Epub 2013 Dec 30.

PMID:
24382813
36.

The photochemical reaction of vinylaziridines and vinylazetidines with chromium(0) and molybdenum(0) (Fischer) carbene complexes.

Rivero AR, Fernández I, Sierra MA.

Chemistry. 2014 Jan 27;20(5):1359-66. doi: 10.1002/chem.201302029. Epub 2013 Dec 16.

PMID:
24375694
37.

Synthesis of new bioorganometallic Ir- and Rh-complexes having β-lactam containing ligands.

Muntaner JG, Casarrubios L, Sierra MA.

Org Biomol Chem. 2014 Jan 14;12(2):286-97. doi: 10.1039/c3ob41354c.

PMID:
24217409
38.

Regio- and diastereoselective stepwise [8 + 3]-Cycloaddition reaction between tropone derivatives and donor-acceptor cyclopropanes.

Rivero AR, Fernández I, Sierra MÁ.

Org Lett. 2013 Oct 4;15(19):4928-31. doi: 10.1021/ol4020656. Epub 2013 Sep 16.

PMID:
24040858
39.

Intentional forgetting: note-taking as a naturalistic example.

Eskritt M, Ma S.

Mem Cognit. 2014 Feb;42(2):237-46. doi: 10.3758/s13421-013-0362-1.

PMID:
24014168
40.

Towards a general synthesis of 3-metal-substituted β-lactams.

Baeza B, Casarrubios L, Sierra MA.

Chemistry. 2013 Aug 26;19(35):11536-40. doi: 10.1002/chem.201301114. Epub 2013 Jul 18.

PMID:
23868560
41.

Synthesis, structure, and electronic properties of extended π-conjugated Group 6 Fischer alkoxy-bis(carbene) complexes.

Chu GM, Fernández I, Sierra MA.

Chemistry. 2013 May 3;19(19):5899-908. doi: 10.1002/chem.201204512. Epub 2013 Mar 15.

PMID:
23504973
42.

The "click" reaction involving metal azides, metal alkynes, or both: an exploration into multimetal structures.

Casarrubios L, de la Torre MC, Sierra MA.

Chemistry. 2013 Mar 11;19(11):3534-41. doi: 10.1002/chem.201204596. Epub 2013 Feb 18.

PMID:
23418069
43.

Mono- and dinuclear osmium N,N'-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry.

Esteruelas MA, Fernández I, Gómez-Gallego M, Martín-Ortíz M, Molina P, Oliván M, Otón F, Sierra MA, Valencia M.

Dalton Trans. 2013 Mar 14;42(10):3597-608. doi: 10.1039/c2dt32548a. Epub 2013 Jan 4.

PMID:
23292252
44.

Control over the E/Z selectivity of the catalytic dimerization of group 6 (Fischer) metal carbene complexes.

Chu GM, Fernández I, Sierra MA.

J Org Chem. 2013 Feb 1;78(3):865-71. doi: 10.1021/jo302130h. Epub 2013 Jan 14.

PMID:
23289828
45.

Structure and photoreactivity of stable zwitterionic group 6 metal allenyls.

Santiago A, Gómez-Gallego M, de Arellano CR, Sierra MA.

Chem Commun (Camb). 2013 Feb 4;49(11):1112-4. doi: 10.1039/c2cc38223g.

PMID:
23283285
46.

A click approach to polymetallic chromium(0) and tungsten(0) Fischer-carbene complexes and their use in the synthesis of functionalized polymetallic metal-carbene complexes.

Baeza B, Casarrubios L, Sierra MA.

Chemistry. 2013 Jan 21;19(4):1429-35. doi: 10.1002/chem.201202328. Epub 2012 Nov 30.

PMID:
23203658
47.

Intramolecular Pd(0)-catalyzed reactions of (2-iodoanilino)-aldehydes: a joint experimental-computational study.

Solé D, Mariani F, Fernández I, Sierra MA.

J Org Chem. 2012 Nov 16;77(22):10272-84. doi: 10.1021/jo301924e. Epub 2012 Nov 5.

PMID:
23095061
48.

The selective synthesis of metallanucleosides and metallanucleotides: a new tool for the functionalization of nucleic acids.

Martín-Ortíz M, Gómez-Gallego M, Ramírez de Arellano C, Sierra MA.

Chemistry. 2012 Oct 1;18(40):12603-8. doi: 10.1002/chem.201202327. Epub 2012 Aug 30.

PMID:
22933336
49.

Regioselective and stepwise [8 + 2] cycloaddition reaction between alkynyl-Fischer carbene complexes and tropothione.

Rivero AR, Fernández I, Sierra MA.

J Org Chem. 2012 Aug 3;77(15):6648-52. doi: 10.1021/jo3011304. Epub 2012 Jul 16.

PMID:
22780846
50.

Synthesis and characterisation of [6]-azaosmahelicenes: the first d4-heterometallahelicenes.

Crespo O, Eguillor B, Esteruelas MA, Fernández I, García-Raboso J, Gómez-Gallego M, Martín-Ortiz M, Oliván M, Sierra MA.

Chem Commun (Camb). 2012 May 28;48(43):5328-30. doi: 10.1039/c2cc30356f. Epub 2012 Apr 20.

PMID:
22517029

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