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Items: 1 to 50 of 217

1.

Silica-Supported Molybdenum Oxo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis.

Pucino M, Zhai F, Gordon CP, Mance D, Hoveyda AH, Schrock RR, Copéret C.

Angew Chem Int Ed Engl. 2019 Aug 19;58(34):11816-11819. doi: 10.1002/anie.201903325. Epub 2019 Jul 11.

PMID:
31099940
2.

E- and Z-, di- and tri-substituted alkenyl nitriles through catalytic cross-metathesis.

Mu Y, Nguyen TT, Koh MJ, Schrock RR, Hoveyda AH.

Nat Chem. 2019 May;11(5):478-487. doi: 10.1038/s41557-019-0233-x. Epub 2019 Apr 1.

3.

Protonation Studies of Molybdenum(VI) Nitride Complexes That Contain the [2,6-(ArNCH2)2NC5H3]2- Ligand (Ar = 2,6-Diisopropylphenyl).

Hickey AK, Wickramasinghe LA, Schrock RR, Tsay C, Müller P.

Inorg Chem. 2019 Mar 18;58(6):3724-3731. doi: 10.1021/acs.inorgchem.8b03346. Epub 2019 Feb 26.

PMID:
30807124
4.

Traceless Protection for More Broadly Applicable Olefin Metathesis.

Mu Y, Nguyen TT, van der Mei FW, Schrock RR, Hoveyda AH.

Angew Chem Int Ed Engl. 2019 Apr 8;58(16):5365-5370. doi: 10.1002/anie.201901132. Epub 2019 Mar 13.

PMID:
30747464
5.

Synthesis of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF3, Phosphonium, CN.

VenkatRamami S, Schrock RR, Hoveyda A, Müller P, Tsay C.

Organometallics. 2018 Jun 11;37(11):1641-1644. doi: 10.1021/acs.organomet.8b00168. Epub 2018 May 21.

6.

Molybdenum Complexes that Contain a Calix[6]azacryptand Ligand as Catalysts for Reduction of N2 to Ammonia.

Wickramasinghe LA, Schrock RR, Tsay C, Müller P.

Inorg Chem. 2018 Dec 17;57(24):15566-15574. doi: 10.1021/acs.inorgchem.8b02903. Epub 2018 Dec 5.

PMID:
30516366
7.

Syntheses of Molybdenum Oxo Benzylidene Complexes.

Zhai F, Bukhryakov KV, Schrock RR, Hoveyda AH, Tsay C, Müller P.

J Am Chem Soc. 2018 Oct 24;140(42):13609-13613. doi: 10.1021/jacs.8b09616. Epub 2018 Oct 10.

8.

Beyond fossil fuel-driven nitrogen transformations.

Chen JG, Crooks RM, Seefeldt LC, Bren KL, Bullock RM, Darensbourg MY, Holland PL, Hoffman B, Janik MJ, Jones AK, Kanatzidis MG, King P, Lancaster KM, Lymar SV, Pfromm P, Schneider WF, Schrock RR.

Science. 2018 May 25;360(6391). pii: eaar6611. doi: 10.1126/science.aar6611. Review.

9.

Syntheses of Molybdenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex.

Bukhryakov KV, Schrock RR, Hoveyda AH, Tsay C, Müller P.

J Am Chem Soc. 2018 Feb 28;140(8):2797-2800. doi: 10.1021/jacs.8b00499. Epub 2018 Feb 16.

10.

Synthesis of E- and Z-trisubstituted alkenes by catalytic cross-metathesis.

Nguyen TT, Koh MJ, Mann TJ, Schrock RR, Hoveyda AH.

Nature. 2017 Dec 20;552(7685):347-354. doi: 10.1038/nature25002.

11.

Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes".

Townsend EM, Schrock RR, Hoveyda AH.

J Am Chem Soc. 2017 Nov 15;139(45):16430. doi: 10.1021/jacs.7b11214. Epub 2017 Nov 7. No abstract available.

PMID:
29112412
12.

Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes.

Wickramasinghe LA, Ogawa T, Schrock RR, Müller P.

J Am Chem Soc. 2017 Jul 12;139(27):9132-9135. doi: 10.1021/jacs.7b04800. Epub 2017 Jun 27.

PMID:
28640615
13.

[Effects of a Phone-Based Follow-Up Care After Inpatient Rehabilitation for Breast Cancer Patients - A Randomized Controlled Trial].

Hass HG, Muthny F, Stepien J, Lerch J, von der Marwitz C, Schröck R, Berger D, Tripp J.

Rehabilitation (Stuttg). 2017 Jun;56(3):189-197. doi: 10.1055/s-0042-121384. Epub 2017 Jun 9. German.

PMID:
28599338
14.

EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]MoVL Complexes (L = N-, NH).

Sharma A, Roemelt M, Reithofer M, Schrock RR, Hoffman BM, Neese F.

Inorg Chem. 2017 Jun 19;56(12):6906-6919. doi: 10.1021/acs.inorgchem.7b00364. Epub 2017 Jun 1.

15.

Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2.

Bukhryakov KV, Schrock RR, Hoveyda AH, Müller P, Becker J.

Org Lett. 2017 May 19;19(10):2607-2609. doi: 10.1021/acs.orglett.7b01062. Epub 2017 May 1.

16.

Temporal Artery Temperature Measurement in the Neonate.

Syrkin-Nikolau ME, Johnson KJ, Colaizy TT, Schrock R, Bell EF.

Am J Perinatol. 2017 Aug;34(10):1026-1031. doi: 10.1055/s-0037-1601440. Epub 2017 Apr 10.

17.

Synthesis of cis,syndiotactic-A-alt-B Copolymers from Enantiomerically Pure Endo-2-Substituted-5,6-Norbornenes.

Jang ES, John JM, Schrock RR.

J Am Chem Soc. 2017 Apr 12;139(14):5043-5046. doi: 10.1021/jacs.7b01747. Epub 2017 Mar 31.

PMID:
28355081
18.

Molybdenum chloride catalysts for Z-selective olefin metathesis reactions.

Koh MJ, Nguyen TT, Lam JK, Torker S, Hyvl J, Schrock RR, Hoveyda AH.

Nature. 2017 Feb 2;542(7639):80-85. doi: 10.1038/nature21043. Epub 2017 Jan 23.

19.

Kinetically E-selective macrocyclic ring-closing metathesis.

Shen X, Nguyen TT, Koh MJ, Xu D, Speed AW, Schrock RR, Hoveyda AH.

Nature. 2017 Jan 19;541(7637):380-385. doi: 10.1038/nature20800. Epub 2017 Jan 9.

20.

Syntheses of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCI and Diphenylmethylphosphine.

Bukhryakov KV, VenkatRamani S, Tsay C, Hoveyda A, Schrock RR.

Organometallics. 2017;36(21):4208-4214. doi: 10.1021/acs.organomet.7b00647. Epub 2017 Oct 23.

21.

Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene.

Lam JK, Zhu C, Bukhryakov KV, Müller P, Hoveyda A, Schrock RR.

J Am Chem Soc. 2016 Dec 7;138(48):15774-15783. Epub 2016 Nov 22.

PMID:
27934034
22.

A DFT study of the role of water in the rhodium-catalyzed hydrogenation of acetone.

Polo V, Schrock RR, Oro LA.

Chem Commun (Camb). 2016 Nov 24;52(96):13881-13884.

PMID:
27841377
23.
24.

Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile.

Yu EC, Johnson BM, Townsend EM, Schrock RR, Hoveyda AH.

Angew Chem Int Ed Engl. 2016 Oct 10;55(42):13210-13214. doi: 10.1002/anie.201608087.

25.

Reducing Them Down To Charge Them Up: Low Temperature Catalyst Activation.

Schrock RR.

ACS Cent Sci. 2016 Aug 24;2(8):495-6. doi: 10.1021/acscentsci.6b00223. Epub 2016 Aug 16. No abstract available.

26.

Kinetically controlled E-selective catalytic olefin metathesis.

Nguyen TT, Koh MJ, Shen X, Romiti F, Schrock RR, Hoveyda AH.

Science. 2016 Apr 29;352(6285):569-75. doi: 10.1126/science.aaf4622.

27.

Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis.

Koh MJ, Nguyen TT, Zhang H, Schrock RR, Hoveyda AH.

Nature. 2016 Mar 24;531(7595):459-65. doi: 10.1038/nature17396.

28.

Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions.

Zahim S, Wickramasinghe LA, Evano G, Jabin I, Schrock RR, Müller P.

Org Lett. 2016 Apr 1;18(7):1570-3. doi: 10.1021/acs.orglett.6b00410. Epub 2016 Mar 21.

PMID:
26999005
29.

Metathesis by Molybdenum and Tungsten Catalysts.

Schrock RR.

Chimia (Aarau). 2015;69(7-8):388-92. doi: 10.2533/chimia.2015.388.

PMID:
26507590
30.

Metathesis by Molybdenum and Tungsten Catalysts.

Schrock RR.

Chimia (Aarau). 2015 Aug 19;69(7):388-392. doi: 10.2533/chimia.2015.388.

PMID:
28482970
31.

Synthesis of alternating trans-AB copolymers through ring-opening metathesis polymerization initiated by molybdenum alkylidenes.

Jeong H, John JM, Schrock RR, Hoveyda AH.

J Am Chem Soc. 2015 Feb 18;137(6):2239-42. doi: 10.1021/jacs.5b00221. Epub 2015 Feb 5.

PMID:
25642845
32.

The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry.

Bjornsson R, Neese F, Schrock RR, Einsle O, DeBeer S.

J Biol Inorg Chem. 2015 Mar;20(2):447-60. doi: 10.1007/s00775-014-1230-6. Epub 2014 Dec 31. Review.

33.

Preparation of macrocyclic Z-enoates and (E,Z)- or (Z,E)-dienoates through catalytic stereoselective ring-closing metathesis.

Zhang H, Yu EC, Torker S, Schrock RR, Hoveyda AH.

J Am Chem Soc. 2014 Nov 26;136(47):16493-6. doi: 10.1021/ja510768c. Epub 2014 Nov 17.

34.

Catalytic Z-selective cross-metathesis in complex molecule synthesis: a convergent stereoselective route to disorazole C1.

Speed AW, Mann TJ, O'Brien RV, Schrock RR, Hoveyda AH.

J Am Chem Soc. 2014 Nov 19;136(46):16136-9. doi: 10.1021/ja509973r. Epub 2014 Nov 7.

35.

Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide.

Yu M, Schrock RR, Hoveyda AH.

Angew Chem Int Ed Engl. 2015 Jan 2;54(1):215-20. doi: 10.1002/anie.201409120. Epub 2014 Nov 6.

36.

Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand.

Axtell JC, Schrock RR, Müller P, Smith SJ, Hoveyda AH.

Organometallics. 2014 Oct 13;33(19):5342-5348. Epub 2014 Sep 17.

37.

Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands.

Townsend EM, Hyvl J, Forrest WP, Schrock RR, Müller P, Hoveyda AH.

Organometallics. 2014 Oct 13;33(19):5334-5341. Epub 2014 Sep 22.

38.

Bulky aryloxide ligand stabilizes a heterogeneous metathesis catalyst.

Conley MP, Forrest WP, Mougel V, Copéret C, Schrock RR.

Angew Chem Int Ed Engl. 2014 Dec 15;53(51):14221-4. doi: 10.1002/anie.201408880. Epub 2014 Oct 15.

PMID:
25320050
39.

Stereospecific ring-opening metathesis polymerization of norbornadienes employing tungsten oxo alkylidene initiators.

Forrest WP, Weis JG, John JM, Axtell JC, Simpson JH, Swager TM, Schrock RR.

J Am Chem Soc. 2014 Aug 6;136(31):10910-3. doi: 10.1021/ja506446n. Epub 2014 Jul 22.

PMID:
25036528
40.

Synthesis of stereoregular polymers through ring-opening metathesis polymerization.

Schrock RR.

Acc Chem Res. 2014 Aug 19;47(8):2457-66. doi: 10.1021/ar500139s. Epub 2014 Jun 6.

PMID:
24905960
41.

A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst.

Conley MP, Mougel V, Peryshkov DV, Forrest WP Jr, Gajan D, Lesage A, Emsley L, Copéret C, Schrock RR.

J Am Chem Soc. 2013 Dec 26;135(51):19068-70. doi: 10.1021/ja410052u. Epub 2013 Dec 13.

PMID:
24304004
42.

Q&A: A sustainable chemist. Interview by Jonathan Moerdyk.

Schrock R.

Nature. 2013 Oct 17;502(7471):S59. doi: 10.1038/502S59a. No abstract available.

PMID:
24132336
43.

Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes.

Townsend EM, Kilyanek SM, Schrock RR, Müller P, Smith SJ, Hoveyda AH.

Organometallics. 2013 Aug 26;32(16):4612-4617.

44.

Synthesis of a TREN in which the aryl substituents are part of a 45 atom macrocycle.

Cain MF, Forrest WP Jr, Peryshkov DV, Schrock RR, Müller P.

J Am Chem Soc. 2013 Oct 16;135(41):15338-41. doi: 10.1021/ja408964g. Epub 2013 Oct 3.

PMID:
24074292
45.

Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis.

Dobereiner GE, Yuan J, Schrock RR, Goldman AS, Hackenberg JD.

J Am Chem Soc. 2013 Aug 28;135(34):12572-5. doi: 10.1021/ja4066392. Epub 2013 Aug 8.

PMID:
23909821
46.

Turkey must end violent response to protests.

Altindis E, Alpar MA, Aksay E, Beckwith J, Bökel C, Curl RF, Darnell RB, Elledge SJ, Erman B, Frahm J, Goff SP, Greengard P, Hoffmann R, Ilhan B, Kaslin J, Lipkin SM, Poulopoulou C, Raz E, Rubin MA, Salturk M, Schrock RR, Trautmann A, Unutmaz D, Weinstein H, Kizil C.

Science. 2013 Jul 19;341(6143):236. doi: 10.1126/science.341.6143.236-a. No abstract available. Erratum in: Science. 2013 Aug 30;341(6149):959.

PMID:
23869001
48.

Catalytic Z-selective cross-metathesis with secondary silyl- and benzyl-protected allylic ethers: mechanistic aspects and applications to natural product synthesis.

Mann TJ, Speed AW, Schrock RR, Hoveyda AH.

Angew Chem Int Ed Engl. 2013 Aug 5;52(32):8395-400. doi: 10.1002/anie.201302538. Epub 2013 Jun 21. No abstract available.

49.

Alkyne metathesis by molybdenum and tungsten alkylidyne complexes.

Schrock RR.

Chem Commun (Camb). 2013 Jun 21;49(49):5529-31. doi: 10.1039/c3cc42609b.

PMID:
23673995
50.

Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis.

Kiesewetter ET, O'Brien RV, Yu EC, Meek SJ, Schrock RR, Hoveyda AH.

J Am Chem Soc. 2013 Apr 24;135(16):6026-9. doi: 10.1021/ja403188t. Epub 2013 Apr 15.

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