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Science. 1976 Jun 18;192(4245):1231-4.

Atmospheric carbon tetrachloride: another man-made pollutant.

Abstract

On the basis of an analysis of historic worldwide emissions and removal mechanisms for carbon tetrachloride, a possible precursor for stratospheric ozone destruction, it has been demonstrated that the present atmospheric loading and distribution of carbon tetrachloride is primarily attributable to man-made emissions and no natural sources need be invoked to explain its presence in the atmosphere.

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