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Items: 7


Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization.

Zhao S, Gensch T, Murray B, Niemeyer ZL, Sigman MS, Biscoe MR.

Science. 2018 Nov 9;362(6415):670-674. doi: 10.1126/science.aat2299. Epub 2018 Sep 20.


Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis.

Christian AH, Niemeyer ZL, Sigman MS, Toste FD.

ACS Catal. 2017 Jun 2;7(6):3973-3978. doi: 10.1021/acscatal.7b00757. Epub 2017 May 10.


Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates.

Bischoff AJ, Nelson BM, Niemeyer ZL, Sigman MS, Movassaghi M.

J Am Chem Soc. 2017 Nov 1;139(43):15539-15547. doi: 10.1021/jacs.7b09541. Epub 2017 Oct 18.


Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

Niemeyer ZL, Pindi S, Khrakovsky DA, Kuzniewski CN, Hong CM, Joyce LA, Sigman MS, Toste FD.

J Am Chem Soc. 2017 Sep 20;139(37):12943-12946. doi: 10.1021/jacs.7b08791. Epub 2017 Sep 8.


Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines.

Keylor MH, Niemeyer ZL, Sigman MS, Tan KL.

J Am Chem Soc. 2017 Aug 9;139(31):10613-10616. doi: 10.1021/jacs.7b05409. Epub 2017 Jul 27.


Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes.

Niemeyer ZL, Milo A, Hickey DP, Sigman MS.

Nat Chem. 2016 Jun;8(6):610-7. doi: 10.1038/nchem.2501. Epub 2016 May 16.


Redox mediators in visible light photocatalysis: photocatalytic radical thiol-ene additions.

Tyson EL, Niemeyer ZL, Yoon TP.

J Org Chem. 2014 Feb 7;79(3):1427-36. doi: 10.1021/jo500031g. Epub 2014 Jan 27.

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