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Hydroxyl-rich macromolecules enable the bio-inspired synthesis of single crystal nanocomposites.

Kim YY, Darkins R, Broad A, Kulak AN, Holden MA, Nahi O, Armes SP, Tang CC, Thompson RF, Marin F, Duffy DM, Meldrum FC.

Nat Commun. 2019 Dec 12;10(1):5682. doi: 10.1038/s41467-019-13422-9.


Super-Resolution Microscopy Reveals Shape and Distribution of Dislocations in Single-Crystal Nanocomposites.

Ihli J, Green DC, Lynch C, Holden MA, Lee PA, Zhang S, Robinson IK, Webb SED, Meldrum FC.

Angew Chem Int Ed Engl. 2019 Nov 25;58(48):17328-17334. doi: 10.1002/anie.201905293. Epub 2019 Oct 31. Review.


How Many Phosphoric Acid Units Are Required to Ensure Uniform Occlusion of Sterically Stabilized Nanoparticles within Calcite?

Douverne M, Ning Y, Tatani A, Meldrum FC, Armes SP.

Angew Chem Int Ed Engl. 2019 Jun 24;58(26):8692-8697. doi: 10.1002/anie.201901307. Epub 2019 May 22.


Visualization of the effect of additives on the nanostructures of individual bio-inspired calcite crystals.

Ihli J, Clark JN, Kanwal N, Kim YY, Holden MA, Harder RJ, Tang CC, Ashbrook SE, Robinson IK, Meldrum FC.

Chem Sci. 2018 Nov 9;10(4):1176-1185. doi: 10.1039/c8sc03733g. eCollection 2019 Jan 28.


High-speed imaging of ice nucleation in water proves the existence of active sites.

Holden MA, Whale TF, Tarn MD, O'Sullivan D, Walshaw RD, Murray BJ, Meldrum FC, Christenson HK.

Sci Adv. 2019 Feb 1;5(2):eaav4316. doi: 10.1126/sciadv.aav4316. eCollection 2019 Feb.


What Dictates the Spatial Distribution of Nanoparticles within Calcite?

Ning Y, Han L, Douverne M, Penfold NJW, Derry MJ, Meldrum FC, Armes SP.

J Am Chem Soc. 2019 Feb 13;141(6):2481-2489. doi: 10.1021/jacs.8b12291. Epub 2019 Jan 30.


Model Anionic Block Copolymer Vesicles Provide Important Design Rules for Efficient Nanoparticle Occlusion within Calcite.

Ning Y, Han L, Derry MJ, Meldrum FC, Armes SP.

J Am Chem Soc. 2019 Feb 13;141(6):2557-2567. doi: 10.1021/jacs.8b12507. Epub 2019 Jan 29.


Spatially Controlled Occlusion of Polymer-Stabilized Gold Nanoparticles within ZnO.

Ning Y, Fielding LA, Nutter J, Kulak AN, Meldrum FC, Armes SP.

Angew Chem Int Ed Engl. 2019 Mar 22;58(13):4302-4307. doi: 10.1002/anie.201814492. Epub 2019 Feb 20.


Controlling the fluorescence and room-temperature phosphorescence behaviour of carbon nanodots with inorganic crystalline nanocomposites.

Green DC, Holden MA, Levenstein MA, Zhang S, Johnson BRG, Gala de Pablo J, Ward A, Botchway SW, Meldrum FC.

Nat Commun. 2019 Jan 14;10(1):206. doi: 10.1038/s41467-018-08214-6.


Anionic block copolymer vesicles act as Trojan horses to enable efficient occlusion of guest species into host calcite crystals.

Ning Y, Whitaker DJ, Mable CJ, Derry MJ, Penfold NJW, Kulak AN, Green DC, Meldrum FC, Armes SP.

Chem Sci. 2018 Sep 10;9(44):8396-8401. doi: 10.1039/c8sc03623c. eCollection 2018 Nov 28.


Confinement generates single-crystal aragonite rods at room temperature.

Zeng M, Kim YY, Anduix-Canto C, Frontera C, Laundy D, Kapur N, Christenson HK, Meldrum FC.

Proc Natl Acad Sci U S A. 2018 Jul 24;115(30):7670-7675. doi: 10.1073/pnas.1718926115. Epub 2018 Jul 2.


Amino Acid Assisted Incorporation of Dye Molecules within Calcite Crystals.

Marzec B, Green DC, Holden MA, Coté AS, Ihli J, Khalid S, Kulak A, Walker D, Tang C, Duffy DM, Kim YY, Meldrum FC.

Angew Chem Int Ed Engl. 2018 Jul 9;57(28):8623-8628. doi: 10.1002/anie.201804365. Epub 2018 Jun 10.


The role of phase separation and related topography in the exceptional ice-nucleating ability of alkali feldspars.

Whale TF, Holden MA, Kulak AN, Kim YY, Meldrum FC, Christenson HK, Murray BJ.

Phys Chem Chem Phys. 2017 Nov 29;19(46):31186-31193. doi: 10.1039/c7cp04898j.


Passive Picoinjection Enables Controlled Crystallization in a Droplet Microfluidic Device.

Li S, Zeng M, Gaule T, McPherson MJ, Meldrum FC.

Small. 2017 Nov;13(41). doi: 10.1002/smll.201702154. Epub 2017 Sep 5.


The Effect of Additives on the Early Stages of Growth of Calcite Single Crystals.

Kim YY, Freeman CL, Gong X, Levenstein MA, Wang Y, Kulak A, Anduix-Canto C, Lee PA, Li S, Chen L, Christenson HK, Meldrum FC.

Angew Chem Int Ed Engl. 2017 Sep 18;56(39):11885-11890. doi: 10.1002/anie.201706800. Epub 2017 Aug 18.


Synchrotron FTIR mapping of mineralization in a microfluidic device.

Li S, Ihli J, Marchant WJ, Zeng M, Chen L, Wehbe K, Cinque G, Cespedes O, Kapur N, Meldrum FC.

Lab Chip. 2017 May 2;17(9):1616-1624. doi: 10.1039/c6lc01393g.


Virus-directed formation of electrocatalytically active nanoparticle-based Co3O4 tubes.

Schenk AS, Eiben S, Goll M, Reith L, Kulak AN, Meldrum FC, Jeske H, Wege C, Ludwigs S.

Nanoscale. 2017 May 18;9(19):6334-6345. doi: 10.1039/c7nr00508c.


Observing the formation of ice and organic crystals in active sites.

Campbell JM, Meldrum FC, Christenson HK.

Proc Natl Acad Sci U S A. 2017 Jan 31;114(5):810-815. doi: 10.1073/pnas.1617717114. Epub 2016 Dec 19.


3D visualization of additive occlusion and tunable full-spectrum fluorescence in calcite.

Green DC, Ihli J, Thornton PD, Holden MA, Marzec B, Kim YY, Kulak AN, Levenstein MA, Tang C, Lynch C, Webb SE, Tynan CJ, Meldrum FC.

Nat Commun. 2016 Nov 18;7:13524. doi: 10.1038/ncomms13524.


Combinatorial microfluidic droplet engineering for biomimetic material synthesis.

Bawazer LA, McNally CS, Empson CJ, Marchant WJ, Comyn TP, Niu X, Cho S, McPherson MJ, Binks BP, deMello A, Meldrum FC.

Sci Adv. 2016 Oct 7;2(10):e1600567. eCollection 2016 Oct.


Occlusion of Sulfate-Based Diblock Copolymer Nanoparticles within Calcite: Effect of Varying the Surface Density of Anionic Stabilizer Chains.

Ning Y, Fielding LA, Ratcliffe LP, Wang YW, Meldrum FC, Armes SP.

J Am Chem Soc. 2016 Sep 14;138(36):11734-42. doi: 10.1021/jacs.6b05563. Epub 2016 Aug 30.


Strain-relief by single dislocation loops in calcite crystals grown on self-assembled monolayers.

Ihli J, Clark JN, Côté AS, Kim YY, Schenk AS, Kulak AN, Comyn TP, Chammas O, Harder RJ, Duffy DM, Robinson IK, Meldrum FC.

Nat Commun. 2016 Jun 15;7:11878. doi: 10.1038/ncomms11878.


Tuning hardness in calcite by incorporation of amino acids.

Kim YY, Carloni JD, Demarchi B, Sparks D, Reid DG, Kunitake ME, Tang CC, Duer MJ, Freeman CL, Pokroy B, Penkman K, Harding JH, Estroff LA, Baker SP, Meldrum FC.

Nat Mater. 2016 Aug;15(8):903-10. doi: 10.1038/nmat4631. Epub 2016 May 2.


Direct observation of mineral-organic composite formation reveals occlusion mechanism.

Rae Cho K, Kim YY, Yang P, Cai W, Pan H, Kulak AN, Lau JL, Kulshreshtha P, Armes SP, Meldrum FC, De Yoreo JJ.

Nat Commun. 2016 Jan 6;7:10187. doi: 10.1038/ncomms10187.


The Crystal Hotel: A Microfluidic Approach to Biomimetic Crystallization.

Gong X, Wang YW, Ihli J, Kim YY, Li S, Walshaw R, Chen L, Meldrum FC.

Adv Mater. 2015 Dec 2;27(45):7395-400. doi: 10.1002/adma.201503931. Epub 2015 Oct 19.


CRYSTAL GROWTH. Crystallization by particle attachment in synthetic, biogenic, and geologic environments.

De Yoreo JJ, Gilbert PU, Sommerdijk NA, Penn RL, Whitelam S, Joester D, Zhang H, Rimer JD, Navrotsky A, Banfield JF, Wallace AF, Michel FM, Meldrum FC, Cölfen H, Dove PM.

Science. 2015 Jul 31;349(6247):aaa6760. doi: 10.1126/science.aaa6760. Review.


Three-dimensional imaging of dislocation propagation during crystal growth and dissolution.

Clark JN, Ihli J, Schenk AS, Kim YY, Kulak AN, Campbell JM, Nisbet G, Meldrum FC, Robinson IK.

Nat Mater. 2015 Aug;14(8):780-784. doi: 10.1038/nmat4320. Epub 2015 Jun 1.


Genetic algorithm-guided discovery of additive combinations that direct quantum dot assembly.

Bawazer LA, Ihli J, Comyn TP, Critchley K, Empson CJ, Meldrum FC.

Adv Mater. 2015 Jan 14;27(2):223-7. doi: 10.1002/adma.201403185. Epub 2014 Nov 25.


A critical analysis of calcium carbonate mesocrystals.

Kim YY, Schenk AS, Ihli J, Kulak AN, Hetherington NB, Tang CC, Schmahl WW, Griesshaber E, Hyett G, Meldrum FC.

Nat Commun. 2014 Jul 11;5:4341. doi: 10.1038/ncomms5341.


Oxygen spectroscopy and polarization-dependent imaging contrast (PIC)-mapping of calcium carbonate minerals and biominerals.

DeVol RT, Metzler RA, Kabalah-Amitai L, Pokroy B, Politi Y, Gal A, Addadi L, Weiner S, Fernandez-Martinez A, Demichelis R, Gale JD, Ihli J, Meldrum FC, Blonsky AZ, Killian CE, Salling CB, Young AT, Marcus MA, Scholl A, Doran A, Jenkins C, Bechtel HA, Gilbert PU.

J Phys Chem B. 2014 Jul 17;118(28):8449-57. doi: 10.1021/jp503700g. Epub 2014 Jun 10.


Confinement stabilises single crystal vaterite rods.

Schenk AS, Albarracin EJ, Kim YY, Ihli J, Meldrum FC.

Chem Commun (Camb). 2014 May 11;50(36):4729-32. doi: 10.1039/c4cc01093k.


Correlation between anisotropy and lattice distortions in single crystal calcite nanowires grown in confinement.

Verch A, Côté AS, Darkins R, Kim YY, van de Locht R, Meldrum FC, Duffy DM, Kröger R.

Small. 2014 Jul 9;10(13):2697-702. doi: 10.1002/smll.201303839. Epub 2014 Mar 18.


Formation and Structure of Calcium Carbonate Thin Films and Nanofibers Precipitated in the Presence of Poly(Allylamine Hydrochloride) and Magnesium Ions.

Cantaert B, Verch A, Kim YY, Ludwig H, Paunov VN, Kröger R, Meldrum FC.

Chem Mater. 2013 Dec 23;25(24):4994-5003. Epub 2013 Dec 6.


Dehydration and crystallization of amorphous calcium carbonate in solution and in air.

Ihli J, Wong WC, Noel EH, Kim YY, Kulak AN, Christenson HK, Duer MJ, Meldrum FC.

Nat Commun. 2014;5:3169. doi: 10.1038/ncomms4169.


The Role of Poly(Aspartic Acid) in the Precipitation of Calcium Phosphate in Confinement.

Cantaert B, Beniash E, Meldrum FC.

J Mater Chem B. 2013 Dec 28;1(48). doi: 10.1039/C3TB21296C.


Efficient selection of biomineralizing DNA aptamers using deep sequencing and population clustering.

Bawazer LA, Newman AM, Gu Q, Ibish A, Arcila M, Cooper JB, Meldrum FC, Morse DE.

ACS Nano. 2014 Jan 28;8(1):387-95. doi: 10.1021/nn404448s. Epub 2013 Dec 23.


Bio-inspired formation of functional calcite/metal oxide nanoparticle composites.

Kim YY, Schenk AS, Walsh D, Kulak AN, Cespedes O, Meldrum FC.

Nanoscale. 2014 Jan 21;6(2):852-9. doi: 10.1039/c3nr05081e.


Colouring crystals with inorganic nanoparticles.

Kulak AN, Yang P, Kim YY, Armes SP, Meldrum FC.

Chem Commun (Camb). 2014 Jan 4;50(1):67-9. doi: 10.1039/c3cc47904h. Epub 2013 Nov 8.


Nanoscale confinement controls the crystallization of calcium phosphate: relevance to bone formation.

Cantaert B, Beniash E, Meldrum FC.

Chemistry. 2013 Oct 25;19(44):14918-24. doi: 10.1002/chem.201302835. Epub 2013 Sep 20.


Freeze-drying yields stable and pure amorphous calcium carbonate (ACC).

Ihli J, Kulak AN, Meldrum FC.

Chem Commun (Camb). 2013 Apr 18;49(30):3134-6. doi: 10.1039/c3cc40807h. Epub 2013 Mar 11.


Simple photosystem II water oxidation centre analogues in visible light oxygen and H+ generation.

Kim YY, Williams D, Meldrum FC, Walsh D.

Small. 2013 Jan 14;9(1):61-6. doi: 10.1002/smll.201201451. Epub 2012 Oct 5.


Crystal Nucleation without Supersaturation.

Kovács T, Meldrum FC, Christenson HK.

J Phys Chem Lett. 2012 Jun 21;3(12):1602-6. doi: 10.1021/jz300450g. Epub 2012 Jun 1.


High-magnesian calcite mesocrystals: a coordination chemistry approach.

Lenders JJ, Dey A, Bomans PH, Spielmann J, Hendrix MM, de With G, Meldrum FC, Harder S, Sommerdijk NA.

J Am Chem Soc. 2012 Jan 18;134(2):1367-73. doi: 10.1021/ja210791p. Epub 2012 Jan 6.


The use of cationic surfactants to control the structure of zinc oxide films prepared by chemical vapour deposition.

McNally CS, Turner DP, Kulak AN, Meldrum FC, Hyett G.

Chem Commun (Camb). 2012 Feb 1;48(10):1490-2. doi: 10.1039/c2cc14468a. Epub 2011 Dec 14.


Capillarity creates single-crystal calcite nanowires from amorphous calcium carbonate.

Kim YY, Hetherington NB, Noel EH, Kröger R, Charnock JM, Christenson HK, Meldrum FC.

Angew Chem Int Ed Engl. 2011 Dec 23;50(52):12572-7. doi: 10.1002/anie.201104407. Epub 2011 Nov 8.


A new precipitation pathway for calcium sulfate dihydrate (gypsum) via amorphous and hemihydrate intermediates.

Wang YW, Kim YY, Christenson HK, Meldrum FC.

Chem Commun (Camb). 2012 Jan 14;48(4):504-6. doi: 10.1039/c1cc14210k. Epub 2011 Oct 4.


An artificial biomineral formed by incorporation of copolymer micelles in calcite crystals.

Kim YY, Ganesan K, Yang P, Kulak AN, Borukhin S, Pechook S, Ribeiro L, Kröger R, Eichhorn SJ, Armes SP, Pokroy B, Meldrum FC.

Nat Mater. 2011 Sep 4;10(11):890-6. doi: 10.1038/nmat3103.


Synthesis of macroporous calcium carbonate/magnetite nanocomposites and their application in photocatalytic water splitting.

Walsh D, Kim YY, Miyamoto A, Meldrum FC.

Small. 2011 Aug 8;7(15):2168-72. doi: 10.1002/smll.201100268. Epub 2011 May 31. No abstract available.


Early stages of crystallization of calcium carbonate revealed in picoliter droplets.

Stephens CJ, Kim YY, Evans SD, Meldrum FC, Christenson HK.

J Am Chem Soc. 2011 Apr 13;133(14):5210-3. doi: 10.1021/ja200309m. Epub 2011 Mar 22.


Crystallization and formation mechanisms of nanostructures.

Meldrum FC, Colfen H.

Nanoscale. 2010 Nov;2(11):2326-7. doi: 10.1039/c0nr90029j. Epub 2010 Oct 14. No abstract available.


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