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Items: 39

1.

Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes.

Schiegerl LJ, Melaimi M, Tolentino DR, Klein W, Bertrand G, Fässler TF.

Inorg Chem. 2019 Mar 4;58(5):3256-3264. doi: 10.1021/acs.inorgchem.8b03338. Epub 2019 Feb 11.

PMID:
30741546
2.

Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes.

Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G.

J Am Chem Soc. 2018 Jul 25;140(29):9255-9260. doi: 10.1021/jacs.8b05518. Epub 2018 Jul 13.

PMID:
29954178
3.

Controlled Expansion of a Strong-Field Iron Nitride Cluster: Multi-Site Ligand Substitution as a Strategy for Activating Interstitial Nitride Nucleophilicity.

Drance MJ, Mokhtarzadeh CC, Melaimi M, Agnew DW, Moore CE, Rheingold AL, Figueroa JS.

Angew Chem Int Ed Engl. 2018 Oct 1;57(40):13057-13061. doi: 10.1002/anie.201801206. Epub 2018 May 24.

PMID:
29719103
4.

Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes.

Hansmann MM, Melaimi M, Munz D, Bertrand G.

J Am Chem Soc. 2018 Feb 21;140(7):2546-2554. doi: 10.1021/jacs.7b11183. Epub 2018 Feb 9.

PMID:
29382199
5.

Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes.

Hansmann MM, Melaimi M, Bertrand G.

J Am Chem Soc. 2018 Feb 14;140(6):2206-2213. doi: 10.1021/jacs.7b11184. Epub 2018 Feb 1.

PMID:
29342351
6.

Crystalline Monomeric Allenyl/Propargyl Radical.

Hansmann MM, Melaimi M, Bertrand G.

J Am Chem Soc. 2017 Nov 8;139(44):15620-15623. doi: 10.1021/jacs.7b09622. Epub 2017 Oct 25.

PMID:
29046060
7.

Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs.

Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G.

J Am Chem Soc. 2017 Jun 14;139(23):7753-7756. doi: 10.1021/jacs.7b04640. Epub 2017 Jun 1.

PMID:
28541687
8.

Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments.

Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G.

Angew Chem Int Ed Engl. 2017 Aug 14;56(34):10046-10068. doi: 10.1002/anie.201702148. Epub 2017 Jun 12. Review.

PMID:
28376253
9.

NHC-CAAC Heterodimers with Three Stable Oxidation States.

Munz D, Chu J, Melaimi M, Bertrand G.

Angew Chem Int Ed Engl. 2016 Oct 4;55(41):12886-90. doi: 10.1002/anie.201607537. Epub 2016 Sep 15.

PMID:
27628756
10.

Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry.

Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G.

J Am Chem Soc. 2016 Jun 29;138(25):7884-7. doi: 10.1021/jacs.6b05221. Epub 2016 Jun 20.

PMID:
27304485
11.

Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes.

Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS.

Chemistry. 2016 Jun 27;22(27):9404-9. doi: 10.1002/chem.201601254. Epub 2016 May 30.

PMID:
27238837
12.

Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2.

Peltier JL, Jazzar R, Melaimi M, Bertrand G.

Chem Commun (Camb). 2016 Feb 14;52(13):2733-5. doi: 10.1039/c5cc10427k.

PMID:
26757745
13.

Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes.

Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G.

Chem Sci. 2016 Jan 1;7(1):150-154. doi: 10.1039/c5sc03654b. Epub 2015 Nov 16.

14.

The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition.

Jin L, Romero EA, Melaimi M, Bertrand G.

J Am Chem Soc. 2015 Dec 23;137(50):15696-8. doi: 10.1021/jacs.5b11028. Epub 2015 Dec 4.

PMID:
26611196
15.

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction".

Jin L, Tolentino DR, Melaimi M, Bertrand G.

Sci Adv. 2015 Jun 12;1(5):e1500304. doi: 10.1126/sciadv.1500304. eCollection 2015 Jun.

16.

Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals.

Rao B, Tang H, Zeng X, Liu L, Melaimi M, Bertrand G.

Angew Chem Int Ed Engl. 2015 Dec 1;54(49):14915-9. doi: 10.1002/anie.201507844. Epub 2015 Oct 12.

PMID:
26457345
17.

Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical.

Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G.

Chemistry. 2015 Jun 1;21(23):8441-6. doi: 10.1002/chem.201500740. Epub 2015 Apr 29.

PMID:
25925367
18.

Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3.

Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G.

Angew Chem Int Ed Engl. 2015 May 11;54(20):6008-11. doi: 10.1002/anie.201500224. Epub 2015 Mar 20.

PMID:
25802096
19.

A simple access to transition metal cyclopropenylidene complexes.

Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS.

Chem Commun (Camb). 2015 Mar 21;51(23):4778-81. doi: 10.1039/c4cc10375k.

PMID:
25621852
20.

Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine.

Tolentino DR, Jin L, Melaimi M, Bertrand G.

Chem Asian J. 2015 Oct;10(10):2139-42. doi: 10.1002/asia.201403408. Epub 2015 Feb 5.

PMID:
25597889
21.

Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis.

Marx VM, Sullivan AH, Melaimi M, Virgil SC, Keitz BK, Weinberger DS, Bertrand G, Grubbs RH.

Angew Chem Int Ed Engl. 2015 Feb 2;54(6):1919-23. doi: 10.1002/anie.201410797. Epub 2014 Dec 17.

22.

Gold-catalyzed hydroarylation of alkenes with dialkylanilines.

Hu X, Martin D, Melaimi M, Bertrand G.

J Am Chem Soc. 2014 Oct 1;136(39):13594-7. doi: 10.1021/ja507788r. Epub 2014 Sep 19.

PMID:
25222130
23.

Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts.

Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G.

Angew Chem Int Ed Engl. 2014 Aug 18;53(34):9059-63. doi: 10.1002/anie.201404665. Epub 2014 Jul 1.

PMID:
24985149
24.

An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].

Ruiz DA, Melaimi M, Bertrand G.

Chem Commun (Camb). 2014 Jul 25;50(58):7837-9. doi: 10.1039/c4cc03497j.

PMID:
24909943
25.

Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes.

Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G.

J Am Chem Soc. 2014 Apr 30;136(17):6235-8. doi: 10.1021/ja502521b. Epub 2014 Apr 17.

PMID:
24731250
26.

Carbodicarbenes, carbon(0) derivatives, can dimerize.

Ruiz DA, Melaimi M, Bertrand G.

Chem Asian J. 2013 Dec;8(12):2940-2. doi: 10.1002/asia.201300887. Epub 2013 Aug 19. No abstract available.

PMID:
23960023
27.

Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes.

Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G.

Angew Chem Int Ed Engl. 2013 Aug 19;52(34):8964-7. doi: 10.1002/anie.201304820. Epub 2013 Jul 16. No abstract available.

PMID:
23861304
28.

Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion.

Ruiz DA, Ung G, Melaimi M, Bertrand G.

Angew Chem Int Ed Engl. 2013 Jul 15;52(29):7590-2. doi: 10.1002/anie.201303457. Epub 2013 Jun 13.

29.

A Brief Survey of our Contribution to Stable Carbene Chemistry.

Martin D, Melaimi M, Soleilhavoup M, Bertrand G.

Organometallics. 2011 Oct 24;30(20):5304-5313. Epub 2011 Sep 22.

30.

Stable cyclic carbenes and related species beyond diaminocarbenes.

Melaimi M, Soleilhavoup M, Bertrand G.

Angew Chem Int Ed Engl. 2010 Nov 15;49(47):8810-49. doi: 10.1002/anie.201000165. Review.

31.

A crystalline phosphinyl radical cation.

Back O, Celik MA, Frenking G, Melaimi M, Donnadieu B, Bertrand G.

J Am Chem Soc. 2010 Aug 4;132(30):10262-3. doi: 10.1021/ja1046846.

PMID:
20662507
32.

Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene.

Melaimi M, Parameswaran P, Donnadieu B, Frenking G, Bertrand G.

Angew Chem Int Ed Engl. 2009;48(26):4792-5. doi: 10.1002/anie.200901117.

PMID:
19472243
33.

Structural and electrochemical investigations of the high fluoride affinity of sterically hindered 1,8-bis(boryl)naphthalenes.

Melaïmi M, Solé S, Chiu CW, Wang H, Gabbaï FP.

Inorg Chem. 2006 Oct 2;45(20):8136-43.

PMID:
16999411
34.

Hybrid Lewis acid/hydrogen-bond donor receptor for fluoride.

Hudnall TW, Melaïmi M, Gabbaï FP.

Org Lett. 2006 Jun 22;8(13):2747-9.

PMID:
16774247
35.

A heteronuclear bidentate Lewis acid as a phosphorescent fluoride sensor.

Melaimi M, Gabbaï FP.

J Am Chem Soc. 2005 Jul 13;127(27):9680-1.

PMID:
15998060
36.
37.

Synthesis of phosphole-2,5-dicarboxylic acids via a [1,5]-shift of carbon dioxide around the phosphole nucleus.

Melaimi M, Ricard L, Mathey F, Le Floch P.

Org Lett. 2002 Apr 18;4(8):1245-7.

PMID:
11950333
38.

An efficient synthesis of a new series of acyclonucleosides starting from beta-amino alcohols.

Agami C, Dechoux L, Hamon L, Melaimi M.

J Org Chem. 2000 Oct 6;65(20):6666-9.

PMID:
11052116
39.

An efficient synthesis of pyrimidines from beta-amino alcohols.

Agami C, Dechoux L, Melaimi M.

Org Lett. 2000 Mar 9;2(5):633-4.

PMID:
10814396

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