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Items: 36

1.

Vinyl Carbocations Generated under Basic Conditions and Their Intramolecular C-H Insertion Reactions.

Wigman B, Popov S, Bagdasarian AL, Shao B, Benton TR, Williams CG, Fisher SP, Lavallo V, Houk KN, Nelson HM.

J Am Chem Soc. 2019 Jun 12;141(23):9140-9144. doi: 10.1021/jacs.9b02110. Epub 2019 May 29.

2.

Comparative Study of Mg(CB11H12)2 and Mg(TFSI)2 at the Magnesium/Electrolyte Interface.

Jay R, Tomich AW, Zhang J, Zhao Y, De Gorostiza A, Lavallo V, Guo J.

ACS Appl Mater Interfaces. 2019 Mar 27;11(12):11414-11420. doi: 10.1021/acsami.9b00037. Epub 2019 Mar 20.

PMID:
30860349
3.

Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage.

Fisher SP, Tomich AW, Lovera SO, Kleinsasser JF, Guo J, Asay MJ, Nelson HM, Lavallo V.

Chem Rev. 2019 Jul 24;119(14):8262-8290. doi: 10.1021/acs.chemrev.8b00551. Epub 2019 Feb 1.

PMID:
30707011
4.

Teaching an old dog new tricks: new directions in fundamental and applied closo-carborane anion chemistry.

Fisher SP, Tomich AW, Guo J, Lavallo V.

Chem Commun (Camb). 2019 Feb 5;55(12):1684-1701. doi: 10.1039/c8cc09663e.

PMID:
30666325
5.

Reversible Silver Electrodeposition from Boron Cluster Ionic Liquid (BCIL) Electrolytes.

Dziedzic RM, Waddington MA, Lee SE, Kleinsasser J, Plumley JB, Ewing WC, Bosley BD, Lavallo V, Peng TL, Spokoyny AM.

ACS Appl Mater Interfaces. 2018 Feb 28;10(8):6825-6830. doi: 10.1021/acsami.7b19302. Epub 2018 Feb 16.

PMID:
29405694
6.

Fusing Dicarbollide Ions with N-Heterocyclic Carbenes.

Estrada J, Lavallo V.

Angew Chem Int Ed Engl. 2017 Aug 7;56(33):9906-9909. doi: 10.1002/anie.201705857. Epub 2017 Jul 17.

PMID:
28651037
7.

Below the 12-vertex: 10-vertex carborane anions as non-corrosive, halide free, electrolytes for rechargeable Mg batteries.

McArthur SG, Jay R, Geng L, Guo J, Lavallo V.

Chem Commun (Camb). 2017 Apr 18;53(32):4453-4456. doi: 10.1039/c7cc01570d.

8.

Anionic and zwitterionic carboranyl N-heterocyclic carbene Au(i) complexes.

Fisher SP, El-Hellani A, Tham FS, Lavallo V.

Dalton Trans. 2016 Jun 14;45(24):9762-5. doi: 10.1039/c6dt00551a.

PMID:
26922968
9.

Quantitation of Alpha-Glucosidase Activity Using Fluorinated Carbohydrate Array and MALDI-TOF-MS.

Yang H, Chan AL, LaVallo V, Cheng Q.

ACS Appl Mater Interfaces. 2016 Feb 3;8(4):2872-8. doi: 10.1021/acsami.5b12518. Epub 2016 Jan 25.

PMID:
26760440
10.

Dehydrogenation of icosahedral carborane anions via gas-phase collisional activation.

Hamdy OM, Pham HT, McArthur SG, Lavallo V, Julian RR.

Rapid Commun Mass Spectrom. 2016 May 30;30(10):1223-1227. doi: 10.1002/rcm.7547.

PMID:
28328027
11.

Inductive effects of 10 and 12-vertex closo-carborane anions: cluster size and charge make a difference.

Estrada J, Lugo CA, McArthur SG, Lavallo V.

Chem Commun (Camb). 2016 Jan 31;52(9):1824-6. doi: 10.1039/c5cc08377j.

PMID:
26671630
12.

Synthesis and reactivity of a zwitterionic palladium allyl complex supported by a perchlorinated carboranyl phosphine.

Estrada J, Woen DH, Tham FS, Miyake GM, Lavallo V.

Inorg Chem. 2015 Jun 1;54(11):5142-4. doi: 10.1021/acs.inorgchem.5b00576. Epub 2015 May 12.

PMID:
25965071
13.

Synthesis of a hybrid m-terphenyl/o-carborane building block: applications in phosphine ligand design.

Lugo CA, Moore CE, Rheingold AL, Lavallo V.

Inorg Chem. 2015 Mar 2;54(5):2094-6. doi: 10.1021/ic5030636. Epub 2015 Feb 10.

PMID:
25668570
14.

Synthesis of unsymmetrical N-carboranyl NHCs: directing effect of the carborane anion.

Asay MJ, Fisher SP, Lee SE, Tham FS, Borchardt D, Lavallo V.

Chem Commun (Camb). 2015 Mar 28;51(25):5359-62. doi: 10.1039/c4cc08267b.

PMID:
25387660
15.

Fusing N-heterocyclic carbenes with carborane anions.

El-Hellani A, Lavallo V.

Angew Chem Int Ed Engl. 2014 Apr 22;53(17):4489-93. doi: 10.1002/anie.201402445. Epub 2014 Mar 24.

PMID:
24664969
16.

Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates.

Martin D, Canac Y, Lavallo V, Bertrand G.

J Am Chem Soc. 2014 Apr 2;136(13):5023-30. doi: 10.1021/ja412981x. Epub 2014 Mar 24.

PMID:
24634983
17.

Observation of room temperature B-Cl activation of the HCB11Cl11(-) anion and isolation of a stable anionic carboranyl phosphazide.

Chan AL, Fajardo J Jr, Wright JH 2nd, Asay M, Lavallo V.

Inorg Chem. 2013 Nov 4;52(21):12308-10. doi: 10.1021/ic402436w. Epub 2013 Oct 18.

PMID:
24138749
18.

Isolation of a carborane-fused triazole radical anion.

Asay M, Kefalidis CE, Estrada J, Weinberger DS, Wright J, Moore CE, Rheingold AL, Maron L, Lavallo V.

Angew Chem Int Ed Engl. 2013 Oct 25;52(44):11560-3. doi: 10.1002/anie.201306764. Epub 2013 Sep 17.

PMID:
24106045
19.

Click-like reactions with the inert HCB11Cl11(-) anion lead to carborane-fused heterocycles with unusual aromatic character.

Wright JH 2nd, Kefalidis CE, Tham FS, Maron L, Lavallo V.

Inorg Chem. 2013 May 20;52(10):6223-9. doi: 10.1021/ic400786a. Epub 2013 May 7.

PMID:
23651253
20.

Perhalogenated carba-closo-dodecaborate anions as ligand substituents: applications in gold catalysis.

Lavallo V, Wright JH 2nd, Tham FS, Quinlivan S.

Angew Chem Int Ed Engl. 2013 Mar 11;52(11):3172-6. doi: 10.1002/anie.201209107. Epub 2013 Feb 13. No abstract available.

PMID:
23404892
21.

Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.

Bouffard J, Keitz BK, Tonner R, Lavallo V, Guisado-Barrios G, Frenking G, Grubbs RH, Bertrand G.

Organometallics. 2011 Mar 9;30(9):2617-2627.

22.

Insights into the carbene-initiated aggregation of [Fe(cot)(2)].

Lavallo V, El-Batta A, Bertrand G, Grubbs RH.

Angew Chem Int Ed Engl. 2011 Jan 3;50(1):268-71. doi: 10.1002/anie.201005212. No abstract available.

23.

Carbenes as catalysts for transformations of organometallic iron complexes.

Lavallo V, Grubbs RH.

Science. 2009 Oct 23;326(5952):559-62. doi: 10.1126/science.1178919.

24.

Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements.

Lavallo V, Dyker CA, Donnadieu B, Bertrand G.

Angew Chem Int Ed Engl. 2008;47(29):5411-4. doi: 10.1002/anie.200801176. No abstract available.

PMID:
18551494
25.

Homogeneous catalytic hydroamination of alkynes and allenes with ammonia.

Lavallo V, Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G.

Angew Chem Int Ed Engl. 2008;47(28):5224-8. doi: 10.1002/anie.200801136. No abstract available.

26.

Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand.

Dyker CA, Lavallo V, Donnadieu B, Bertrand G.

Angew Chem Int Ed Engl. 2008;47(17):3206-9. doi: 10.1002/anie.200705620. No abstract available.

PMID:
18311741
27.

Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.

Lavallo V, Frey GD, Kousar S, Donnadieu B, Bertrand G.

Proc Natl Acad Sci U S A. 2007 Aug 21;104(34):13569-73. Epub 2007 Aug 13.

28.

Recently reported crystalline isothiazole carbenes: myth or reality.

DeHope A, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G.

Angew Chem Int Ed Engl. 2007;46(36):6922-5; discussion 6926. No abstract available.

PMID:
17661300
29.

Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes.

Anderson DR, Lavallo V, O'Leary DJ, Bertrand G, Grubbs RH.

Angew Chem Int Ed Engl. 2007;46(38):7262-5. No abstract available.

30.

Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.

Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G.

Science. 2007 Apr 20;316(5823):439-41.

31.

Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent.

Lavallo V, Ishida Y, Donnadieu B, Bertrand G.

Angew Chem Int Ed Engl. 2006 Oct 13;45(40):6652-5. No abstract available.

32.

CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.

Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G.

Angew Chem Int Ed Engl. 2006 May 19;45(21):3488-91. No abstract available.

33.

Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory.

Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G.

Science. 2006 May 5;312(5774):722-4. Epub 2006 Apr 13.

34.

A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes.

Lavallo V, Canac Y, DeHope A, Donnadieu B, Bertrand G.

Angew Chem Int Ed Engl. 2005 Nov 11;44(44):7236-9. No abstract available.

35.

Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.

Lavallo V, Canac Y, Präsang C, Donnadieu B, Bertrand G.

Angew Chem Int Ed Engl. 2005 Sep 5;44(35):5705-9. No abstract available.

36.

Synthesis, reactivity, and ligand properties of a stable alkyl carbene.

Lavallo V, Mafhouz J, Canac Y, Donnadieu B, Schoeller WW, Bertrand G.

J Am Chem Soc. 2004 Jul 21;126(28):8670-1.

PMID:
15250717

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