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Items: 1 to 50 of 51

1.

Revving up an artificial metalloenzyme.

Lancaster KM.

Science. 2018 Sep 14;361(6407):1071-1072. doi: 10.1126/science.aau7754. No abstract available.

PMID:
30213900
2.

Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO-N3 Charge-Transfer Complex.

Siu JC, Sauer GS, Saha A, Macey RL, Fu N, Chauviré T, Lancaster KM, Lin S.

J Am Chem Soc. 2018 Oct 3;140(39):12511-12520. doi: 10.1021/jacs.8b06744. Epub 2018 Sep 12.

PMID:
30160949
3.

Chalcogen Impact on Covalency within Molecular [Cu33-E)]3+ Clusters (E = O, S, Se): A Synthetic, Spectroscopic, and Computational Study.

Cook BJ, Di Francesco GN, Ferreira RB, Lukens JT, Silberstein KE, Keegan BC, Catalano VJ, Lancaster KM, Shearer J, Murray LJ.

Inorg Chem. 2018 Sep 17;57(18):11382-11392. doi: 10.1021/acs.inorgchem.8b01000. Epub 2018 Aug 30.

PMID:
30160943
4.

A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues.

Dey A, Confer AM, Vilbert AC, Moënne-Loccoz P, Lancaster KM, Goldberg DP.

Angew Chem Int Ed Engl. 2018 Oct 8;57(41):13465-13469. doi: 10.1002/anie.201806146. Epub 2018 Sep 17.

PMID:
30125450
5.

Manganese binding to Rubisco could drive a photorespiratory pathway that increases the energy efficiency of photosynthesis.

Bloom AJ, Lancaster KM.

Nat Plants. 2018 Jul;4(7):414-422. doi: 10.1038/s41477-018-0191-0. Epub 2018 Jul 2.

PMID:
29967515
6.

Beyond fossil fuel-driven nitrogen transformations.

Chen JG, Crooks RM, Seefeldt LC, Bren KL, Bullock RM, Darensbourg MY, Holland PL, Hoffman B, Janik MJ, Jones AK, Kanatzidis MG, King P, Lancaster KM, Lymar SV, Pfromm P, Schneider WF, Schrock RR.

Science. 2018 May 25;360(6391). pii: eaar6611. doi: 10.1126/science.aar6611. Review.

PMID:
29798857
7.

Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L3-edge X-ray absorption spectroscopy.

Goodwin CAP, Réant BLL, Kragskow JGC, DiMucci IM, Lancaster KM, Mills DP, Sproules S.

Dalton Trans. 2018 Aug 21;47(31):10613-10625. doi: 10.1039/c8dt01452c. Epub 2018 May 23.

8.

Sizing up a supercharged ferryl.

Lancaster KM.

Proc Natl Acad Sci U S A. 2018 May 1;115(18):4532-4534. doi: 10.1073/pnas.1804490115. Epub 2018 Apr 16. No abstract available.

PMID:
29666275
9.

Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes.

Broere DLJ, Mercado BQ, Lukens JT, Vilbert AC, Banerjee G, Lant HMC, Lee SH, Bill E, Sproules S, Lancaster KM, Holland PL.

Chemistry. 2018 Jul 2;24(37):9417-9425. doi: 10.1002/chem.201801298. Epub 2018 Jun 7.

PMID:
29663542
10.

Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry.

Broere DLJ, Mercado BQ, Bill E, Lancaster KM, Sproules S, Holland PL.

Inorg Chem. 2018 Aug 20;57(16):9580-9591. doi: 10.1021/acs.inorgchem.8b00226. Epub 2018 Apr 9.

PMID:
29629752
11.

Influences of the heme-lysine crosslink in cytochrome P460 over redox catalysis and nitric oxide sensitivity.

Vilbert AC, Caranto JD, Lancaster KM.

Chem Sci. 2017 Nov 7;9(2):368-379. doi: 10.1039/c7sc03450d. eCollection 2018 Jan 14.

12.

Organometallic and radical intermediates reveal mechanism of diphthamide biosynthesis.

Dong M, Kathiresan V, Fenwick MK, Torelli AT, Zhang Y, Caranto JD, Dzikovski B, Sharma A, Lancaster KM, Freed JH, Ealick SE, Hoffman BM, Lin H.

Science. 2018 Mar 16;359(6381):1247-1250. doi: 10.1126/science.aao6595.

PMID:
29590073
13.

The Eponymous Cofactors in Cytochrome P460s from Ammonia-Oxidizing Bacteria Are Iron Porphyrinoids Whose Macrocycles Are Dibasic.

Smith MA, Lancaster KM.

Biochemistry. 2018 Jan 23;57(3):334-343. doi: 10.1021/acs.biochem.7b00921. Epub 2017 Dec 6.

PMID:
29211462
14.

Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides.

Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa JS.

J Am Chem Soc. 2017 Dec 6;139(48):17257-17260. doi: 10.1021/jacs.7b09569. Epub 2017 Nov 17.

15.

Direct Comparison of C-H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.

Wilding MJT, Iovan DA, Wrobel AT, Lukens JT, MacMillan SN, Lancaster KM, Betley TA.

J Am Chem Soc. 2017 Oct 18;139(41):14757-14766. doi: 10.1021/jacs.7b08714. Epub 2017 Oct 9.

16.

Electronic Structural Analysis of Copper(II)-TEMPO/ABNO Complexes Provides Evidence for Copper(I)-Oxoammonium Character.

Walroth RC, Miles KC, Lukens JT, MacMillan SN, Stahl SS, Lancaster KM.

J Am Chem Soc. 2017 Sep 27;139(38):13507-13517. doi: 10.1021/jacs.7b07186. Epub 2017 Sep 18.

PMID:
28921958
17.

Expanding the Scope of Ligand Substitution from [M(S2C2Ph2] (M = Ni2+, Pd2+, Pt2+) To Afford New Heteroleptic Dithiolene Complexes.

Obanda A, Martinez K, Schmehl RH, Mague JT, Rubtsov IV, MacMillan SN, Lancaster KM, Sproules S, Donahue JP.

Inorg Chem. 2017 Sep 5;56(17):10257-10267. doi: 10.1021/acs.inorgchem.7b00971. Epub 2017 Aug 18.

PMID:
28820242
18.

Nitric oxide is an obligate bacterial nitrification intermediate produced by hydroxylamine oxidoreductase.

Caranto JD, Lancaster KM.

Proc Natl Acad Sci U S A. 2017 Aug 1;114(31):8217-8222. doi: 10.1073/pnas.1704504114. Epub 2017 Jul 17. Erratum in: Proc Natl Acad Sci U S A. 2018 Aug 28;115(35):E8325.

19.

Nitrosomonas europaea cytochrome P460 is a direct link between nitrification and nitrous oxide emission.

Caranto JD, Vilbert AC, Lancaster KM.

Proc Natl Acad Sci U S A. 2016 Dec 20;113(51):14704-14709. doi: 10.1073/pnas.1611051113. Epub 2016 Nov 16.

20.

Spectroscopic Evidence for a 3d(10) Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4](1-).

Walroth RC, Lukens JT, MacMillan SN, Finkelstein KD, Lancaster KM.

J Am Chem Soc. 2016 Feb 17;138(6):1922-31. doi: 10.1021/jacs.5b10819. Epub 2016 Feb 4.

PMID:
26844693
21.

Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity.

Varela-Álvarez A, Yang T, Jennings H, Kornecki KP, Macmillan SN, Lancaster KM, Mack JB, Du Bois J, Berry JF, Musaev DG.

J Am Chem Soc. 2016 Feb 24;138(7):2327-41. doi: 10.1021/jacs.5b12790. Epub 2016 Feb 15.

PMID:
26820386
22.

Oxygen Activation by Co(II) and a Redox Non-Innocent Ligand: Spectroscopic Characterization of a Radical-Co(II)-Superoxide Complex with Divergent Catalytic Reactivity.

Corcos AR, Villanueva O, Walroth RC, Sharma SK, Bacsa J, Lancaster KM, MacBeth CE, Berry JF.

J Am Chem Soc. 2016 Feb 17;138(6):1796-9. doi: 10.1021/jacs.5b12643. Epub 2016 Feb 2.

PMID:
26799113
23.

Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy.

Walroth RC, Uebler JW, Lancaster KM.

Chem Commun (Camb). 2015 Jun 18;51(48):9864-7. doi: 10.1039/c5cc01827g.

24.

Electronic Structure of Ni₂E₂ Complexes (E = S, Se, Te) and a Global Analysis of M₂E₂ Compounds: A Case for Quantized E₂(n-) Oxidation Levels with n = 2, 3, or 4.

Yao SA, Martin-Diaconescu V, Infante I, Lancaster KM, Götz AW, DeBeer S, Berry JF.

J Am Chem Soc. 2015 Apr 22;137(15):4993-5011. doi: 10.1021/ja511607j. Epub 2015 Apr 8.

PMID:
25797853
25.

Stabilizing coordinated radicals via metal-ligand covalency: a structural, spectroscopic, and theoretical investigation of group 9 tris(dithiolene) complexes.

Morsing TJ, MacMillan SN, Uebler JW, Brock-Nannestad T, Bendix J, Lancaster KM.

Inorg Chem. 2015 Apr 6;54(7):3660-9. doi: 10.1021/acs.inorgchem.5b00289. Epub 2015 Mar 10.

PMID:
25756298
26.

Ligand-sensitive but not ligand-diagnostic: evaluating Cr valence-to-core X-ray emission spectroscopy as a probe of inner-sphere coordination.

MacMillan SN, Walroth RC, Perry DM, Morsing TJ, Lancaster KM.

Inorg Chem. 2015 Jan 5;54(1):205-14. doi: 10.1021/ic502152r. Epub 2014 Dec 15.

27.

Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex.

Neu HM, Quesne MG, Yang T, Prokop-Prigge KA, Lancaster KM, Donohoe J, DeBeer S, de Visser SP, Goldberg DP.

Chemistry. 2014 Nov 3;20(45):14584-8. doi: 10.1002/chem.201404349. Epub 2014 Sep 26.

28.

Study of iron dimers reveals angular dependence of valence-to-core X-ray emission spectra.

Pollock CJ, Lancaster KM, Finkelstein KD, DeBeer S.

Inorg Chem. 2014 Oct 6;53(19):10378-85. doi: 10.1021/ic501462y. Epub 2014 Sep 11.

29.

X-ray absorption spectroscopy systematics at the tungsten L-edge.

Jayarathne U, Chandrasekaran P, Greene AF, Mague JT, DeBeer S, Lancaster KM, Sproules S, Donahue JP.

Inorg Chem. 2014 Aug 18;53(16):8230-41. doi: 10.1021/ic500256a. Epub 2014 Jul 28.

30.

Light-atom influences on the electronic structures of iron-sulfur clusters.

Pollock CJ, Tan LL, Zhang W, Lancaster KM, Lee SC, DeBeer S.

Inorg Chem. 2014 Mar 3;53(5):2591-7. doi: 10.1021/ic402944r. Epub 2014 Feb 19.

PMID:
24552488
31.

Direct spectroscopic characterization of a transitory dirhodium donor-acceptor carbene complex.

Kornecki KP, Briones JF, Boyarskikh V, Fullilove F, Autschbach J, Schrote KE, Lancaster KM, Davies HM, Berry JF.

Science. 2013 Oct 18;342(6156):351-4. doi: 10.1126/science.1243200. Epub 2013 Sep 12.

32.

Ancillary ligand effects upon dithiolene redox noninnocence in tungsten bis(dithiolene) complexes.

Yan Y, Keating C, Chandrasekaran P, Jayarathne U, Mague JT, DeBeer S, Lancaster KM, Sproules S, Rubtsov IV, Donahue JP.

Inorg Chem. 2013 Jun 3;52(11):6743-51. doi: 10.1021/ic4009174. Epub 2013 May 15.

PMID:
23675834
33.

X-ray spectroscopic observation of an interstitial carbide in NifEN-bound FeMoco precursor.

Lancaster KM, Hu Y, Bergmann U, Ribbe MW, DeBeer S.

J Am Chem Soc. 2013 Jan 16;135(2):610-2. doi: 10.1021/ja309254g. Epub 2013 Jan 8.

34.

Molecular redox: revisiting the electronic structures of the group 9 metallocorroles.

Palmer JH, Lancaster KM.

Inorg Chem. 2012 Nov 19;51(22):12473-82. doi: 10.1021/ic3018826. Epub 2012 Nov 1.

PMID:
23116160
35.

Manganese nitride complexes in oxidation states III, IV, and V: synthesis and electronic structure.

Kropp H, King AE, Khusniyarov MM, Heinemann FW, Lancaster KM, DeBeer S, Bill E, Meyer K.

J Am Chem Soc. 2012 Sep 19;134(37):15538-44. Epub 2012 Sep 6.

PMID:
22920682
36.

X-ray absorption spectroscopic, crystallographic, theoretical (DFT) and chemical evidence for a chalcogen-chalcogen two-center/three-electron half bond in an unprecedented "subselenide" Se2(3-) ligand.

Yao SA, Lancaster KM, Götz AW, DeBeer S, Berry JF.

Chemistry. 2012 Jul 23;18(30):9179-83. doi: 10.1002/chem.201201291. Epub 2012 Jun 21.

PMID:
22730046
37.

Inner- and outer-sphere metal coordination in blue copper proteins.

Warren JJ, Lancaster KM, Richards JH, Gray HB.

J Inorg Biochem. 2012 Oct;115:119-26. doi: 10.1016/j.jinorgbio.2012.05.002. Epub 2012 May 9. Review.

38.

Outer-sphere contributions to the electronic structure of type zero copper proteins.

Lancaster KM, Zaballa ME, Sproules S, Sundararajan M, DeBeer S, Richards JH, Vila AJ, Neese F, Gray HB.

J Am Chem Soc. 2012 May 16;134(19):8241-53. doi: 10.1021/ja302190r. Epub 2012 May 7.

39.

Spin delocalization over type zero copper.

Potapov A, Lancaster KM, Richards JH, Gray HB, Goldfarb D.

Inorg Chem. 2012 Apr 2;51(7):4066-75. doi: 10.1021/ic202336m. Epub 2012 Mar 20.

40.

Experimental fingerprints for redox-active terpyridine in [Cr(tpy)2](PF6)n (n = 3-0), and the remarkable electronic structure of [Cr(tpy)2]1-.

Scarborough CC, Lancaster KM, DeBeer S, Weyhermüller T, Sproules S, Wieghardt K.

Inorg Chem. 2012 Mar 19;51(6):3718-32. doi: 10.1021/ic2027219. Epub 2012 Mar 6.

PMID:
22424275
41.

X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor.

Lancaster KM, Roemelt M, Ettenhuber P, Hu Y, Ribbe MW, Neese F, Bergmann U, DeBeer S.

Science. 2011 Nov 18;334(6058):974-7. doi: 10.1126/science.1206445.

42.

Kβ X-ray emission spectroscopy offers unique chemical bonding insights: revisiting the electronic structure of ferrocene.

Lancaster KM, Finkelstein KD, DeBeer S.

Inorg Chem. 2011 Jul 18;50(14):6767-74. doi: 10.1021/ic200822b. Epub 2011 Jun 21.

PMID:
21692497
43.

Electron transfer reactivity of type zero Pseudomonas aeruginosa azurin.

Lancaster KM, Farver O, Wherland S, Crane EJ 3rd, Richards JH, Pecht I, Gray HB.

J Am Chem Soc. 2011 Apr 6;133(13):4865-73. doi: 10.1021/ja1093919. Epub 2011 Mar 15.

44.

Ultrafast excited-state dynamics of rhenium(I) photosensitizers [Re(Cl)(CO)3(N,N)] and [Re(imidazole)(CO)3(N,N)]+: diimine effects.

El Nahhas A, Consani C, Blanco-Rodríguez AM, Lancaster KM, Braem O, Cannizzo A, Towrie M, Clark IP, Zális S, Chergui M, Vlcek A Jr.

Inorg Chem. 2011 Apr 4;50(7):2932-43. doi: 10.1021/ic102324p. Epub 2011 Mar 9.

PMID:
21388162
45.

Rhesus monkeys (Macaca mulatta) do recognize themselves in the mirror: implications for the evolution of self-recognition.

Rajala AZ, Reininger KR, Lancaster KM, Populin LC.

PLoS One. 2010 Sep 29;5(9). pii: e12865. doi: 10.1371/journal.pone.0012865.

46.

Outer-sphere effects on reduction potentials of copper sites in proteins: the curious case of high potential type 2 C112D/M121E Pseudomonas aeruginosa azurin.

Lancaster KM, Sproules S, Palmer JH, Richards JH, Gray HB.

J Am Chem Soc. 2010 Oct 20;132(41):14590-5. doi: 10.1021/ja105731x.

47.

Type-zero copper proteins.

Lancaster KM, DeBeer George S, Yokoyama K, Richards JH, Gray HB.

Nat Chem. 2009 Dec;1(9):711-5. doi: 10.1038/nchem.412.

48.

Structures and reactivity patterns of group 9 metallocorroles.

Palmer JH, Mahammed A, Lancaster KM, Gross Z, Gray HB.

Inorg Chem. 2009 Oct 5;48(19):9308-15. doi: 10.1021/ic901164r.

PMID:
19736908
49.

High-potential C112D/M121X (X = M, E, H, L) Pseudomonas aeruginosa azurins.

Lancaster KM, Yokoyama K, Richards JH, Winkler JR, Gray HB.

Inorg Chem. 2009 Feb 16;48(4):1278-80. doi: 10.1021/ic802322e.

50.

Determination of coenzyme A levels in Pyrococcus furiosus and other Archaea: implications for a general role for coenzyme A in thermophiles.

Hummel CS, Lancaster KM, Crane EJ 3rd.

FEMS Microbiol Lett. 2005 Nov 15;252(2):229-34. Epub 2005 Sep 19.

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