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Items: 1 to 50 of 166

1.

Why Do Five Ga+ Cations Form a Ligand-Stabilized [Ga5 ]5+ Pentagon and How Does a 5:1 Salt Pack in the Solid State?

Glootz K, Himmel D, Kratzert D, Butschke B, Scherer H, Krossing I.

Angew Chem Int Ed Engl. 2019 Oct 1;58(40):14162-14166. doi: 10.1002/anie.201907974. Epub 2019 Aug 28.

2.

Coordination Chemistry of P4 S3 and P4 Se3 towards the Iron Fragments [Fe(Cp)(CO)2 ]+ and [Fe(Cp)(PPh3 )(CO)].

Weis P, Riddlestone IM, Scherer H, Krossing I.

Chemistry. 2019 Sep 18;25(52):12159-12168. doi: 10.1002/chem.201902339. Epub 2019 Aug 23.

3.

Oxidative Fluorination of Cu/ZnO Methanol Catalysts.

Dybbert V, Fehr SM, Klein F, Schaadt A, Hoffmann A, Frei E, Erdem E, Ludwig T, Hillebrecht H, Krossing I.

Angew Chem Int Ed Engl. 2019 Sep 9;58(37):12935-12939. doi: 10.1002/anie.201811267. Epub 2019 Jul 4.

PMID:
31169940
4.

From Phosphidic to Phosphonium? Umpolung of the P4 -Bonding Situation in [CpFe(CO)(L)(η1 -P4 )]+ Cations (L=CO or PPh3 ).

Riddlestone IM, Weis P, Martens A, Schorpp M, Scherer H, Krossing I.

Chemistry. 2019 Aug 9;25(45):10546-10551. doi: 10.1002/chem.201902075. Epub 2019 Jul 4.

PMID:
31066932
5.

Going Homoleptic: Synthesis and Full Characterization of Stable Manganese Tetranitrosyl Cation Salts.

Bohnenberger J, Derstine B, Daub M, Krossing I.

Angew Chem Int Ed Engl. 2019 Jul 8;58(28):9586-9589. doi: 10.1002/anie.201904191. Epub 2019 Jun 5.

PMID:
31050097
6.

Investigations on non-classical silylium ions leading to a cyclobutenyl cation.

Martens A, Kreuzer M, Ripp A, Schneider M, Himmel D, Scherer H, Krossing I.

Chem Sci. 2019 Jan 10;10(9):2821-2829. doi: 10.1039/c8sc04591g. eCollection 2019 Mar 7.

7.

Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue.

Bohnenberger J, Feuerstein W, Himmel D, Daub M, Breher F, Krossing I.

Nat Commun. 2019 Feb 7;10(1):624. doi: 10.1038/s41467-019-08517-2.

8.

Facile and systematic access to the least-coordinating WCA [(RFO)3Al-F-Al(ORF)3]- and its more Lewis-basic brother [F-Al(ORF)3]- (RF = C(CF3)3).

Martens A, Weis P, Krummer MC, Kreuzer M, Meierhöfer A, Meier SC, Bohnenberger J, Scherer H, Riddlestone I, Krossing I.

Chem Sci. 2018 Aug 1;9(35):7058-7068. doi: 10.1039/c8sc02591f. eCollection 2018 Sep 21.

9.

How does the Environment Influence a Given Cation? A Systematic Investigation of [Co(CO)5 ]+ in Gas Phase, Solution, and Solid State.

Meier SC, Himmel D, Krossing I.

Chemistry. 2018 Dec 20;24(72):19348-19360. doi: 10.1002/chem.201804546. Epub 2018 Nov 23.

PMID:
30259588
10.

Tetracationic Gallium Cluster Cations.

Glootz K, Kratzert D, Himmel D, Kastro A, Yassine Z, Findeisen T, Krossing I.

Angew Chem Int Ed Engl. 2018 Oct 22;57(43):14203-14206. doi: 10.1002/anie.201807486. Epub 2018 Oct 2.

PMID:
30168255
11.

Guilty and charged: a stable solution of the hexamethylbenzene radical cation as a ligand forming oxidising agent.

Schorpp M, Rein S, Weber S, Scherer H, Krossing I.

Chem Commun (Camb). 2018 Sep 6;54(72):10036-10039. doi: 10.1039/c8cc04690e.

PMID:
30063051
12.

The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)2 and c-C6F10-1-(CF3)OH.

Schaab J, Schwab M, Kratzert D, Schwabedissen J, Stammler HG, Mitzel NW, Krossing I.

Chem Commun (Camb). 2018 Aug 16;54(67):9294-9297. doi: 10.1039/c8cc05148h.

PMID:
30033461
13.

Towards a Sustainable Synthesis of Oxymethylene Dimethyl Ether by Homogeneous Catalysis and Uptake of Molecular Formaldehyde.

Peter A, Fehr SM, Dybbert V, Himmel D, Lindner I, Jacob E, Ouda M, Schaadt A, White RJ, Scherer H, Krossing I.

Angew Chem Int Ed Engl. 2018 Jul 20;57(30):9461-9464. doi: 10.1002/anie.201802247. Epub 2018 Jul 3.

PMID:
29893511
14.

Access to the Bis-benzene Cobalt(I) Sandwich Cation and its Derivatives: Synthons for a "Naked" Cobalt(I) Source?

Meier SC, Holz A, Kulenkampff J, Schmidt A, Kratzert D, Himmel D, Schmitz D, Scheidt EW, Scherer W, Bülow C, Timm M, Lindblad R, Akin ST, Zamudio-Bayer V, von Issendorff B, Duncan MA, Lau JT, Krossing I.

Angew Chem Int Ed Engl. 2018 Jul 20;57(30):9310-9314. doi: 10.1002/anie.201803108. Epub 2018 Jun 25.

PMID:
29847000
15.

The Lewis superacid Al[N(C6F5)2]3 and its higher homolog Ga[N(C6F5)2]3 - structural features, theoretical investigation and reactions of a metal amide with higher fluoride ion affinity than SbF5.

Kögel JF, Sorokin DA, Khvorost A, Scott M, Harms K, Himmel D, Krossing I, Sundermeyer J.

Chem Sci. 2017 Oct 23;9(1):245-253. doi: 10.1039/c7sc03988c. eCollection 2018 Jan 7.

16.

Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions.

Riddlestone IM, Kraft A, Schaefer J, Krossing I.

Angew Chem Int Ed Engl. 2018 Oct 22;57(43):13982-14024. doi: 10.1002/anie.201710782. Epub 2018 Sep 13. Review.

PMID:
29266644
17.

The Ideal Ionic Liquid Salt Bridge for Direct Determination of Gibbs Energies of Transfer of Single Ions, Part II: Evaluation of the Role of Ion Solvation and Ion Mobilities.

Ermantraut A, Radtke V, Gebel N, Himmel D, Koslowski T, Leito I, Krossing I.

Angew Chem Int Ed Engl. 2018 Feb 23;57(9):2348-2352. doi: 10.1002/anie.201707334. Epub 2018 Feb 7.

PMID:
29235721
18.

The Ideal Ionic Liquid Salt Bridge for the Direct Determination of Gibbs Energies of Transfer of Single Ions, Part I: The Concept.

Radtke V, Ermantraut A, Himmel D, Koslowski T, Leito I, Krossing I.

Angew Chem Int Ed Engl. 2018 Feb 23;57(9):2344-2347. doi: 10.1002/anie.201707333. Epub 2018 Feb 5.

PMID:
29235713
19.

More Stable Template Localization for an Incremental Focal-Point Approach-Implementation and Application to the Intramolecular Decomposition of Tris-perfluoro-tert-butoxyalane.

Fiedler B, Himmel D, Krossing I, Friedrich J.

J Chem Theory Comput. 2018 Feb 13;14(2):557-571. doi: 10.1021/acs.jctc.7b00707. Epub 2018 Jan 23.

PMID:
29186657
20.

Basic Remarks on Acidity.

Himmel D, Radtke V, Butschke B, Krossing I.

Angew Chem Int Ed Engl. 2018 Apr 9;57(16):4386-4411. doi: 10.1002/anie.201709057. Epub 2018 Mar 15. Review.

PMID:
29171707
21.

Synthesis, Characterisation and Reactions of Truly Cationic NiI -Phosphine Complexes.

Schwab MM, Himmel D, Kacprzak S, Radtke V, Kratzert D, Weis P, Wernet M, Peter A, Yassine Z, Schmitz D, Scheidt EW, Scherer W, Weber S, Feuerstein W, Breher F, Higelin A, Krossing I.

Chemistry. 2018 Jan 19;24(4):918-927. doi: 10.1002/chem.201704436. Epub 2017 Dec 13.

PMID:
29155467
22.

A unified view to Brønsted acidity scales: do we need solvated protons?

Paenurk E, Kaupmees K, Himmel D, Kütt A, Kaljurand I, Koppel IA, Krossing I, Leito I.

Chem Sci. 2017 Oct 1;8(10):6964-6973. doi: 10.1039/c7sc01424d. Epub 2017 Aug 7.

23.

Two synthetic approaches for the preparation of tin(ii) dications.

Schleep M, Hettich C, Kratzert D, Scherer H, Krossing I.

Chem Commun (Camb). 2017 Oct 3;53(79):10914-10917. doi: 10.1039/c7cc06201j.

PMID:
28929160
24.

From an Easily Accessible Pentacarbonylcobalt(I) Salt to Piano-Stool Cations [(arene)Co(CO)2 ].

Meier SC, Holz A, Schmidt A, Kratzert D, Himmel D, Krossing I.

Chemistry. 2017 Oct 17;23(58):14658-14664. doi: 10.1002/chem.201703589. Epub 2017 Sep 18.

PMID:
28796933
25.

From Square-Planar [ICl4 ]- to Novel Chloroiodates(III)? A Systematic Experimental and Theoretical Investigation of Their Ionic Liquids.

Burgenmeister B, Sonnenberg K, Riedel S, Krossing I.

Chemistry. 2017 Aug 22;23(47):11312-11322. doi: 10.1002/chem.201701555. Epub 2017 Jul 31.

PMID:
28759128
26.

An Investigation of the Symmetric and Asymmetric Cleavage Products in the System Aluminum Trihalide/1-Butylimidazole.

Hog M, Schneider M, Studer G, Bäuerle M, Föhrenbacher SA, Scherer H, Krossing I.

Chemistry. 2017 Aug 16;23(46):11054-11066. doi: 10.1002/chem.201701553. Epub 2017 Jul 31.

PMID:
28608508
27.

Synthesis and Characterization of Bromoaluminate Ionic Liquids.

Hog M, Schneider M, Krossing I.

Chemistry. 2017 Jul 21;23(41):9821-9830. doi: 10.1002/chem.201700105. Epub 2017 Jun 29.

PMID:
28556995
28.

Using the Lewis Acid Me3 Si-F-Al(ORF )3 To Prepare Phosphino-Phosphonium Cations with the Least-Coordinating Anion [(RF O)3 Al-F-Al(ORF )3 ].

Possart J, Martens A, Schleep M, Ripp A, Scherer H, Kratzert D, Krossing I.

Chemistry. 2017 Sep 7;23(50):12305-12313. doi: 10.1002/chem.201701260. Epub 2017 Jun 29.

PMID:
28494112
29.

Inhibiting Polysulfide Shuttle in Lithium-Sulfur Batteries through Low-Ion-Pairing Salts and a Triflamide Solvent.

Shyamsunder A, Beichel W, Klose P, Pang Q, Scherer H, Hoffmann A, Murphy GK, Krossing I, Nazar LF.

Angew Chem Int Ed Engl. 2017 May 22;56(22):6192-6197. doi: 10.1002/anie.201701026. Epub 2017 May 2.

PMID:
28464473
30.

The Parent Cyclopentadienyltin Cation, Its Toluene Adduct, and the Quadruple-Decker [Sn3 Cp4 ]2.

Schleep M, Hettich C, Velázquez Rojas J, Kratzert D, Ludwig T, Lieberth K, Krossing I.

Angew Chem Int Ed Engl. 2017 Mar 6;56(11):2880-2884. doi: 10.1002/anie.201611351. Epub 2017 Feb 8.

PMID:
28177204
31.

From Ion-Like Ethylzinc Aluminates to [EtZn(arene)2 ]+ [Al(ORF )4 ]- Salts.

Petersen TO, Simone D, Krossing I.

Chemistry. 2016 Oct 24;22(44):15847-15855. doi: 10.1002/chem.201601860. Epub 2016 Sep 15.

PMID:
27630061
32.

Homoleptic Gold Acetonitrile Complexes with Medium to Very Weakly Coordinating Counterions: Effect on Aurophilicity?

Engesser TA, Friedmann C, Martens A, Kratzert D, Malinowski PJ, Krossing I.

Chemistry. 2016 Oct 10;22(42):15085-15094. doi: 10.1002/chem.201602797. Epub 2016 Sep 4.

PMID:
27593411
33.

A Ferrocenyl-Backboned Unsymmetric O,C-Coordinating Ligand and Its Tin Derivatives.

Janssen B, Lutter M, Alnasr H, Krossing I, Jurkschat K.

ChemistryOpen. 2016 Jun 15;5(4):319-24. doi: 10.1002/open.201600048. eCollection 2016 Aug.

34.

Coordination Chemistry of Diiodine and Implications for the Oxidation Capacity of the Synergistic Ag(+) /X2 (X=Cl, Br, I) System.

Malinowski PJ, Himmel D, Krossing I.

Angew Chem Int Ed Engl. 2016 Aug 1;55(32):9262-6. doi: 10.1002/anie.201603913. Epub 2016 Jul 13.

PMID:
27411163
35.

Silver Complexes of Dihalogen Molecules.

Malinowski PJ, Himmel D, Krossing I.

Angew Chem Int Ed Engl. 2016 Aug 1;55(32):9259-61. doi: 10.1002/anie.201603741. Epub 2016 Jul 12.

PMID:
27404568
36.

Tunable Aryl Alkyl Ionic Liquids with Weakly Coordinating Tetrakis((1,1,1,3,3,3-hexafluoropropan-2-yl)oxy)borate [B(hfip)4 ] Anions.

Kaliner M, Rupp A, Krossing I, Strassner T.

Chemistry. 2016 Jul 11;22(29):10044-9. doi: 10.1002/chem.201601063. Epub 2016 Jun 22.

PMID:
27333433
37.

Reactive p-block cations stabilized by weakly coordinating anions.

Engesser TA, Lichtenthaler MR, Schleep M, Krossing I.

Chem Soc Rev. 2016 Feb 21;45(4):789-899. doi: 10.1039/c5cs00672d. Epub 2015 Nov 27.

38.

Cationic cluster formation versus disproportionation of low-valent indium and gallium complexes of 2,2'-bipyridine.

Lichtenthaler MR, Stahl F, Kratzert D, Heidinger L, Schleicher E, Hamann J, Himmel D, Weber S, Krossing I.

Nat Commun. 2015 Oct 19;6:8288. doi: 10.1038/ncomms9288.

39.

[Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) Chemistry.

Schwab MM, Himmel D, Kacprzak S, Kratzert D, Radtke V, Weis P, Ray K, Scheidt EW, Scherer W, de Bruin B, Weber S, Krossing I.

Angew Chem Int Ed Engl. 2015 Dec 1;54(49):14706-9. doi: 10.1002/anie.201506475. Epub 2015 Oct 13.

40.

Ionic liquid-mediated technology to produce cellulose nanocrystals directly from wood.

Abushammala H, Krossing I, Laborie MP.

Carbohydr Polym. 2015 Dec 10;134:609-16. doi: 10.1016/j.carbpol.2015.07.079. Epub 2015 Jul 26.

PMID:
26428164
41.

Ionic Liquids with Weakly Coordinating [M(III)(OR(F))4](-) Anions.

Rupp AB, Krossing I.

Acc Chem Res. 2015 Sep 15;48(9):2537-46. doi: 10.1021/acs.accounts.5b00247. Epub 2015 Aug 24.

PMID:
26299782
42.

Ethyl-Zinc(II)-Cation Equivalents: Synthesis and Hydroamination Catalysis.

Petersen TO, Tausch E, Schaefer J, Scherer H, Roesky PW, Krossing I.

Chemistry. 2015 Sep 21;21(39):13696-702. doi: 10.1002/chem.201502328. Epub 2015 Aug 11.

PMID:
26264355
43.

DSR: enhanced modelling and refinement of disordered structures with SHELXL.

Kratzert D, Holstein JJ, Krossing I.

J Appl Crystallogr. 2015 Apr 25;48(Pt 3):933-938. eCollection 2015 Jun 1.

44.

Effect of Dimethyl Carbonate on the Dynamic Properties and Ionicities of Ionic Liquids with [M(III) (hfip)4 ](-) (M=B, Al) Anions.

Rupp AB, Welle S, Klose P, Scherer H, Krossing I.

Chemphyschem. 2015 Jun 22;16(9):1940-7. doi: 10.1002/cphc.201500069. Epub 2015 Apr 15.

PMID:
25877038
45.

Absolute Brønsted Acidities and pH Scales in Ionic Liquids.

Himmel D, Goll SK, Scholz F, Radtke V, Leito I, Krossing I.

Chemphyschem. 2015 May 18;16(7):1428-39. doi: 10.1002/cphc.201402906. Epub 2015 Apr 8.

PMID:
25853921
46.

The Acidity of the HBr/AlBr3 System: Stabilization of Crystalline Protonated Arenes and Their Acidity in Bromoaluminate Ionic Liquids.

Scholz F, Himmel D, Eisele L, Unkrig W, Martens A, Schlüter P, Krossing I.

Chemistry. 2015 May 11;21(20):7489-502. doi: 10.1002/chem.201405952. Epub 2015 Mar 25.

PMID:
25808398
47.
48.

Homoleptic borates and aluminates containing the difluorophosphato ligand - [M(O2PF2)x](y-) - synthesis and characterization.

Schulz C, Eiden P, Klose P, Ermantraut A, Schmidt M, Garsuch A, Krossing I.

Dalton Trans. 2015 Apr 21;44(15):7048-57. doi: 10.1039/c5dt00469a.

PMID:
25785817
49.

Fluoro- and perfluoralkylsulfonylpentafluoroanilides: synthesis and characterization of NH acids for weakly coordinating anions and their gas-phase and solution acidities.

Kögel JF, Linder T, Schröder FG, Sundermeyer J, Goll SK, Himmel D, Krossing I, Kütt K, Saame J, Leito I.

Chemistry. 2015 Apr 7;21(15):5769-82. doi: 10.1002/chem.201405391. Epub 2015 Feb 26.

PMID:
25727401
50.

Unified pH values of liquid chromatography mobile phases.

Suu A, Jalukse L, Liigand J, Kruve A, Himmel D, Krossing I, Rosés M, Leito I.

Anal Chem. 2015 Mar 3;87(5):2623-30. doi: 10.1021/ac504692m. Epub 2015 Feb 23.

PMID:
25664372

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