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Items: 1 to 50 of 124

1.

Isolation and characterization of a high-spin mixed-valent iron dinitrogen complex.

McWilliams SF, Bunting PC, Kathiresan V, Mercado BQ, Hoffman BM, Long JR, Holland PL.

Chem Commun (Camb). 2018 Nov 27;54(95):13339-13342. doi: 10.1039/c8cc07294a.

PMID:
30403226
2.

Effects of N2 Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex.

McWilliams SF, Bill E, Lukat-Rodgers G, Rodgers KR, Mercado BQ, Holland PL.

J Am Chem Soc. 2018 Jul 11;140(27):8586-8598. doi: 10.1021/jacs.8b04828. Epub 2018 Jun 29.

PMID:
29957940
3.

So Close, yet Sulfur Away: Opening the Nitrogenase Cofactor Structure Creates a Binding Site.

Skubi KL, Holland PL.

Biochemistry. 2018 Jul 3;57(26):3540-3541. doi: 10.1021/acs.biochem.8b00529. Epub 2018 Jun 21. No abstract available.

PMID:
29927241
4.

High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT.

Pelmenschikov V, Gee LB, Wang H, MacLeod KC, McWilliams SF, Skubi KL, Cramer SP, Holland PL.

Angew Chem Int Ed Engl. 2018 Jul 20;57(30):9367-9371. doi: 10.1002/anie.201804601. Epub 2018 Jun 25.

PMID:
29847703
5.

Beyond fossil fuel-driven nitrogen transformations.

Chen JG, Crooks RM, Seefeldt LC, Bren KL, Bullock RM, Darensbourg MY, Holland PL, Hoffman B, Janik MJ, Jones AK, Kanatzidis MG, King P, Lancaster KM, Lymar SV, Pfromm P, Schneider WF, Schrock RR.

Science. 2018 May 25;360(6391). pii: eaar6611. doi: 10.1126/science.aar6611. Review.

PMID:
29798857
6.

Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation.

Bonyhady SJ, DeRosha DE, Vela J, Vinyard DJ, Cowley RE, Mercado BQ, Brennessel WW, Holland PL.

Inorg Chem. 2018 May 21;57(10):5959-5972. doi: 10.1021/acs.inorgchem.8b00468. Epub 2018 May 9.

PMID:
29741884
7.

Incorporating light atoms into synthetic analogues of FeMoco.

DeRosha DE, Holland PL.

Proc Natl Acad Sci U S A. 2018 May 15;115(20):5054-5056. doi: 10.1073/pnas.1805700115. Epub 2018 Apr 30. No abstract available.

8.

Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes.

Broere DLJ, Mercado BQ, Lukens JT, Vilbert AC, Banerjee G, Lant HMC, Lee SH, Bill E, Sproules S, Lancaster KM, Holland PL.

Chemistry. 2018 Jul 2;24(37):9417-9425. doi: 10.1002/chem.201801298. Epub 2018 Jun 7.

PMID:
29663542
9.

Selective Conversion of CO2 into Isocyanate by Low-Coordinate Iron Complexes.

Broere DLJ, Mercado BQ, Holland PL.

Angew Chem Int Ed Engl. 2018 May 28;57(22):6507-6511. doi: 10.1002/anie.201802357. Epub 2018 Apr 30.

PMID:
29633494
10.

Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry.

Broere DLJ, Mercado BQ, Bill E, Lancaster KM, Sproules S, Holland PL.

Inorg Chem. 2018 Aug 20;57(16):9580-9591. doi: 10.1021/acs.inorgchem.8b00226. Epub 2018 Apr 9.

PMID:
29629752
11.

Boron compounds tackle dinitrogen.

Broere DLJ, Holland PL.

Science. 2018 Feb 23;359(6378):871. doi: 10.1126/science.aar7395. No abstract available.

PMID:
29472470
12.

Functionalized Self-Assembled Monolayers Bearing Diiminate Complexes Immobilized through Covalently Anchored Ligands.

Rozen E, Erlich Y, Reesbeck ME, Holland PL, Sukenik CN.

Langmuir. 2018 Nov 13;34(45):13472-13480. doi: 10.1021/acs.langmuir.7b00984. Epub 2017 Nov 2.

PMID:
29048903
13.

Protonation and electrochemical reduction of rhodium- and iridium-dinitrogen complexes in organic solution.

Connor GP, Lease N, Casuras A, Goldman AS, Holland PL, Mayer JM.

Dalton Trans. 2017 Oct 24;46(41):14325-14330. doi: 10.1039/c7dt03476h.

PMID:
29019358
14.

ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase.

Horitani M, Grubel K, McWilliams SF, Stubbert BD, Mercado BQ, Yu Y, Gurubasavaraj PM, Lees NS, Holland PL, Hoffman BM.

Chem Sci. 2017 Sep 1;8(9):5941-5948. doi: 10.1039/c7sc01602f. Epub 2017 Jun 30.

15.

Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes.

Bellows SM, Brennessel WW, Holland PL.

Eur J Inorg Chem. 2016 Jul;2016(20):3344-3355. doi: 10.1002/ejic.201600112. Epub 2016 May 30.

16.

Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron.

Arnet NA, McWilliams SF, DeRosha DE, Mercado BQ, Holland PL.

Inorg Chem. 2017 Aug 7;56(15):9185-9193. doi: 10.1021/acs.inorgchem.7b01230. Epub 2017 Jul 20.

17.

Density Functional Calculations for Prediction of 57Fe Mössbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes.

McWilliams SF, Brennan-Wydra E, MacLeod KC, Holland PL.

ACS Omega. 2017 Jun 30;2(6):2594-2606. doi: 10.1021/acsomega.7b00595. Epub 2017 Jun 12.

18.

Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction.

Connor GP, Holland PL.

Catal Today. 2017 May 15;286:21-40. doi: 10.1016/j.cattod.2016.08.014. Epub 2016 Aug 16.

19.

Quantitation of the THF Content in Fe[N(SiMe3)2]2·xTHF.

Broere DL, Čorić I, Brosnahan A, Holland PL.

Inorg Chem. 2017 Mar 20;56(6):3140-3143. doi: 10.1021/acs.inorgchem.7b00056. Epub 2017 Mar 1.

20.

Enhancement of C-H Oxidizing Ability in Co-O2  Complexes through an Isolated Heterobimetallic Oxo Intermediate.

DeRosha DE, Mercado BQ, Lukat-Rodgers G, Rodgers KR, Holland PL.

Angew Chem Int Ed Engl. 2017 Mar 13;56(12):3211-3215. doi: 10.1002/anie.201612010. Epub 2017 Feb 14.

PMID:
28194845
21.

Fe-Catalyzed C-C Bond Construction from Olefins via Radicals.

Lo JC, Kim D, Pan CM, Edwards JT, Yabe Y, Gui J, Qin T, Gutiérrez S, Giacoboni J, Smith MW, Holland PL, Baran PS.

J Am Chem Soc. 2017 Feb 15;139(6):2484-2503. doi: 10.1021/jacs.6b13155. Epub 2017 Feb 2.

22.

Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II).

Reesbeck ME, Grubel K, Kim D, Brennessel WW, Mercado BQ, Holland PL.

Inorg Chem. 2017 Feb 6;56(3):1019-1022. doi: 10.1021/acs.inorgchem.6b01952. Epub 2017 Jan 9.

23.

Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia.

MacLeod KC, McWilliams SF, Mercado BQ, Holland PL.

Chem Sci. 2016;7(9):5736-5746. doi: 10.1039/C6SC00423G. Epub 2016 Jun 14.

24.

C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron.

MacLeod KC, Lewis RA, DeRosha DE, Mercado BQ, Holland PL.

Angew Chem Int Ed Engl. 2017 Jan 19;56(4):1069-1072. doi: 10.1002/anie.201610679. Epub 2016 Dec 21.

25.

A [3Fe-4S] cluster is required for tRNA thiolation in archaea and eukaryotes.

Liu Y, Vinyard DJ, Reesbeck ME, Suzuki T, Manakongtreecheep K, Holland PL, Brudvig GW, Söll D.

Proc Natl Acad Sci U S A. 2016 Nov 8;113(45):12703-12708. doi: 10.1073/pnas.1615732113. Epub 2016 Oct 24.

26.

The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex.

Bellows SM, Arnet NA, Gurubasavaraj PM, Brennessel WW, Bill E, Cundari TR, Holland PL.

J Am Chem Soc. 2016 Sep 21;138(37):12112-23. doi: 10.1021/jacs.6b04654. Epub 2016 Sep 6.

27.

Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides.

MacLeod KC, Menges FS, McWilliams SF, Craig SM, Mercado BQ, Johnson MA, Holland PL.

J Am Chem Soc. 2016 Sep 7;138(35):11185-91. doi: 10.1021/jacs.6b04984. Epub 2016 Aug 29.

28.

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands.

Čorić I, Holland PL.

J Am Chem Soc. 2016 Jun 15;138(23):7200-11. doi: 10.1021/jacs.6b00747. Epub 2016 Jun 3. Review.

29.

Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes.

McWilliams SF, Rodgers KR, Lukat-Rodgers G, Mercado BQ, Grubel K, Holland PL.

Inorg Chem. 2016 Mar 21;55(6):2960-8. doi: 10.1021/acs.inorgchem.5b02841. Epub 2016 Mar 1.

30.

Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride.

Arnet NA, Dugan TR, Menges FS, Mercado BQ, Brennessel WW, Bill E, Johnson MA, Holland PL.

J Am Chem Soc. 2015 Oct 21;137(41):13220-3. doi: 10.1021/jacs.5b06841. Epub 2015 Oct 12.

31.

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst.

Chen C, Hecht MB, Kavara A, Brennessel WW, Mercado BQ, Weix DJ, Holland PL.

J Am Chem Soc. 2015 Oct 21;137(41):13244-7. doi: 10.1021/jacs.5b08611. Epub 2015 Oct 7.

PMID:
26444496
32.

Binding of dinitrogen to an iron-sulfur-carbon site.

Čorić I, Mercado BQ, Bill E, Vinyard DJ, Holland PL.

Nature. 2015 Oct 1;526(7571):96-9. doi: 10.1038/nature15246. Epub 2015 Sep 23.

33.

Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex.

Al-Afyouni MH, Suturina E, Pathak S, Atanasov M, Bill E, DeRosha DE, Brennessel WW, Neese F, Holland PL.

J Am Chem Soc. 2015 Aug 26;137(33):10689-99. doi: 10.1021/jacs.5b06078. Epub 2015 Aug 12.

PMID:
26267848
34.

Tuning steric and electronic effects in transition-metal β-diketiminate complexes.

Chen C, Bellows SM, Holland PL.

Dalton Trans. 2015 Oct 14;44(38):16654-70. doi: 10.1039/c5dt02215k. Epub 2015 Aug 5.

35.

Dinitrogen binding and cleavage by multinuclear iron complexes.

McWilliams SF, Holland PL.

Acc Chem Res. 2015 Jul 21;48(7):2059-65. doi: 10.1021/acs.accounts.5b00213. Epub 2015 Jun 23. Review.

36.

Oxidized and reduced [2Fe-2S] clusters from an iron(I) synthon.

Reesbeck ME, Rodriguez MM, Brennessel WW, Mercado BQ, Vinyard D, Holland PL.

J Biol Inorg Chem. 2015 Jul;20(5):875-83. doi: 10.1007/s00775-015-1272-4. Epub 2015 Jun 5.

37.

Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts.

Holland PL.

Acc Chem Res. 2015 Jun 16;48(6):1696-702. doi: 10.1021/acs.accounts.5b00036. Epub 2015 May 19.

PMID:
25989357
38.

Cobalt(II) Complex of a Diazoalkane Radical Anion.

Bonyhady SJ, Goldberg JM, Wedgwood N, Dugan TR, Eklund AG, Brennessel WW, Holland PL.

Inorg Chem. 2015 Jun 1;54(11):5148-50. doi: 10.1021/acs.inorgchem.5b00673. Epub 2015 May 19.

PMID:
25986783
39.

Alkali metal control over N-N cleavage in iron complexes.

Grubel K, Brennessel WW, Mercado BQ, Holland PL.

J Am Chem Soc. 2014 Dec 3;136(48):16807-16. doi: 10.1021/ja507442b. Epub 2014 Nov 20.

40.

Structural and spectroscopic characterization of iron(II), cobalt(II), and nickel(II) ortho-dihalophenolate complexes: insights into metal-halogen secondary bonding.

Machonkin TE, Boshart MD, Schofield JA, Rodriguez MM, Grubel K, Rokhsana D, Brennessel WW, Holland PL.

Inorg Chem. 2014 Sep 15;53(18):9837-48. doi: 10.1021/ic501424e. Epub 2014 Aug 28.

PMID:
25167329
41.

Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons.

Lewis RA, MacLeod KC, Mercado BQ, Holland PL.

Chem Commun (Camb). 2014 Oct 4;50(76):11114-7. doi: 10.1039/c4cc05495d.

42.

A multi-iron system capable of rapid N2 formation and N2 cleavage.

MacLeod KC, Vinyard DJ, Holland PL.

J Am Chem Soc. 2014 Jul 23;136(29):10226-9. doi: 10.1021/ja505193z. Epub 2014 Jul 8.

43.

A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4Ligand.

Stubbert BD, Vela J, Brennessel WW, Holland PL.

Z Anorg Allg Chem. 2013 Jul 1;639(8-9):1351-1355.

44.

Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexes.

Dugan TR, Bill E, MacLeod KC, Brennessel WW, Holland PL.

Inorg Chem. 2014 Mar 3;53(5):2370-80. doi: 10.1021/ic4013137. Epub 2014 Feb 20.

45.

Z-selective alkene isomerization by high-spin cobalt(II) complexes.

Chen C, Dugan TR, Brennessel WW, Weix DJ, Holland PL.

J Am Chem Soc. 2014 Jan 22;136(3):945-55. doi: 10.1021/ja408238n. Epub 2014 Jan 3.

PMID:
24386941
46.

Multimetallic Cooperativity in Activation of Dinitrogen at Iron-Potassium Sites.

Chiang KP, Bellows SM, Brennessel WW, Holland PL.

Chem Sci. 2014 Jan 1;5(1). doi: 10.1039/C3SC52487F.

47.

Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges.

Dugan TR, Macleod KC, Brennessel WW, Holland PL.

Eur J Inorg Chem. 2013 Aug 1;2013(22-23). doi: 10.1002/ejic.201300187.

48.

Nickel pyridinethiolate complexes as catalysts for the light-driven production of hydrogen from aqueous solutions in noble-metal-free systems.

Han Z, Shen L, Brennessel WW, Holland PL, Eisenberg R.

J Am Chem Soc. 2013 Oct 2;135(39):14659-69. doi: 10.1021/ja405257s. Epub 2013 Sep 18.

PMID:
24004329
49.

Generation of high-spin iron(I) in a protein environment using cryoreduction.

Davydov RM, McLaughlin MP, Bill E, Hoffman BM, Holland PL.

Inorg Chem. 2013 Jul 1;52(13):7323-5. doi: 10.1021/ic4011339. Epub 2013 Jun 10.

50.

Experimentally quantifying small-molecule bond activation using valence-to-core X-ray emission spectroscopy.

Pollock CJ, Grubel K, Holland PL, DeBeer S.

J Am Chem Soc. 2013 Aug 14;135(32):11803-8. doi: 10.1021/ja3116247. Epub 2013 Jul 30.

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