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Items: 1 to 50 of 102

1.

Central (S) to Central (M = Ir, Rh) to Planar (Metallocene, M = Fe, Ru) Chirality Transfer Using Sulfoxide Substituted Mesoionic Carbene Ligands: Synthesis of Bimetallic Planar-Chiral Metallocenes.

Sierra MA, de la Torre MC, Avello MG, Gornitzka H, Hemmert C.

Chemistry. 2019 Aug 9. doi: 10.1002/chem.201902102. [Epub ahead of print]

PMID:
31397497
2.

Arsagermene, a compound with an -As[double bond, length as m-dash]Ge[double bond splayed right] double bond.

Lee VY, Kawai M, Gapurenko OA, Minkin VI, Gornitzka H, Sekiguchi A.

Chem Commun (Camb). 2018 Sep 27;54(78):10947-10949. doi: 10.1039/c8cc05630g.

PMID:
30105326
3.

Pharmacomodulation on Gold-NHC complexes for anticancer applications - is lipophilicity the key point?

Zhang C, Maddelein ML, Wai-Yin Sun R, Gornitzka H, Cuvillier O, Hemmert C.

Eur J Med Chem. 2018 Sep 5;157:320-332. doi: 10.1016/j.ejmech.2018.07.070. Epub 2018 Aug 2.

PMID:
30099254
4.

From Borapyramidane to Borole Dianion.

Lee VY, Sugasawa H, Gapurenko OA, Minyaev RM, Minkin VI, Gornitzka H, Sekiguchi A.

J Am Chem Soc. 2018 May 16;140(19):6053-6056. doi: 10.1021/jacs.8b03473. Epub 2018 May 2.

PMID:
29669416
5.

Cationic and Neutral N-Heterocyclic Carbene Gold(I) Complexes: Cytotoxicity, NCI-60 Screening, Cellular Uptake, Inhibition of Mammalian Thioredoxin Reductase, and Reactive Oxygen Species Formation.

Zhang C, Hemmert C, Gornitzka H, Cuvillier O, Zhang M, Sun RW.

ChemMedChem. 2018 Jun 20;13(12):1218-1229. doi: 10.1002/cmdc.201800181. Epub 2018 May 23.

PMID:
29603648
6.

Synthesis, characterization, and antileishmanial activity of neutral N-heterocyclic carbenes gold(I) complexes.

Zhang C, Bourgeade Delmas S, Fernández Álvarez Á, Valentin A, Hemmert C, Gornitzka H.

Eur J Med Chem. 2018 Jan 1;143:1635-1643. doi: 10.1016/j.ejmech.2017.10.060. Epub 2017 Oct 24.

PMID:
29133045
7.

Bis(stibahousene).

Lee VY, Ota K, Ito Y, Gapurenko OA, Sekiguchi A, Minyaev RM, Minkin VI, Gornitzka H.

J Am Chem Soc. 2017 Oct 4;139(39):13897-13902. doi: 10.1021/jacs.7b07712. Epub 2017 Sep 22.

PMID:
28892377
8.

Chiral Sulfur Functional Groups as Definers of the Chirality at the Metal in Ir and Rh Half-Sandwich Complexes: A Combined CD/X-ray Study.

Avello MG, Frutos M, de la Torre MC, Viso A, Velado M, de la Pradilla RF, Sierra MA, Gornitzka H, Hemmert C.

Chemistry. 2017 Oct 17;23(58):14523-14531. doi: 10.1002/chem.201702662. Epub 2017 Sep 18.

PMID:
28749583
9.

Gold(I)-Catalyzed Cycloisomerization-Dimerization Cascade of Benzene-Tethered 1,6-Enynes.

Álvarez-Pérez M, Frutos M, Viso A, Fernández de la Pradilla R, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

J Org Chem. 2017 Jul 21;82(14):7546-7554. doi: 10.1021/acs.joc.7b01273. Epub 2017 Jul 5.

PMID:
28650170
10.

"Breathing" Motion of a Modulable Molecular Cavity.

Zhang D, Cochrane JR, Di Pietro S, Guy L, Gornitzka H, Dutasta JP, Martinez A.

Chemistry. 2017 May 11;23(27):6495-6498. doi: 10.1002/chem.201700395. Epub 2017 Apr 20.

PMID:
28158931
11.

Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)-1,2,3-Triazole Carbene Complexes.

Frutos M, Ortuño MA, Lledos A, Viso A, Fernández de la Pradilla R, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

Org Lett. 2017 Feb 17;19(4):822-825. doi: 10.1021/acs.orglett.6b03808. Epub 2017 Jan 30.

PMID:
28135109
12.

A Cationic Phosphapyramidane.

Lee VY, Sugasawa H, Gapurenko OA, Minyaev RM, Minkin VI, Gornitzka H, Sekiguchi A.

Chemistry. 2016 Dec 5;22(49):17585-17589. doi: 10.1002/chem.201604480. Epub 2016 Oct 24.

PMID:
27775186
13.

Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity.

Frutos M, Avello MG, Viso A, Fernández de la Pradilla R, de la Torre MC, Sierra MA, Gornitzka H, Hemmert C.

Org Lett. 2016 Aug 5;18(15):3570-3. doi: 10.1021/acs.orglett.6b01555. Epub 2016 Jul 12.

PMID:
27403763
14.

Antiplasmodial activities of gold(I) complexes involving functionalized N-heterocyclic carbenes.

Hemmert C, Ramadani AP, Boselli L, Fernández Álvarez Á, Paloque L, Augereau JM, Gornitzka H, Benoit-Vical F.

Bioorg Med Chem. 2016 Jul 1;24(13):3075-3082. doi: 10.1016/j.bmc.2016.05.023. Epub 2016 May 17.

PMID:
27240469
15.

Luminescent bioactive NHC-metal complexes to bring light into cells.

Hemmert C, Gornitzka H.

Dalton Trans. 2016 Jan 14;45(2):440-7. doi: 10.1039/c5dt03904e.

PMID:
26631876
16.

From a Si3-Cyclopropene to a Si3S-Bicyclo[1.1.0]butane to a Si3S-Cyclopropene to a Si3S2-Bicyclo[1.1.0]butane: Back-and-Forth, and In-Between.

Lee VY, Gapurenko OA, Miyazaki S, Sekiguchi A, Minyaev RM, Minkin VI, Gornitzka H.

Angew Chem Int Ed Engl. 2015 Nov 16;54(47):14118-22. doi: 10.1002/anie.201506625. Epub 2015 Sep 25.

PMID:
26403356
17.

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO2 nanoparticles.

Matioszek D, Ojo WS, Cornejo A, Katir N, El Ezzi M, Le Troedec M, Martinez H, Gornitzka H, Castel A, Nayral C, Delpech F.

Dalton Trans. 2015 Apr 28;44(16):7242-50. doi: 10.1039/c5dt00392j.

PMID:
25790067
18.

Pentagermapyramidane: crystallizing the "transition-state" structure.

Lee VY, Ito Y, Gapurenko OA, Sekiguchi A, Minkin VI, Minyaev RM, Gornitzka H.

Angew Chem Int Ed Engl. 2015 May 4;54(19):5654-7. doi: 10.1002/anie.201500731. Epub 2015 Mar 13.

PMID:
25777772
19.

Synthesis, characterization, and antileishmanial activities of gold(I) complexes involving quinoline functionalized N-heterocyclic carbenes.

Paloque L, Hemmert C, Valentin A, Gornitzka H.

Eur J Med Chem. 2015 Apr 13;94:22-9. doi: 10.1016/j.ejmech.2015.02.046. Epub 2015 Feb 25.

PMID:
25747497
20.

Remote stereocontrol in the synthesis of acyclic 1,4-diols and 1,4-aminoalcohols from 2-sulfinyl dienes.

Fernández de la Pradilla R, Velado M, Colomer I, Simal C, Viso A, Gornitzka H, Hemmert C.

Org Lett. 2014 Oct 3;16(19):5200-3. doi: 10.1021/ol502592y. Epub 2014 Sep 24.

PMID:
25252268
21.

Synthesis, structures, and selective toxicity to cancer cells of gold(I) complexes involving N-heterocyclic carbene ligands.

Boselli L, Ader I, Carraz M, Hemmert C, Cuvillier O, Gornitzka H.

Eur J Med Chem. 2014 Oct 6;85:87-94. doi: 10.1016/j.ejmech.2014.07.086. Epub 2014 Jul 24.

PMID:
25078312
22.

Superbases in confined space: control of the basicity and reactivity of the proton transfer.

Chatelet B, Gornitzka H, Dufaud V, Jeanneau E, Dutasta JP, Martinez A.

J Am Chem Soc. 2013 Dec 11;135(49):18659-64. doi: 10.1021/ja409444s. Epub 2013 Nov 22.

PMID:
24228613
23.

Pyramidanes.

Lee VY, Ito Y, Sekiguchi A, Gornitzka H, Gapurenko OA, Minkin VI, Minyaev RM.

J Am Chem Soc. 2013 Jun 19;135(24):8794-7. doi: 10.1021/ja403173e. Epub 2013 Jun 5.

PMID:
23718868
24.

Spirobis(pentagerma[1.1.1]propellane): a stable tetraradicaloid.

Ito Y, Lee VY, Gornitzka H, Goedecke C, Frenking G, Sekiguchi A.

J Am Chem Soc. 2013 May 8;135(18):6770-3. doi: 10.1021/ja401650q. Epub 2013 Apr 23.

PMID:
23594370
25.

Toward a silicon version of metathesis: from Schrock-type titanium silylidenes to silatitanacyclobutenes.

Lee VY, Aoki S, Yokoyama T, Horiguchi S, Sekiguchi A, Gornitzka H, Guo JD, Nagase S.

J Am Chem Soc. 2013 Feb 27;135(8):2987-90. doi: 10.1021/ja401072j. Epub 2013 Feb 18.

PMID:
23406539
26.

Synthesis, structures, and antimalarial activities of some silver(I), gold(I) and gold(III) complexes involving N-heterocyclic carbene ligands.

Hemmert C, Fabié A, Fabre A, Benoit-Vical F, Gornitzka H.

Eur J Med Chem. 2013 Feb;60:64-75. doi: 10.1016/j.ejmech.2012.11.038. Epub 2012 Dec 7.

PMID:
23287052
27.

Surprising unreactivity of cholesterol-5,6-epoxides towards nucleophiles.

Paillasse MR, Saffon N, Gornitzka H, Silvente-Poirot S, Poirot M, de Medina P.

J Lipid Res. 2012 Apr;53(4):718-25. doi: 10.1194/jlr.M023689. Epub 2012 Jan 29. Erratum in: J Lipid Res. 2012 May;53(5):1037.

28.

Combined cation-π and anion-π interactions for zwitterion recognition.

Perraud O, Robert V, Gornitzka H, Martinez A, Dutasta JP.

Angew Chem Int Ed Engl. 2012 Jan 9;51(2):504-8. doi: 10.1002/anie.201106934. Epub 2011 Nov 23.

PMID:
22109959
29.

Versatile stereoselective cycloadditions between heterocumulenes and phosphagermaallene Tip(tBu)Ge=C=PMes*: experimental and theoretical investigations.

Ghereg D, André E, Gornitzka H, Escudié J, Ouhsaine F, Saffon N, Miqueu K, Sotiropoulos JM.

Chemistry. 2011 Nov 4;17(45):12763-72. doi: 10.1002/chem.201100281. Epub 2011 Sep 28.

PMID:
21956731
30.

Electronic properties and reactivity of an isolable phosphagermaheterocyclic carbene.

Ghereg D, Ladeira S, Saffon N, Escudié J, Gornitzka H.

Angew Chem Int Ed Engl. 2011 Aug 8;50(33):7607-10. doi: 10.1002/anie.201102500. Epub 2011 Jun 29. No abstract available.

PMID:
21717549
31.

Encaging the Verkade's superbases: thermodynamic and kinetic consequences.

Raytchev PD, Martinez A, Gornitzka H, Dutasta JP.

J Am Chem Soc. 2011 Feb 23;133(7):2157-9. doi: 10.1021/ja1110333. Epub 2011 Jan 31.

PMID:
21280610
32.

The reactivity of phosphagermaallene Tip(t-Bu)Ge=C=PMes* with doubly and triply bonded nitrogen compounds.

Ghereg D, Gornitzka H, Escudié J, Ladeira S.

Inorg Chem. 2010 Nov 15;49(22):10497-505. doi: 10.1021/ic1014913. Epub 2010 Oct 13.

PMID:
20942445
33.

1,3-Dipole behavior of phosphagermaallene Tip(tBu)Ge=C=PMes* leading to a phosphagermaheterocyclic carbene.

Ghereg D, André E, Sotiropoulos JM, Miqueu K, Gornitzka H, Escudié J.

Angew Chem Int Ed Engl. 2010 Nov 8;49(46):8704-7. doi: 10.1002/anie.201003044. No abstract available.

PMID:
20836104
34.

Reactions of germenes with various naphthoquinones controlled by substituent effects.

Ghereg D, Gornitzka H, Ranaivonjatovo H, Escudié J.

Dalton Trans. 2010 Feb 28;39(8):2016-22. doi: 10.1039/b921729k. Epub 2010 Jan 12.

PMID:
20148219
35.

Controlling helical chirality in atrane structures: solvent-dependent chirality sense in hemicryptophane-oxidovanadium(V) complexes.

Martinez A, Robert V, Gornitzka H, Dutasta JP.

Chemistry. 2010 Jan 11;16(2):520-7. doi: 10.1002/chem.200901976.

PMID:
19918819
36.

Antimalarial activity of simalikalactone E, a new quassinoid from Quassia amara L. (Simaroubaceae).

Cachet N, Hoakwie F, Bertani S, Bourdy G, Deharo E, Stien D, Houel E, Gornitzka H, Fillaux J, Chevalley S, Valentin A, Jullian V.

Antimicrob Agents Chemother. 2009 Oct;53(10):4393-8. doi: 10.1128/AAC.00951-09. Epub 2009 Aug 10.

37.

An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide.

Ghereg D, Ech-Cherif El Kettani S, Lazraq M, Ranaivonjatovo H, Schoeller WW, Escudié J, Gornitzka H.

Chem Commun (Camb). 2009 Aug 28;(32):4821-3. doi: 10.1039/b910001f. Epub 2009 Jul 14.

PMID:
19652792
38.

Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization.

Benhamou L, César V, Gornitzka H, Lugan N, Lavigne G.

Chem Commun (Camb). 2009 Aug 21;(31):4720-2. doi: 10.1039/b907908d. Epub 2009 Jun 25.

PMID:
19641821
39.

Dinuclear gold(I) and gold(III) complexes of bridging functionalized bis(N-heterocyclic carbene) ligands: synthesis, structural, spectroscopic and electrochemical characterizations.

Jean-Baptiste dit Dominique F, Gornitzka H, Sournia-Saquet A, Hemmert C.

Dalton Trans. 2009 Jan 14;(2):340-52. doi: 10.1039/b809943j. Epub 2008 Nov 6.

PMID:
19089016
40.

An unexpected epoxidation of benzil derivatives in their reaction with a germene.

El Kettani SE, Lazraq M, Ouhsaine F, Gornitzka H, Ranaivonjatovo H, Escudié J.

Org Biomol Chem. 2008 Nov 7;6(21):4064-6. doi: 10.1039/b812694c. Epub 2008 Sep 10.

PMID:
18931816
41.

Novel N-phosphonio imine-catalyzed epoxidation reactions.

Prieur D, El Kazzi A, Kato T, Gornitzka H, Baceiredo A.

Org Lett. 2008 Jun 5;10(11):2291-4. doi: 10.1021/ol800690c. Epub 2008 May 7.

PMID:
18459794
42.

Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes.

Vignolle J, Gornitzka H, Donnadieu B, Bourissou D, Bertrand G.

Angew Chem Int Ed Engl. 2008;47(12):2271-4. doi: 10.1002/anie.200704927. No abstract available.

43.

Stereoselective coordination of ditopic phospholyl-azahelicenes: a novel approach towards structural diversity in chiral pi-conjugated assemblies.

Shen W, Graule S, Crassous J, Lescop C, Gornitzka H, Réau R.

Chem Commun (Camb). 2008 Feb 21;(7):850-2. doi: 10.1039/b714340k. Epub 2007 Dec 18.

PMID:
18253525
44.

Preparation and study of new poly-8-hydroxyquinoline chelators for an anti-Alzheimer strategy.

Deraeve C, Boldron C, Maraval A, Mazarguil H, Gornitzka H, Vendier L, Pitié M, Meunier B.

Chemistry. 2008;14(2):682-96.

PMID:
17969218
45.

Palladate salts from chiral pyridinium ionic liquids: synthesis and crystal structures.

Tourneux E, Gornitzka H, Marty JD, Lauth-de Viguerie N.

Molecules. 2007 Aug 20;12(8):1940-9.

46.

1,3-Digermacyclobutanes with exocyclic C=P and C=P=S double bonds.

Petrar PM, Nemes G, Silaghi-Dumitrescu I, Ranaivonjatovo H, Gornitzka H, Escudié J.

Chem Commun (Camb). 2007 Oct 28;(40):4149-51. Epub 2007 Aug 3.

PMID:
17925958
47.

Changes of the membrane lipid organization characterized by means of a new cholesterol-pyrene probe.

Le Guyader L, Le Roux C, Mazères S, Gaspard-Iloughmane H, Gornitzka H, Millot C, Mingotaud C, Lopez A.

Biophys J. 2007 Dec 15;93(12):4462-73. Epub 2007 Aug 31.

48.

Synthesis of ferulic ester dimers, functionalisation and biological evaluation as potential antiatherogenic and antiplasmodial agents.

Rakotondramanana DL, Delomenède M, Baltas M, Duran H, Bedos-Belval F, Rasoanaivo P, Negre-Salvayre A, Gornitzka H.

Bioorg Med Chem. 2007 Sep 15;15(18):6018-26. Epub 2007 Jun 29.

PMID:
17624792
49.

Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls.

Bourg JB, Rodriguez A, Scheschkewitz D, Gornitzka H, Bourissou D, Bertrand G.

Angew Chem Int Ed Engl. 2007;46(30):5741-5. No abstract available.

PMID:
17592605
50.

Spirolactone iridoids might be responsible for the antileishmanial activity of a Peruvian traditional remedy made with Himatanthus sucuuba (Apocynaceae).

Castillo D, Arevalo J, Herrera F, Ruiz C, Rojas R, Rengifo E, Vaisberg A, Lock O, Lemesre JL, Gornitzka H, Sauvain M.

J Ethnopharmacol. 2007 Jun 13;112(2):410-4. Epub 2007 Mar 24.

PMID:
17459622

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