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Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies.

Zaragoza JPT, Cummins DC, Mubarak MQE, Siegler MA, de Visser SP, Goldberg DP.

Inorg Chem. 2019 Dec 16;58(24):16761-16770. doi: 10.1021/acs.inorgchem.9b02923. Epub 2019 Dec 5.


Activation of Dioxygen by a Mononuclear Nonheme Iron Complex: Sequential Peroxo, Oxo, and Hydroxo Intermediates.

Gordon JB, Vilbert AC, DiMucci IM, MacMillan SN, Lancaster KM, Moënne-Loccoz P, Goldberg DP.

J Am Chem Soc. 2019 Nov 6;141(44):17533-17547. doi: 10.1021/jacs.9b05274. Epub 2019 Oct 24.


Mononuclear, Nonheme, High-Spin {FeNO}7/8 Complexes Supported by a Sterically Encumbered N4S-Thioether Ligand.

Confer AM, Sabuncu S, Siegler MA, Moënne-Loccoz P, Goldberg DP.

Inorg Chem. 2019 Aug 5;58(15):9576-9580. doi: 10.1021/acs.inorgchem.9b01475. Epub 2019 Jul 22.


Mechanistic Investigation of Oxygen Rebound in a Mononuclear Nonheme Iron Complex.

Pangia TM, Yadav V, Gérard EF, Lin YT, de Visser SP, Jameson GNL, Goldberg DP.

Inorg Chem. 2019 Aug 5;58(15):9557-9561. doi: 10.1021/acs.inorgchem.9b01208. Epub 2019 Jul 17.


Dioxygen-Derived Nonheme Mononuclear FeIII(OH) Complex and Its Reactivity with Carbon Radicals.

Yadav V, Gordon JB, Siegler MA, Goldberg DP.

J Am Chem Soc. 2019 Jul 3;141(26):10148-10153. doi: 10.1021/jacs.9b03329. Epub 2019 Jun 20.


A Mononuclear, Nonheme FeII-Piloty's Acid (PhSO2NHOH) Adduct: An Intermediate in the Production of {FeNO}7/8 Complexes from Piloty's Acid.

Confer AM, Vilbert AC, Dey A, Lancaster KM, Goldberg DP.

J Am Chem Soc. 2019 May 1;141(17):7046-7055. doi: 10.1021/jacs.9b01700. Epub 2019 Apr 17.


A Nonheme Thiolate-Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity.

Gordon JB, Vilbert AC, Siegler MA, Lancaster KM, Moënne-Loccoz P, Goldberg DP.

J Am Chem Soc. 2019 Feb 27;141(8):3641-3653. doi: 10.1021/jacs.8b13134. Epub 2019 Feb 18.


The hydrogen atom transfer reactivity of a porphyrinoid cobalt superoxide complex.

Sacramento JJD, Goldberg DP.

Chem Commun (Camb). 2019 Jan 17;55(7):913-916. doi: 10.1039/c8cc08453j.


Factors Affecting Hydrogen Atom Transfer Reactivity of Metal-Oxo Porphyrinoid Complexes.

Sacramento JJD, Goldberg DP.

Acc Chem Res. 2018 Nov 20;51(11):2641-2652. doi: 10.1021/acs.accounts.8b00414. Epub 2018 Nov 7.


Diagnostic consequences of a new category of anxious depression and a reduced duration requirement for anxiety symptoms in the ICD-11 PHC.

Ziebold C, Mari JJ, Goldberg DP, Minhas F, Razzaque B, Fortes S, Robles R, Lam TP, Bobes J, Iglesias C, García JÁ, Reed GM.

J Affect Disord. 2019 Feb 15;245:120-125. doi: 10.1016/j.jad.2018.10.082. Epub 2018 Oct 6.


Structures, Spectroscopic Properties, and Dioxygen Reactivity of 5- and 6-Coordinate Nonheme Iron(II) Complexes: A Combined Enzyme/Model Study of Thiol Dioxygenases.

Gordon JB, McGale JP, Prendergast JR, Shirani-Sarmazeh Z, Siegler MA, Jameson GNL, Goldberg DP.

J Am Chem Soc. 2018 Nov 7;140(44):14807-14822. doi: 10.1021/jacs.8b08349. Epub 2018 Oct 22.


A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues.

Dey A, Confer AM, Vilbert AC, Moënne-Loccoz P, Lancaster KM, Goldberg DP.

Angew Chem Int Ed Engl. 2018 Oct 8;57(41):13465-13469. doi: 10.1002/anie.201806146. Epub 2018 Sep 17.


Dimensional analysis of depressive, anxious and somatic symptoms presented by primary care patients and their relationship with ICD-11 PHC proposed diagnoses.

Ziebold C, Goldberg DP, Reed GM, Minhas F, Razzaque B, Fortes S, Robles R, Lam TP, Bobes J, Iglesias C, Cogo-Moreira H, García JÁ, Mari JJ.

Psychol Med. 2019 Apr;49(5):764-771. doi: 10.1017/S0033291718001381. Epub 2018 Jun 4.


A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds.

Zaragoza JPT, Siegler MA, Goldberg DP.

J Am Chem Soc. 2018 Mar 28;140(12):4380-4390. doi: 10.1021/jacs.8b00350. Epub 2018 Mar 15.


Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex.

Pangia TM, Davies CG, Prendergast JR, Gordon JB, Siegler MA, Jameson GNL, Goldberg DP.

J Am Chem Soc. 2018 Mar 28;140(12):4191-4194. doi: 10.1021/jacs.7b12707. Epub 2018 Mar 14.


Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.

Baglia RA, Zaragoza JPT, Goldberg DP.

Chem Rev. 2017 Nov 8;117(21):13320-13352. doi: 10.1021/acs.chemrev.7b00180. Epub 2017 Oct 9.


Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex.

Zaragoza JPT, Yosca TH, Siegler MA, Moënne-Loccoz P, Green MT, Goldberg DP.

J Am Chem Soc. 2017 Oct 4;139(39):13640-13643. doi: 10.1021/jacs.7b07979. Epub 2017 Sep 20.


A Nonheme, High-Spin {FeNO}8 Complex that Spontaneously Generates N2O.

Confer AM, McQuilken AC, Matsumura H, Moënne-Loccoz P, Goldberg DP.

J Am Chem Soc. 2017 Aug 9;139(31):10621-10624. doi: 10.1021/jacs.7b05549. Epub 2017 Jul 27.


Primary care physicians' use of the proposed classification of common mental disorders for ICD-11.

Goldberg DP, Lam TP, Minhas F, Razzaque B, Robles R, Bobes J, Iglesias C, Fortes S, Mari JJ, Gask L, García JÁ, Dowell AC, Rosendal M, Reed GM.

Fam Pract. 2017 Sep 1;34(5):574-580. doi: 10.1093/fampra/cmx033.


Screening for anxiety, depression, and anxious depression in primary care: A field study for ICD-11 PHC.

Goldberg DP, Reed GM, Robles R, Minhas F, Razzaque B, Fortes S, Mari JJ, Lam TP, Garcia JÁ, Gask L, Dowell AC, Rosendal M, Mbatia JK, Saxena S.

J Affect Disord. 2017 Apr 15;213:199-206. doi: 10.1016/j.jad.2017.02.025. Epub 2017 Feb 20.


meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine.

Joslin EE, Zaragoza JP, Siegler MA, Goldberg DP.

Chem Commun (Camb). 2017 Feb 7;53(12):1961-1964. doi: 10.1039/c6cc09341h.


Multiple somatic symptoms in primary care: A field study for ICD-11 PHC, WHO's revised classification of mental disorders in primary care settings.

Goldberg DP, Reed GM, Robles R, Bobes J, Iglesias C, Fortes S, de Jesus Mari J, Lam TP, Minhas F, Razzaque B, Garcia JÁ, Rosendal M, Dowell CA, Gask L, Mbatia JK, Saxena S.

J Psychosom Res. 2016 Dec;91:48-54. doi: 10.1016/j.jpsychores.2016.10.002. Epub 2016 Oct 4.


High-Valent Manganese-Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C-H Bond Cleavage.

Baglia RA, Krest CM, Yang T, Leeladee P, Goldberg DP.

Inorg Chem. 2016 Oct 17;55(20):10800-10809. Epub 2016 Sep 30.


Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.

Sahu S, Zhang B, Pollock CJ, Dürr M, Davies CG, Confer AM, Ivanović-Burmazović I, Siegler MA, Jameson GN, Krebs C, Goldberg DP.

J Am Chem Soc. 2016 Oct 5;138(39):12791-12802. Epub 2016 Sep 22.


Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.

Sahu S, Goldberg DP.

J Am Chem Soc. 2016 Sep 14;138(36):11410-28. doi: 10.1021/jacs.6b05251. Epub 2016 Aug 30. Review.


Singlet versus Triplet Reactivity in an Mn(V)-Oxo Species: Testing Theoretical Predictions Against Experimental Evidence.

Yang T, Quesne MG, Neu HM, Cantú Reinhard FG, Goldberg DP, de Visser SP.

J Am Chem Soc. 2016 Sep 28;138(38):12375-86. doi: 10.1021/jacs.6b05027. Epub 2016 Sep 14.


The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.

Joslin EE, Zaragoza JP, Baglia RA, Siegler MA, Goldberg DP.

Inorg Chem. 2016 Sep 6;55(17):8646-60. doi: 10.1021/acs.inorgchem.6b01219. Epub 2016 Aug 16.


Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.

Jung J, Neu HM, Leeladee P, Siegler MA, Ohkubo K, Goldberg DP, Fukuzumi S.

Inorg Chem. 2016 Apr 4;55(7):3218-28. doi: 10.1021/acs.inorgchem.5b02019. Epub 2016 Mar 14.


Revisiting and re-engineering the classical zinc finger peptide: consensus peptide-1 (CP-1).

Besold AN, Widger LR, Namuswe F, Michalek JL, Michel SL, Goldberg DP.

Mol Biosyst. 2016 Apr;12(4):1183-93. doi: 10.1039/c5mb00796h. Epub 2016 Mar 3.


Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}(7) Complex with Dioxygen.

McQuilken AC, Matsumura H, Dürr M, Confer AM, Sheckelton JP, Siegler MA, McQueen TM, Ivanović-Burmazović I, Moënne-Loccoz P, Goldberg DP.

J Am Chem Soc. 2016 Mar 9;138(9):3107-17. doi: 10.1021/jacs.5b12741. Epub 2016 Feb 26.


Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity.

Zaragoza JP, Siegler MA, Goldberg DP.

Chem Commun (Camb). 2016 Jan 4;52(1):167-70. doi: 10.1039/c5cc07956j.


A Balancing Act: Stability versus Reactivity of Mn(O) Complexes.

Neu HM, Baglia RA, Goldberg DP.

Acc Chem Res. 2015 Oct 20;48(10):2754-64. doi: 10.1021/acs.accounts.5b00273. Epub 2015 Sep 9.


Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction.

Baglia RA, Prokop-Prigge KA, Neu HM, Siegler MA, Goldberg DP.

J Am Chem Soc. 2015 Sep 2;137(34):10874-7. doi: 10.1021/jacs.5b05142. Epub 2015 Aug 21.


Modelling the cost-effectiveness of pharmacotherapy compared with cognitive-behavioural therapy and combination therapy for the treatment of moderate to severe depression in the UK.

Koeser L, Donisi V, Goldberg DP, McCrone P.

Psychol Med. 2015 Oct;45(14):3019-31. doi: 10.1017/S0033291715000951. Epub 2015 Jun 4. Review.


Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid Complexes.

Zaragoza JP, Baglia RA, Siegler MA, Goldberg DP.

J Am Chem Soc. 2015 May 27;137(20):6531-40. doi: 10.1021/jacs.5b00875. Epub 2015 May 12.


Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex.

Neu HM, Jung J, Baglia RA, Siegler MA, Ohkubo K, Fukuzumi S, Goldberg DP.

J Am Chem Soc. 2015 Apr 15;137(14):4614-7. doi: 10.1021/jacs.5b00816. Epub 2015 Apr 3.


Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex.

Neu HM, Quesne MG, Yang T, Prokop-Prigge KA, Lancaster KM, Donohoe J, DeBeer S, de Visser SP, Goldberg DP.

Chemistry. 2014 Nov 3;20(45):14584-8. doi: 10.1002/chem.201404349. Epub 2014 Sep 26.


Direct observation of a nonheme iron(IV)-oxo complex that mediates aromatic C-F hydroxylation.

Sahu S, Quesne MG, Davies CG, Dürr M, Ivanović-Burmazović I, Siegler MA, Jameson GN, de Visser SP, Goldberg DP.

J Am Chem Soc. 2014 Oct 1;136(39):13542-5. doi: 10.1021/ja507346t. Epub 2014 Sep 23.


Oxygen-atom transfer reactivity of axially ligated Mn(V)-oxo complexes: evidence for enhanced electrophilic and nucleophilic pathways.

Neu HM, Yang T, Baglia RA, Yosca TH, Green MT, Quesne MG, de Visser SP, Goldberg DP.

J Am Chem Soc. 2014 Oct 1;136(39):13845-52. doi: 10.1021/ja507177h. Epub 2014 Sep 19.


Photocatalytic oxygenation of 10-methyl-9,10-dihydroacridine by O₂ with manganese porphyrins.

Jung J, Ohkubo K, Goldberg DP, Fukuzumi S.

J Phys Chem A. 2014 Aug 14;118(32):6223-9. doi: 10.1021/jp505860f. Epub 2014 Jul 31.


Activation of a high-valent manganese-oxo complex by a nonmetallic Lewis acid.

Baglia RA, Dürr M, Ivanović-Burmazović I, Goldberg DP.

Inorg Chem. 2014 Jun 16;53(12):5893-5. doi: 10.1021/ic500901y. Epub 2014 May 29.


Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere.

Widger LR, Jiang Y, McQuilken AC, Yang T, Siegler MA, Matsumura H, Moënne-Loccoz P, Kumar D, de Visser SP, Goldberg DP.

Dalton Trans. 2014 May 28;43(20):7522-32. doi: 10.1039/c4dt00281d.


Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres.

Widger LR, Davies CG, Yang T, Siegler MA, Troeppner O, Jameson GN, Ivanović-Burmazović I, Goldberg DP.

J Am Chem Soc. 2014 Feb 19;136(7):2699-702. doi: 10.1021/ja410240c. Epub 2014 Feb 10.


Training teachers to teach mental health skills to staff in primary care settings in a vast, under-populated area.

Goldberg DP, Gask L, Zakroyeva A, Proselkova E, Ryzhkova N, Williams P.

Ment Health Fam Med. 2012 Dec;9(4):219-24.


Anxious forms of depression.

Goldberg DP.

Depress Anxiety. 2014 Apr;31(4):344-51. doi: 10.1002/da.22206. Epub 2013 Nov 27. Review.


Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex.

Jung J, Ohkubo K, Prokop-Prigge KA, Neu HM, Goldberg DP, Fukuzumi S.

Inorg Chem. 2013 Dec 2;52(23):13594-604. doi: 10.1021/ic402121j. Epub 2013 Nov 12.


Preparation of non-heme {FeNO}7 models of cysteine dioxygenase: sulfur versus nitrogen ligation and photorelease of nitric oxide.

McQuilken AC, Ha Y, Sutherlin KD, Siegler MA, Hodgson KO, Hedman B, Solomon EI, Jameson GN, Goldberg DP.

J Am Chem Soc. 2013 Sep 25;135(38):14024-7. doi: 10.1021/ja4064487. Epub 2013 Sep 17.


Synthesis and ligand non-innocence of thiolate-ligated (N4S) Iron(II) and nickel(II) bis(imino)pyridine complexes.

Widger LR, Jiang Y, Siegler MA, Kumar D, Latifi R, de Visser SP, Jameson GN, Goldberg DP.

Inorg Chem. 2013 Sep 16;52(18):10467-80. doi: 10.1021/ic4013558. Epub 2013 Aug 30.


Anxious and non-anxious forms of major depression: familial, personality and symptom characteristics.

Goldberg DP, Wittchen HU, Zimmermann P, Pfister H, Beesdo-Baum K.

Psychol Med. 2014 Apr;44(6):1223-34. doi: 10.1017/S0033291713001827. Epub 2013 Aug 1.


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