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Items: 1 to 50 of 94

1.

Toward digitally controlled catalyst architectures: Hierarchical nanoporous gold via 3D printing.

Zhu C, Qi Z, Beck VA, Luneau M, Lattimer J, Chen W, Worsley MA, Ye J, Duoss EB, Spadaccini CM, Friend CM, Biener J.

Sci Adv. 2018 Aug 31;4(8):eaas9459. doi: 10.1126/sciadv.aas9459. eCollection 2018 Aug.

2.

Spatially Nonuniform Reaction Rates during Selective Oxidation on Gold.

Xu F, Madix RJ, Friend CM.

J Am Chem Soc. 2018 Sep 17. doi: 10.1021/jacs.8b07438. [Epub ahead of print]

PMID:
30176212
3.

Perspectives on the design of nanoparticle systems for catalysis.

Friend CM, Xu F.

Faraday Discuss. 2018 Sep 3;208(0):595-607. doi: 10.1039/c8fd00124c.

PMID:
30116826
4.

Identifying key descriptors in surface binding: interplay of surface anchoring and intermolecular interactions for carboxylates on Au(110).

O'Connor CR, Hiebel F, Chen W, Kaxiras E, Madix RJ, Friend CM.

Chem Sci. 2018 Mar 12;9(15):3759-3766. doi: 10.1039/c7sc05313d. eCollection 2018 Apr 21.

5.

Water facilitates oxygen migration on gold surfaces.

Xu F, Fampiou I, O'Connor CR, Karakalos S, Hiebel F, Kaxiras E, Madix RJ, Friend CM.

Phys Chem Chem Phys. 2018 Jan 24;20(4):2196-2204. doi: 10.1039/c7cp06451a.

PMID:
29234757
6.

O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts.

Montemore MM, van Spronsen MA, Madix RJ, Friend CM.

Chem Rev. 2018 Mar 14;118(5):2816-2862. doi: 10.1021/acs.chemrev.7b00217. Epub 2017 Nov 8.

PMID:
29116787
7.

New Architectures for Designed Catalysts: Selective Oxidation using AgAu Nanoparticles on Colloid-Templated Silica.

Shirman T, Lattimer J, Luneau M, Shirman E, Reece C, Aizenberg M, Madix RJ, Aizenberg J, Friend CM.

Chemistry. 2018 Feb 6;24(8):1833-1837. doi: 10.1002/chem.201704552. Epub 2017 Nov 14.

PMID:
28960528
8.

Heterogeneous Catalysis: A Central Science for a Sustainable Future.

Friend CM, Xu B.

Acc Chem Res. 2017 Mar 21;50(3):517-521. doi: 10.1021/acs.accounts.6b00510.

PMID:
28945397
9.

Structure of the Clean and Oxygen-Covered Cu(100) Surface at Room Temperature in the Presence of Methanol Vapor in the 10-200 mTorr Pressure Range.

Eren B, Kersell H, Weatherup RS, Heine C, Crumlin EJ, Friend CM, Salmeron MB.

J Phys Chem B. 2018 Jan 18;122(2):548-554. doi: 10.1021/acs.jpcb.7b04681. Epub 2017 Aug 14.

PMID:
28749680
10.

General Effect of van der Waals Interactions on the Stability of Alkoxy Intermediates on Metal Surfaces.

Xu Y, Chen W, Kaxiras E, Friend CM, Madix RJ.

J Phys Chem B. 2018 Jan 18;122(2):555-560. doi: 10.1021/acs.jpcb.7b04952. Epub 2017 Aug 7.

PMID:
28722410
11.

Multiscale Morphology of Nanoporous Copper Made from Intermetallic Phases.

Egle T, Barroo C, Janvelyan N, Baumgaertel AC, Akey AJ, Biener MM, Friend CM, Bell DC, Biener J.

ACS Appl Mater Interfaces. 2017 Aug 2;9(30):25615-25622. doi: 10.1021/acsami.7b05648. Epub 2017 Jul 19.

PMID:
28693326
12.

Dynamic restructuring drives catalytic activity on nanoporous gold-silver alloy catalysts.

Zugic B, Wang L, Heine C, Zakharov DN, Lechner BAJ, Stach EA, Biener J, Salmeron M, Madix RJ, Friend CM.

Nat Mater. 2017 May;16(5):558-564. doi: 10.1038/nmat4824. Epub 2016 Dec 19.

PMID:
27992418
13.

Noncovalent Bonding Controls Selectivity in Heterogeneous Catalysis: Coupling Reactions on Gold.

Karakalos S, Xu Y, Cheenicode Kabeer F, Chen W, Rodríguez-Reyes JC, Tkatchenko A, Kaxiras E, Madix RJ, Friend CM.

J Am Chem Soc. 2016 Nov 23;138(46):15243-15250. Epub 2016 Nov 11.

PMID:
27775885
14.

Self-assembly of acetate adsorbates drives atomic rearrangement on the Au(110) surface.

Hiebel F, Shong B, Chen W, Madix RJ, Kaxiras E, Friend CM.

Nat Commun. 2016 Oct 12;7:13139. doi: 10.1038/ncomms13139.

15.

Controlling O coverage and stability by alloying Au and Ag.

Montemore MM, Cubuk ED, Klobas JE, Schmid M, Madix RJ, Friend CM, Kaxiras E.

Phys Chem Chem Phys. 2016 Sep 29;18(38):26844-26853.

PMID:
27722678
16.

Active site densities, oxygen activation and adsorbed reactive oxygen in alcohol activation on npAu catalysts.

Wang LC, Friend CM, Fushimi R, Madix RJ.

Faraday Discuss. 2016 Jul 4;188:57-67. doi: 10.1039/c5fd00161g.

PMID:
27376884
17.

Designing for selectivity: weak interactions and the competition for reactive sites on gold catalysts.

Siler CG, Madix RJ, Friend CM.

Faraday Discuss. 2016 Jul 4;188:355-68. doi: 10.1039/c5fd00192g.

PMID:
27181023
18.

Catalyst design for enhanced sustainability through fundamental surface chemistry.

Personick ML, Montemore MM, Kaxiras E, Madix RJ, Biener J, Friend CM.

Philos Trans A Math Phys Eng Sci. 2016 Feb 28;374(2061). pii: 20150077. doi: 10.1098/rsta.2015.0077. Review.

19.

Achieving Selective and Efficient Electrocatalytic Activity for CO2 Reduction Using Immobilized Silver Nanoparticles.

Kim C, Jeon HS, Eom T, Jee MS, Kim H, Friend CM, Min BK, Hwang YJ.

J Am Chem Soc. 2015 Nov 4;137(43):13844-50. doi: 10.1021/jacs.5b06568. Epub 2015 Oct 20.

PMID:
26447349
20.

Anatomy of the Photochemical Reaction: Excited-State Dynamics Reveals the C-H Acidity Mechanism of Methoxy Photo-oxidation on Titania.

Kolesov G, Vinichenko D, Tritsaris GA, Friend CM, Kaxiras E.

J Phys Chem Lett. 2015 May 7;6(9):1624-7. doi: 10.1021/acs.jpclett.5b00429. Epub 2015 Apr 15.

PMID:
26263325
21.

Van der Waals interactions determine selectivity in catalysis by metallic gold.

Rodriguez-Reyes JC, Siler CG, Liu W, Tkatchenko A, Friend CM, Madix RJ.

J Am Chem Soc. 2014 Sep 24;136(38):13333-40. doi: 10.1021/ja506447y. Epub 2014 Sep 16.

PMID:
25170677
22.

Perspectives on heterogeneous photochemistry.

Friend CM.

Chem Rec. 2014 Oct;14(5):944-51. doi: 10.1002/tcr.201402037. Epub 2014 Aug 18.

PMID:
25131154
23.

Defects in surface chemistry--reductive coupling of benzaldehyde on rutile TiO₂(110).

Clawin PM, Friend CM, Al-Shamery K.

Chemistry. 2014 Jun 16;20(25):7665-9. doi: 10.1002/chem.201402102. Epub 2014 May 13.

PMID:
24825761
24.

Tuning the Stability of Surface Intermediates Using Adsorbed Oxygen: Acetate on Au(111).

Cremer T, Siler CG, Rodríguez-Reyes JC, Friend CM, Madix RJ.

J Phys Chem Lett. 2014 Apr 3;5(7):1126-30. doi: 10.1021/jz500192k. Epub 2014 Mar 18.

PMID:
26274459
25.

Gold catalysis.

Friend CM, Hashmi AS.

Acc Chem Res. 2014 Mar 18;47(3):729-30. doi: 10.1021/ar5000506. No abstract available.

PMID:
24635456
26.

Ag/Au mixed sites promote oxidative coupling of methanol on the alloy surface.

Xu B, Siler CG, Madix RJ, Friend CM.

Chemistry. 2014 Apr 14;20(16):4646-52. doi: 10.1002/chem.201304837. Epub 2014 Mar 13.

PMID:
24633724
27.

Predicting gold-mediated catalytic oxidative-coupling reactions from single crystal studies.

Xu B, Madix RJ, Friend CM.

Acc Chem Res. 2014 Mar 18;47(3):761-72. doi: 10.1021/ar4002476. Epub 2014 Jan 3.

PMID:
24387694
28.

Norrish Type I surface photochemistry for butyrophenone on TiO2(110).

Jensen SC, Phillips KR, Baron M, Landis EC, Friend CM.

Phys Chem Chem Phys. 2013 Apr 14;15(14):5193-201. doi: 10.1039/c3cp44602f.

PMID:
23455572
29.

Alkyl groups as synthetic vehicles in gold-mediated oxidative coupling reactions.

Xu B, Madix RJ, Friend CM.

Phys Chem Chem Phys. 2013 Mar 7;15(9):3179-85. doi: 10.1039/c3cp43956a. Epub 2013 Jan 22.

PMID:
23340817
30.

Sequential photo-oxidation of methanol to methyl formate on TiO2(110).

Phillips KR, Jensen SC, Baron M, Li SC, Friend CM.

J Am Chem Soc. 2013 Jan 16;135(2):574-7. doi: 10.1021/ja3106797. Epub 2013 Jan 2.

PMID:
23268565
31.

Role of surface-bound intermediates in the oxygen-assisted synthesis of amides by metallic silver and gold.

Siler CG, Xu B, Madix RJ, Friend CM.

J Am Chem Soc. 2012 Aug 1;134(30):12604-10. doi: 10.1021/ja303178z. Epub 2012 Jul 19.

PMID:
22770474
32.

Butyrophenone on O-TiO2(110): one-dimensional motion in a weakly confined potential well.

Jensen SC, Shank A, Madix RJ, Friend CM.

ACS Nano. 2012 Apr 24;6(4):2925-30. doi: 10.1021/nn300949q. Epub 2012 Apr 2.

PMID:
22452747
33.

Dual-function of alcohols in gold-mediated selective coupling of amines and alcohols.

Xu B, Madix RJ, Friend CM.

Chemistry. 2012 Feb 20;18(8):2313-8. doi: 10.1002/chem.201103232. Epub 2012 Jan 17.

PMID:
22253014
34.

Oxygen-mediated coupling of alcohols over nanoporous gold catalysts at ambient pressures.

Kosuda KM, Wittstock A, Friend CM, Bäumer M.

Angew Chem Int Ed Engl. 2012 Feb 13;51(7):1698-701. doi: 10.1002/anie.201107178. Epub 2012 Jan 3. No abstract available.

PMID:
22223430
35.

Interfacial chemistry: gold's enigmatic surface.

Madix RJ, Friend CM.

Nature. 2011 Nov 23;479(7374):482-3. doi: 10.1038/479482a. No abstract available.

PMID:
22113688
36.

Activated metallic gold as an agent for direct methoxycarbonylation.

Xu B, Madix RJ, Friend CM.

J Am Chem Soc. 2011 Dec 21;133(50):20378-83. doi: 10.1021/ja207389z. Epub 2011 Nov 22.

PMID:
22035206
37.

Carbonyl coupling: defects and O2 make or break the essential reaction intermediate on titanium dioxide.

Jensen SC, Haubrich J, Shank A, Friend CM.

Chemistry. 2011 Jul 18;17(30):8309-12. doi: 10.1002/chem.201101094. Epub 2011 Jun 8. No abstract available.

PMID:
21656865
38.

The role of surface and subsurface point defects for chemical model studies on TiO2: a first-principles theoretical study of formaldehyde bonding on rutile TiO2(110).

Haubrich J, Kaxiras E, Friend CM.

Chemistry. 2011 Apr 11;17(16):4496-506. doi: 10.1002/chem.201002588. Epub 2011 Mar 23.

PMID:
21433119
39.

Molecular imaging of reductive coupling reactions: interstitial-mediated coupling of benzaldehyde on reduced TiO2(110).

Benz L, Haubrich J, Jensen SC, Friend CM.

ACS Nano. 2011 Feb 22;5(2):834-43. doi: 10.1021/nn103144u. Epub 2011 Jan 13.

PMID:
21229961
40.

Oxidative coupling of alcohols on gold: insights from experiments and theory.

Xu B, Friend CM.

Faraday Discuss. 2011;152:307-20; discussion 393-413.

PMID:
22455052
41.
42.

Vapour-phase gold-surface-mediated coupling of aldehydes with methanol.

Xu B, Liu X, Haubrich J, Friend CM.

Nat Chem. 2010 Jan;2(1):61-5. doi: 10.1038/nchem.467. Epub 2009 Nov 29.

PMID:
21124382
43.

The mystery of gold's chemical activity: local bonding, morphology and reactivity of atomic oxygen.

Baker TA, Liu X, Friend CM.

Phys Chem Chem Phys. 2011 Jan 7;13(1):34-46. doi: 10.1039/c0cp01514h. Epub 2010 Nov 22.

PMID:
21103516
44.

Achieving optimum selectivity in oxygen assisted alcohol cross-coupling on gold.

Xu B, Madix RJ, Friend CM.

J Am Chem Soc. 2010 Nov 24;132(46):16571-80. doi: 10.1021/ja106706v. Epub 2010 Oct 26.

PMID:
20977212
45.

Selective oxidation of cyclohexanol and 2-cyclohexen-1-ol on O/Au(111): the effect of molecular structure.

Liu X, Friend CM.

Langmuir. 2010 Nov 2;26(21):16552-7. doi: 10.1021/la1015302.

PMID:
20973586
46.

Effect of molecular structure on epoxidation of allylic olefins by atomic oxygen on Au.

Liu X, Baker TA, Friend CM.

Dalton Trans. 2010 Sep 28;39(36):8521-6. doi: 10.1039/c0dt00047g. Epub 2010 May 29.

PMID:
20512193
47.

Direct selective oxygen-assisted acylation of amines driven by metallic silver surfaces: dimethylamine with formaldehyde.

Zhou L, Freyschlag CG, Xu B, Friend CM, Madix RJ.

Chem Commun (Camb). 2010 Feb 7;46(5):704-6. doi: 10.1039/b921066k. Epub 2009 Dec 21.

PMID:
20087493
48.

Nanoporous gold catalysts for selective gas-phase oxidative coupling of methanol at low temperature.

Wittstock A, Zielasek V, Biener J, Friend CM, Bäumer M.

Science. 2010 Jan 15;327(5963):319-22. doi: 10.1126/science.1183591.

49.

In situ ambient pressure studies of the chemistry of NO2 and water on rutile TiO2(110).

Haubrich J, Quiller RG, Benz L, Liu Z, Friend CM.

Langmuir. 2010 Feb 16;26(4):2445-51. doi: 10.1021/la904141k.

PMID:
20070108
50.

Local Bonding Effects in the Oxidation of CO on Oxygen-Covered Au(111) from Ab Initio Molecular Dynamics Simulations.

Baker TA, Friend CM, Kaxiras E.

J Chem Theory Comput. 2010 Jan 12;6(1):279-87. doi: 10.1021/ct9004596. Epub 2009 Dec 3.

PMID:
26614338

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