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Items: 49

1.

Structural insight into metallocofactor maturation in carbon monoxide dehydrogenase.

Wittenborn EC, Cohen SE, Merrouch M, Léger C, Fourmond V, Dementin S, Drennan CL.

J Biol Chem. 2019 Jul 11. pii: jbc.RA119.009610. doi: 10.1074/jbc.RA119.009610. [Epub ahead of print]

PMID:
31296570
Free Article
2.

Understanding and Design of Bidirectional and Reversible Catalysts of Multielectron, Multistep Reactions.

Fourmond V, Wiedner ES, Shaw WJ, Léger C.

J Am Chem Soc. 2019 Jul 17;141(28):11269-11285. doi: 10.1021/jacs.9b04854. Epub 2019 Jul 8.

PMID:
31283209
3.

A new electrochemical cell with a uniformly accessible electrode to study fast catalytic reactions.

Fadel M, Daurelle JV, Fourmond V, Vicente J.

Phys Chem Chem Phys. 2019 Jun 21;21(23):12360-12371. doi: 10.1039/c9cp01487j. Epub 2019 May 29.

PMID:
31140495
4.

Tuning the redox properties of a [4Fe-4S] center to modulate the activity of Mo-bisPGD periplasmic nitrate reductase.

Zeamari K, Gerbaud G, Grosse S, Fourmond V, Chaspoul F, Biaso F, Arnoux P, Sabaty M, Pignol D, Guigliarelli B, Burlat B.

Biochim Biophys Acta Bioenerg. 2019 May 1;1860(5):402-413. doi: 10.1016/j.bbabio.2019.01.003. Epub 2019 Jan 29.

PMID:
30707885
5.

Redox-dependent rearrangements of the NiFeS cluster of carbon monoxide dehydrogenase.

Wittenborn EC, Merrouch M, Ueda C, Fradale L, Léger C, Fourmond V, Pandelia ME, Dementin S, Drennan CL.

Elife. 2018 Oct 2;7. pii: e39451. doi: 10.7554/eLife.39451.

6.

Correction to: Maturation of the [Ni-4Fe-4S] active site of carbon monoxide dehydrogenases.

Merrouch M, Benvenuti M, Lorenzi M, Léger C, Fourmond V, Dementin S.

J Biol Inorg Chem. 2018 Jun;23(4):621. doi: 10.1007/s00775-018-1565-5.

7.

Engineering an [FeFe]-Hydrogenase: Do Accessory Clusters Influence O2 Resistance and Catalytic Bias?

Caserta G, Papini C, Adamska-Venkatesh A, Pecqueur L, Sommer C, Reijerse E, Lubitz W, Gauquelin C, Meynial-Salles I, Pramanik D, Artero V, Atta M, Del Barrio M, Faivre B, Fourmond V, Léger C, Fontecave M.

J Am Chem Soc. 2018 Apr 25;140(16):5516-5526. doi: 10.1021/jacs.8b01689. Epub 2018 Apr 17.

PMID:
29595965
8.

Interaction of the H-Cluster of FeFe Hydrogenase with Halides.

Del Barrio M, Sensi M, Fradale L, Bruschi M, Greco C, de Gioia L, Bertini L, Fourmond V, Léger C.

J Am Chem Soc. 2018 Apr 25;140(16):5485-5492. doi: 10.1021/jacs.8b01414. Epub 2018 Apr 12.

PMID:
29590528
9.

Electrochemical Investigations of Hydrogenases and Other Enzymes That Produce and Use Solar Fuels.

Del Barrio M, Sensi M, Orain C, Baffert C, Dementin S, Fourmond V, Léger C.

Acc Chem Res. 2018 Mar 20;51(3):769-777. doi: 10.1021/acs.accounts.7b00622. Epub 2018 Mar 8. Review.

PMID:
29517230
10.

Maturation of the [Ni-4Fe-4S] active site of carbon monoxide dehydrogenases.

Merrouch M, Benvenuti M, Lorenzi M, Léger C, Fourmond V, Dementin S.

J Biol Inorg Chem. 2018 Jun;23(4):613-620. doi: 10.1007/s00775-018-1541-0. Epub 2018 Feb 14. Review. Erratum in: J Biol Inorg Chem. 2018 May 29;:.

11.

CODH-IV: A High-Efficiency CO-Scavenging CO Dehydrogenase with Resistance to O2.

Domnik L, Merrouch M, Goetzl S, Jeoung JH, Léger C, Dementin S, Fourmond V, Dobbek H.

Angew Chem Int Ed Engl. 2017 Nov 27;56(48):15466-15469. doi: 10.1002/anie.201709261. Epub 2017 Nov 2.

PMID:
29024326
12.

Roles of the F-domain in [FeFe] hydrogenase.

Gauquelin C, Baffert C, Richaud P, Kamionka E, Etienne E, Guieysse D, Girbal L, Fourmond V, André I, Guigliarelli B, Léger C, Soucaille P, Meynial-Salles I.

Biochim Biophys Acta Bioenerg. 2018 Feb;1859(2):69-77. doi: 10.1016/j.bbabio.2017.08.010. Epub 2017 Aug 24.

13.

Transient Catalytic Voltammetry of Sulfite Oxidase Reveals Rate Limiting Conformational Changes.

Zeng T, Leimkühler S, Wollenberger U, Fourmond V.

J Am Chem Soc. 2017 Aug 23;139(33):11559-11567. doi: 10.1021/jacs.7b05480. Epub 2017 Aug 8.

PMID:
28727916
14.

Dinitrogen Reduction: Interfacing the Enzyme Nitrogenase with Electrodes.

Fourmond V, Léger C.

Angew Chem Int Ed Engl. 2017 Apr 10;56(16):4388-4390. doi: 10.1002/anie.201701179. Epub 2017 Mar 16.

PMID:
28300341
15.

Mechanism of O2 diffusion and reduction in FeFe hydrogenases.

Kubas A, Orain C, De Sancho D, Saujet L, Sensi M, Gauquelin C, Meynial-Salles I, Soucaille P, Bottin H, Baffert C, Fourmond V, Best RB, Blumberger J, Léger C.

Nat Chem. 2017 Jan;9(1):88-95. doi: 10.1038/nchem.2592. Epub 2016 Aug 22.

16.

Redox Behavior of the S-Adenosylmethionine (SAM)-Binding Fe-S Cluster in Methylthiotransferase RimO, toward Understanding Dual SAM Activity.

Molle T, Moreau Y, Clemancey M, Forouhar F, Ravanat JL, Duraffourg N, Fourmond V, Latour JM, Gambarelli S, Mulliez E, Atta M.

Biochemistry. 2016 Oct 18;55(41):5798-5808. doi: 10.1021/acs.biochem.6b00597. Epub 2016 Oct 6.

PMID:
27677419
17.

Reactivity of the Excited States of the H-Cluster of FeFe Hydrogenases.

Sensi M, Baffert C, Greco C, Caserta G, Gauquelin C, Saujet L, Fontecave M, Roy S, Artero V, Soucaille P, Meynial-Salles I, Bottin H, de Gioia L, Fourmond V, Léger C, Bertini L.

J Am Chem Soc. 2016 Oct 19;138(41):13612-13618. doi: 10.1021/jacs.6b06603. Epub 2016 Oct 6.

PMID:
27649394
18.

Protein Electrochemistry: Questions and Answers.

Fourmond V, Léger C.

Adv Biochem Eng Biotechnol. 2016;158:1-41. doi: 10.1007/10_2015_5016. Review.

PMID:
27629379
19.

QSoas: A Versatile Software for Data Analysis.

Fourmond V.

Anal Chem. 2016 May 17;88(10):5050-2. doi: 10.1021/acs.analchem.6b00224. Epub 2016 May 3.

PMID:
27096413
20.

O2 Inhibition of Ni-Containing CO Dehydrogenase Is Partly Reversible.

Merrouch M, Hadj-Saïd J, Domnik L, Dobbek H, Léger C, Dementin S, Fourmond V.

Chemistry. 2015 Dec 21;21(52):18934-8. doi: 10.1002/chem.201502835. Epub 2015 Nov 16.

PMID:
26568460
21.

Electrochemical Measurements of the Kinetics of Inhibition of Two FeFe Hydrogenases by O2 Demonstrate That the Reaction Is Partly Reversible.

Orain C, Saujet L, Gauquelin C, Soucaille P, Meynial-Salles I, Baffert C, Fourmond V, Bottin H, Léger C.

J Am Chem Soc. 2015 Oct 7;137(39):12580-7. doi: 10.1021/jacs.5b06934. Epub 2015 Sep 25.

PMID:
26352172
22.

Oxidative inactivation of NiFeSe hydrogenase.

Ceccaldi P, Marques MC, Fourmond V, Pereira IC, Léger C.

Chem Commun (Camb). 2015 Sep 28;51(75):14223-6. doi: 10.1039/c5cc05930e. Epub 2015 Aug 11.

PMID:
26260963
23.

The Carbon Monoxide Dehydrogenase from Desulfovibrio vulgaris.

Hadj-Saïd J, Pandelia ME, Léger C, Fourmond V, Dementin S.

Biochim Biophys Acta. 2015 Dec;1847(12):1574-83. doi: 10.1016/j.bbabio.2015.08.002. Epub 2015 Aug 6.

24.

Reductive activation of E. coli respiratory nitrate reductase.

Ceccaldi P, Rendon J, Léger C, Toci R, Guigliarelli B, Magalon A, Grimaldi S, Fourmond V.

Biochim Biophys Acta. 2015 Oct;1847(10):1055-63. doi: 10.1016/j.bbabio.2015.06.007. Epub 2015 Jun 11.

25.

Mechanism of protection of catalysts supported in redox hydrogel films.

Fourmond V, Stapf S, Li H, Buesen D, Birrell J, Rüdiger O, Lubitz W, Schuhmann W, Plumeré N, Léger C.

J Am Chem Soc. 2015 Apr 29;137(16):5494-505. doi: 10.1021/jacs.5b01194. Epub 2015 Apr 17.

PMID:
25835569
26.

Correction to h2 evolution and molecular electrocatalysts: determination of overpotentials and effect of homoconjugation.

Fourmond V, Jacques PA, Fontecave M, Artero V.

Inorg Chem. 2015 Jan 20;54(2):704. doi: 10.1021/ic502988x. Epub 2014 Dec 22. No abstract available.

PMID:
25531629
27.

Kinetics of substrate inhibition of periplasmic nitrate reductase.

Jacques JG, Burlat B, Arnoux P, Sabaty M, Guigliarelli B, Léger C, Pignol D, Fourmond V.

Biochim Biophys Acta. 2014 Oct;1837(10):1801-9. doi: 10.1016/j.bbabio.2014.05.357. Epub 2014 Jun 2.

28.

The oxidative inactivation of FeFe hydrogenase reveals the flexibility of the H-cluster.

Fourmond V, Greco C, Sybirna K, Baffert C, Wang PH, Ezanno P, Montefiori M, Bruschi M, Meynial-Salles I, Soucaille P, Blumberger J, Bottin H, De Gioia L, Léger C.

Nat Chem. 2014 Apr;6(4):336-42. doi: 10.1038/nchem.1892. Epub 2014 Mar 16.

PMID:
24651202
29.

Reductive activation in periplasmic nitrate reductase involves chemical modifications of the Mo-cofactor beyond the first coordination sphere of the metal ion.

Jacques JG, Fourmond V, Arnoux P, Sabaty M, Etienne E, Grosse S, Biaso F, Bertrand P, Pignol D, Léger C, Guigliarelli B, Burlat B.

Biochim Biophys Acta. 2014 Feb;1837(2):277-86. doi: 10.1016/j.bbabio.2013.10.013. Epub 2013 Nov 7.

30.

Does the environment around the H-cluster allow coordination of the pendant amine to the catalytic iron center in [FeFe] hydrogenases? Answers from theory.

Miyake T, Bruschi M, Cosentino U, Baffert C, Fourmond V, Léger C, Moro G, De Gioia L, Greco C.

J Biol Inorg Chem. 2013 Aug;18(6):693-700. doi: 10.1007/s00775-013-1014-4. Epub 2013 Jun 23.

PMID:
23793236
31.

The mechanism of inhibition by H2 of H2-evolution by hydrogenases.

Fourmond V, Baffert C, Sybirna K, Dementin S, Abou-Hamdan A, Meynial-Salles I, Soucaille P, Bottin H, Léger C.

Chem Commun (Camb). 2013 Aug 7;49(61):6840-2. doi: 10.1039/c3cc43297a. Epub 2013 Jun 24.

PMID:
23792933
32.

Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.

Canaguier S, Fourmond V, Perotto CU, Fize J, Pécaut J, Fontecave M, Field MJ, Artero V.

Chem Commun (Camb). 2013 Jun 4;49(44):5004-6. doi: 10.1039/c3cc40987b. Epub 2013 Apr 23.

PMID:
23612503
33.

A cyclic peptide-based redox-active model of rubredoxin.

Jacques A, Clémancey M, Blondin G, Fourmond V, Latour JM, Sénèque O.

Chem Commun (Camb). 2013 Apr 11;49(28):2915-7. doi: 10.1039/c3cc40517f.

PMID:
23459993
34.

Steady-state catalytic wave-shapes for 2-electron reversible electrocatalysts and enzymes.

Fourmond V, Baffert C, Sybirna K, Lautier T, Abou Hamdan A, Dementin S, Soucaille P, Meynial-Salles I, Bottin H, Léger C.

J Am Chem Soc. 2013 Mar 13;135(10):3926-38. doi: 10.1021/ja311607s. Epub 2013 Mar 1.

PMID:
23362993
35.

Relation between anaerobic inactivation and oxygen tolerance in a large series of NiFe hydrogenase mutants.

Abou Hamdan A, Liebgott PP, Fourmond V, Gutiérrez-Sanz O, De Lacey AL, Infossi P, Rousset M, Dementin S, Léger C.

Proc Natl Acad Sci U S A. 2012 Dec 4;109(49):19916-21. doi: 10.1073/pnas.1212258109. Epub 2012 Nov 19.

36.

A Janus cobalt-based catalytic material for electro-splitting of water.

Cobo S, Heidkamp J, Jacques PA, Fize J, Fourmond V, Guetaz L, Jousselme B, Ivanova V, Dau H, Palacin S, Fontecave M, Artero V.

Nat Mater. 2012 Sep;11(9):802-7. doi: 10.1038/nmat3385. Epub 2012 Aug 5.

PMID:
22863815
37.

Rates of intra- and intermolecular electron transfers in hydrogenase deduced from steady-state activity measurements.

Dementin S, Burlat B, Fourmond V, Leroux F, Liebgott PP, Abou Hamdan A, Léger C, Rousset M, Guigliarelli B, Bertrand P.

J Am Chem Soc. 2011 Jul 6;133(26):10211-21. doi: 10.1021/ja202615a. Epub 2011 Jun 14.

PMID:
21615141
38.

The quest for a functional substrate access tunnel in FeFe hydrogenase.

Lautier T, Ezanno P, Baffert C, Fourmond V, Cournac L, Fontecilla-Camps JC, Soucaille P, Bertrand P, Meynial-Salles I, Léger C.

Faraday Discuss. 2011;148:385-407; discussion 421-41.

PMID:
21322495
39.

H2 evolution and molecular electrocatalysts: determination of overpotentials and effect of homoconjugation.

Fourmond V, Jacques PA, Fontecave M, Artero V.

Inorg Chem. 2010 Nov 15;49(22):10338-47. doi: 10.1021/ic101187v. Epub 2010 Oct 21. Erratum in: Inorg Chem. 2015 Jan 20;54(2):704. Inorg Chem. 2015 Jan 20;54(2):704.

PMID:
20964310
40.

Membrane-bound hydrogenase I from the hyperthermophilic bacterium Aquifex aeolicus: enzyme activation, redox intermediates and oxygen tolerance.

Pandelia ME, Fourmond V, Tron-Infossi P, Lojou E, Bertrand P, Léger C, Giudici-Orticoni MT, Lubitz W.

J Am Chem Soc. 2010 May 26;132(20):6991-7004. doi: 10.1021/ja910838d.

PMID:
20441192
41.

"Two-step" chronoamperometric method for studying the anaerobic inactivation of an oxygen tolerant NiFe hydrogenase.

Fourmond V, Infossi P, Giudici-Orticoni MT, Bertrand P, Léger C.

J Am Chem Soc. 2010 Apr 7;132(13):4848-57. doi: 10.1021/ja910685j.

PMID:
20230028
42.

Reassessing the strategies for trapping catalytic intermediates during nitrate reductase turnover.

Fourmond V, Sabaty M, Arnoux P, Bertrand P, Pignol D, Léger C.

J Phys Chem B. 2010 Mar 11;114(9):3341-7. doi: 10.1021/jp911443y.

PMID:
20163092
43.

Dependence of catalytic activity on driving force in solution assays and protein film voltammetry: insights from the comparison of nitrate reductase mutants.

Fourmond V, Burlat B, Dementin S, Sabaty M, Arnoux P, Etienne E, Guigliarelli B, Bertrand P, Pignol D, Léger C.

Biochemistry. 2010 Mar 23;49(11):2424-32. doi: 10.1021/bi902140e.

PMID:
20146468
44.

Relating diffusion along the substrate tunnel and oxygen sensitivity in hydrogenase.

Liebgott PP, Leroux F, Burlat B, Dementin S, Baffert C, Lautier T, Fourmond V, Ceccaldi P, Cavazza C, Meynial-Salles I, Soucaille P, Fontecilla-Camps JC, Guigliarelli B, Bertrand P, Rousset M, Léger C.

Nat Chem Biol. 2010 Jan;6(1):63-70. doi: 10.1038/nchembio.276. Epub 2009 Dec 6.

PMID:
19966788
45.

SOAS: a free program to analyze electrochemical data and other one-dimensional signals.

Fourmond V, Hoke K, Heering HA, Baffert C, Leroux F, Bertrand P, Léger C.

Bioelectrochemistry. 2009 Sep;76(1-2):141-7. doi: 10.1016/j.bioelechem.2009.02.010. Epub 2009 Mar 9.

PMID:
19328046
46.

Correcting for electrocatalyst desorption and inactivation in chronoamperometry experiments.

Fourmond V, Lautier T, Baffert C, Leroux F, Liebgott PP, Dementin S, Rousset M, Arnoux P, Pignol D, Meynial-Salles I, Soucaille P, Bertrand P, Léger C.

Anal Chem. 2009 Apr 15;81(8):2962-8. doi: 10.1021/ac8025702.

PMID:
19298055
47.

Major Mo(V) EPR signature of Rhodobacter sphaeroides periplasmic nitrate reductase arising from a dead-end species that activates upon reduction. Relation to other molybdoenzymes from the DMSO reductase family.

Fourmond V, Burlat B, Dementin S, Arnoux P, Sabaty M, Boiry S, Guigliarelli B, Bertrand P, Pignol D, Léger C.

J Phys Chem B. 2008 Dec 4;112(48):15478-86. doi: 10.1021/jp807092y.

PMID:
19006273
48.

Shewanella oneidensis: a new and efficient system for expression and maturation of heterologous [Fe-Fe] hydrogenase from Chlamydomonas reinhardtii.

Sybirna K, Antoine T, Lindberg P, Fourmond V, Rousset M, Méjean V, Bottin H.

BMC Biotechnol. 2008 Sep 18;8:73. doi: 10.1186/1472-6750-8-73.

49.

Electrochemical study of a reconstituted photosynthetic electron-transfer chain.

Fourmond V, Lagoutte B, Sétif P, Leibl W, Demaille C.

J Am Chem Soc. 2007 Jul 25;129(29):9201-9. Epub 2007 Jun 28.

PMID:
17602558

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