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Items: 1 to 50 of 64

1.

Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers.

Babón JC, Esteruelas MA, Fernández I, López AM, Oñate E.

Inorg Chem. 2019 Jul 1;58(13):8673-8684. doi: 10.1021/acs.inorgchem.9b01013. Epub 2019 Jun 19.

PMID:
31247858
2.

Ruthenium-Catalyzed Oxidative Amidation of Alkynes to Amides.

Álvarez-Pérez A, Esteruelas MA, Izquierdo S, Varela JA, Saá C.

Org Lett. 2019 Jul 5;21(13):5346-5350. doi: 10.1021/acs.orglett.9b01993. Epub 2019 Jun 24.

PMID:
31247753
3.

Iridium-Promoted B-B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer-Tris(boryl) Complex.

Esteruelas MA, Fernández I, Martínez A, Oliván M, Oñate E, Vélez A.

Inorg Chem. 2019 Apr 15;58(8):4712-4717. doi: 10.1021/acs.inorgchem.9b00339. Epub 2019 Mar 27.

PMID:
30916951
4.

Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity.

Esteruelas MA, Fernández I, García-Yebra C, Martín J, Oñate E.

Inorg Chem. 2019 Feb 18;58(4):2265-2269. doi: 10.1021/acs.inorgchem.8b03366. Epub 2019 Jan 30.

PMID:
30698418
5.

Preparation of Tris-Heteroleptic Iridium(III) Complexes Containing a Cyclometalated Aryl-N-Heterocyclic Carbene Ligand.

Adamovich V, Bajo S, Boudreault PT, Esteruelas MA, López AM, Martín J, Oliván M, Oñate E, Palacios AU, San-Torcuato A, Tsai JY, Xia C.

Inorg Chem. 2018 Sep 4;57(17):10744-10760. doi: 10.1021/acs.inorgchem.8b01367. Epub 2018 Aug 23.

PMID:
30137969
6.

Evidence for a Bis(Elongated σ)-Dihydrideborate Coordinated to Osmium.

Babón JC, Esteruelas MA, Fernández I, López AM, Oñate E.

Inorg Chem. 2018 Apr 16;57(8):4482-4491. doi: 10.1021/acs.inorgchem.8b00155. Epub 2018 Apr 2.

PMID:
29608302
7.

Preparation of Phosphorescent Iridium(III) Complexes with a Dianionic C,C,C,C-Tetradentate Ligand.

Esteruelas MA, López AM, Oñate E, San-Torcuato A, Tsai JY, Xia C.

Inorg Chem. 2018 Apr 2;57(7):3720-3730. doi: 10.1021/acs.inorgchem.7b02993. Epub 2018 Mar 14.

PMID:
29537827
8.

η1 -Arene Complexes as Intermediates in the Preparation of Molecular Phosphorescent Iridium(III) Complexes.

Esteruelas MA, Gómez-Bautista D, López AM, Oñate E, Tsai JY, Xia C.

Chemistry. 2017 Nov 7;23(62):15729-15737. doi: 10.1002/chem.201703252. Epub 2017 Oct 16.

PMID:
28898480
9.

Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes.

Eguillor B, Esteruelas MA, Lezáun V, Oliván M, Oñate E.

Chemistry. 2017 Jan 31;23(7):1526-1530. doi: 10.1002/chem.201605843. Epub 2017 Jan 12.

PMID:
27991701
10.

mer, fac, and Bidentate Coordination of an Alkyl-POP Ligand in the Chemistry of Nonclassical Osmium Hydrides.

Esteruelas MA, García-Yebra C, Martín J, Oñate E.

Inorg Chem. 2017 Jan 3;56(1):676-683. doi: 10.1021/acs.inorgchem.6b02837. Epub 2016 Dec 13.

PMID:
27957852
11.

Aromatic Osmacyclopropenefuran Bicycles and Their Relevance for the Metal-Mediated Hydration of Functionalized Allenes.

Batuecas M, Castro-Rodrigo R, Esteruelas MA, García-Yebra C, López AM, Oñate E.

Angew Chem Int Ed Engl. 2016 Oct 24;55(44):13749-13753. doi: 10.1002/anie.201606839. Epub 2016 Oct 4.

PMID:
27701801
12.

Square-Planar Alkylidyne-Osmium and Five-Coordinate Alkylidene-Osmium Complexes: Controlling the Transformation from Hydride-Alkylidyne to Alkylidene.

Buil ML, Cardo JJ, Esteruelas MA, Oñate E.

J Am Chem Soc. 2016 Aug 3;138(30):9720-8. doi: 10.1021/jacs.6b05825. Epub 2016 Jul 21.

13.

Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst.

Esteruelas MA, Nolis P, Oliván M, Oñate E, Vallribera A, Vélez A.

Inorg Chem. 2016 Jul 18;55(14):7176-81. doi: 10.1021/acs.inorgchem.6b01216. Epub 2016 Jul 1.

PMID:
27367792
14.

Polyhydrides of Platinum Group Metals: Nonclassical Interactions and σ-Bond Activation Reactions.

Esteruelas MA, López AM, Oliván M.

Chem Rev. 2016 Aug 10;116(15):8770-847. doi: 10.1021/acs.chemrev.6b00080. Epub 2016 Jun 6.

15.

An Entry to Stable Mixed Phosphine-Osmium-NHC Polyhydrides.

Buil ML, Cardo JJ, Esteruelas MA, Fernández I, Oñate E.

Inorg Chem. 2016 May 16;55(10):5062-70. doi: 10.1021/acs.inorgchem.6b00658. Epub 2016 May 4.

PMID:
27145380
16.

A Capped Octahedral MHC6 Compound of a Platinum Group Metal.

Eguillor B, Esteruelas MA, Lezáun V, Oliván M, Oñate E, Tsai JY, Xia C.

Chemistry. 2016 Jun 27;22(27):9106-10. doi: 10.1002/chem.201601729. Epub 2016 Jun 2.

PMID:
27123555
17.

The effect of supplementation with three commercial inactive dry yeasts on the colour, phenolic compounds, polysaccharides and astringency of a model wine solution and red wine.

González-Royo E, Esteruelas M, Kontoudakis N, Fort F, Canals JM, Zamora F.

J Sci Food Agric. 2017 Jan;97(1):172-181. doi: 10.1002/jsfa.7706. Epub 2016 Apr 13.

PMID:
26970323
18.

Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes.

Casanova N, Esteruelas MA, Gulías M, Larramona C, Mascareñas JL, Oñate E.

Organometallics. 2016 Jan 25;35(2):91-99. Epub 2015 Dec 31.

19.

2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes.

Casarrubios L, Esteruelas MA, Larramona C, Muntaner JG, Oñate E, Sierra MA.

Inorg Chem. 2015 Nov 16;54(22):10998-1006. doi: 10.1021/acs.inorgchem.5b02138. Epub 2015 Oct 29.

PMID:
26512736
20.

Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance.

Casarrubios L, Esteruelas MA, Larramona C, Lledós A, Muntaner JG, Oñate E, Ortuño MA, Sierra MA.

Chemistry. 2015 Nov 16;21(47):16781-5. doi: 10.1002/chem.201503595. Epub 2015 Oct 6.

PMID:
26437692
21.

Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines.

Álvarez-Pérez A, González-Rodríguez C, García-Yebra C, Varela JA, Oñate E, Esteruelas MA, Saá C.

Angew Chem Int Ed Engl. 2015 Nov 2;54(45):13357-61. doi: 10.1002/anie.201505782. Epub 2015 Sep 14.

PMID:
26368394
22.

Conclusive evidence on the mechanism of the rhodium-mediated decyanative borylation.

Esteruelas MA, Oliván M, Vélez A.

J Am Chem Soc. 2015 Sep 30;137(38):12321-9. doi: 10.1021/jacs.5b07357. Epub 2015 Sep 15.

23.

Influence of grape maturity on the foaming properties of base wines and sparkling wines (Cava).

Esteruelas M, González-Royo E, Kontoudakis N, Orte A, Cantos A, Canals JM, Zamora F.

J Sci Food Agric. 2015 Aug 15;95(10):2071-80. doi: 10.1002/jsfa.6922. Epub 2014 Oct 21.

PMID:
25242464
24.

Dihydrobiphenylenes through ruthenium-catalyzed [2+2+2] cycloadditions of ortho-alkenylarylacetylenes with alkynes.

García-Rubín S, González-Rodríguez C, García-Yebra C, Varela JA, Esteruelas MA, Saá C.

Angew Chem Int Ed Engl. 2014 Feb 10;53(7):1841-4. doi: 10.1002/anie.201309496. Epub 2014 Jan 17.

PMID:
24442724
25.

POP-pincer ruthenium complexes: d(6) counterparts of osmium d(4) species.

Alós J, Bolaño T, Esteruelas MA, Oliván M, Oñate E, Valencia M.

Inorg Chem. 2014 Jan 21;53(2):1195-209. doi: 10.1021/ic402795g. Epub 2014 Jan 9.

PMID:
24405059
26.

POP-pincer silyl complexes of group 9: rhodium versus iridium.

Esteruelas MA, Oliván M, Vélez A.

Inorg Chem. 2013 Oct 21;52(20):12108-19. doi: 10.1021/ic401931y. Epub 2013 Oct 2.

PMID:
24088172
27.

B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond.

Esteruelas MA, López AM, Mora M, Oñate E.

Chem Commun (Camb). 2013 Sep 4;49(68):7543-5. doi: 10.1039/c3cc44102d.

PMID:
23873334
28.

Effect of two different treatments for reducing grape yield in Vitis vinifera cv Syrah on wine composition and quality: berry thinning versus cluster thinning.

Gil M, Esteruelas M, González E, Kontoudakis N, Jiménez J, Fort F, Canals JM, Hermosín-Gutiérrez I, Zamora F.

J Agric Food Chem. 2013 May 22;61(20):4968-78. doi: 10.1021/jf400722z. Epub 2013 May 13.

PMID:
23627566
29.

POP-pincer osmium-polyhydrides: head-to-head (Z)-dimerization of terminal alkynes.

Alós J, Bolaño T, Esteruelas MA, Oliván M, Oñate E, Valencia M.

Inorg Chem. 2013 May 20;52(10):6199-213. doi: 10.1021/ic400730a. Epub 2013 Apr 26.

PMID:
23621496
30.

Xantphos-type complexes of group 9: rhodium versus iridium.

Esteruelas MA, Oliván M, Vélez A.

Inorg Chem. 2013 May 6;52(9):5339-49. doi: 10.1021/ic4002658. Epub 2013 Apr 5.

PMID:
23560531
31.

Mono- and dinuclear osmium N,N'-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry.

Esteruelas MA, Fernández I, Gómez-Gallego M, Martín-Ortíz M, Molina P, Oliván M, Otón F, Sierra MA, Valencia M.

Dalton Trans. 2013 Mar 14;42(10):3597-608. doi: 10.1039/c2dt32548a. Epub 2013 Jan 4.

PMID:
23292252
32.

Reactions of an osmium-hexahydride complex with cytosine, deoxycytidine, and cytidine: the importance of the minor tautomers.

Esteruelas MA, García-Raboso J, Oliván M.

Inorg Chem. 2012 Sep 3;51(17):9522-8. doi: 10.1021/ic3013238. Epub 2012 Aug 16.

PMID:
22897627
33.

Influence of grape maturity and maceration length on color, polyphenolic composition, and polysaccharide content of Cabernet Sauvignon and Tempranillo wines.

Gil M, Kontoudakis N, González E, Esteruelas M, Fort F, Canals JM, Zamora F.

J Agric Food Chem. 2012 Aug 15;60(32):7988-8001. doi: 10.1021/jf302064n. Epub 2012 Aug 6.

PMID:
22823470
34.

N-h and N-C bond activation of pyrimidinic nucleobases and nucleosides promoted by an osmium polyhydride.

Esteruelas MA, García-Raboso J, Oliván M, Oñate E.

Inorg Chem. 2012 May 21;51(10):5975-84. doi: 10.1021/ic300639j. Epub 2012 May 9.

PMID:
22571542
35.

Synthesis and characterisation of [6]-azaosmahelicenes: the first d4-heterometallahelicenes.

Crespo O, Eguillor B, Esteruelas MA, Fernández I, García-Raboso J, Gómez-Gallego M, Martín-Ortiz M, Oliván M, Sierra MA.

Chem Commun (Camb). 2012 May 28;48(43):5328-30. doi: 10.1039/c2cc30356f. Epub 2012 Apr 20.

PMID:
22517029
36.

Dehydrative cyclization of alkynals: vinylidene complexes with the Cβ incorporated into unsaturated five- or six-membered rings.

Batuecas M, Escalante L, Esteruelas MA, García-Yebra C, Oñate E, Saá C.

Angew Chem Int Ed Engl. 2011 Oct 4;50(41):9712-5. doi: 10.1002/anie.201102969. Epub 2011 Aug 2. No abstract available.

PMID:
21812081
37.

Ruthenium-catalyzed (2 + 2) intramolecular cycloaddition of allenenes.

Gulías M, Collado A, Trillo B, López F, Oñate E, Esteruelas MA, Mascareñas JL.

J Am Chem Soc. 2011 May 25;133(20):7660-3. doi: 10.1021/ja200784n. Epub 2011 Apr 28.

PMID:
21526771
38.

Influence of wine pH on changes in color and polyphenol composition induced by micro-oxygenation.

Kontoudakis N, González E, Gil M, Esteruelas M, Fort F, Canals JM, Zamora F.

J Agric Food Chem. 2011 Mar 9;59(5):1974-84. doi: 10.1021/jf103038g. Epub 2011 Feb 11.

PMID:
21314122
39.

From tetrahydroborate- to aminoborylvinylidene-osmium complexes via alkynyl-aminoboryl intermediates.

Buil ML, Esteruelas MA, Garcés K, Oñate E.

J Am Chem Soc. 2011 Feb 23;133(7):2250-63. doi: 10.1021/ja109691v. Epub 2011 Jan 27.

PMID:
21271711
40.

Osmium(III) complexes with POP pincer ligands: preparation from commercially available OsCl(3)·3H(2)O and their X-ray structures.

Asensio G, Cuenca AB, Esteruelas MA, Medio-Simón M, Oliván M, Valencia M.

Inorg Chem. 2010 Oct 4;49(19):8665-7. doi: 10.1021/ic101498h.

PMID:
20828213
41.

Osmium-catalyzed 7-endo heterocyclization of aromatic alkynols into benzoxepines.

Varela-Fernández A, García-Yebra C, Varela JA, Esteruelas MA, Saá C.

Angew Chem Int Ed Engl. 2010 Jun 7;49(25):4278-81. doi: 10.1002/anie.201000455. No abstract available.

PMID:
20449862
42.

Borinium cations as sigma-B-H ligands in osmium complexes.

Esteruelas MA, Fernández-Alvarez FJ, López AM, Mora M, Oñate E.

J Am Chem Soc. 2010 Apr 28;132(16):5600-1. doi: 10.1021/ja101806x.

PMID:
20355735
43.

Comparison of methods for estimating phenolic maturity in grapes: correlation between predicted and obtained parameters.

Kontoudakis N, Esteruelas M, Fort F, Canals JM, Zamora F.

Anal Chim Acta. 2010 Feb 15;660(1-2):127-33. doi: 10.1016/j.aca.2009.10.067. Epub 2009 Nov 10.

PMID:
20103153
44.

Cleavage of both C(sp3)-C(sp2) bonds of alkylidenecyclopropanes: formation of ethylene-osmium-vinylidene complexes.

Castro-Rodrigo R, Esteruelas MA, López AM, López F, Mascareñas JL, Oliván M, Oñate E, Saya L, Villarino L.

J Am Chem Soc. 2010 Jan 20;132(2):454-5. doi: 10.1021/ja909240q.

PMID:
20017552
45.

Formation of osmium- and ruthenium-cyclobutylidene complexes by ring expansion of alkylidenecyclopropanes.

Castro-Rodrigo R, Esteruelas MA, Fuertes S, López AM, López F, Mascareñas JL, Mozo S, Oñate E, Saya L, Villarino L.

J Am Chem Soc. 2009 Nov 4;131(43):15572-3. doi: 10.1021/ja904893j.

PMID:
19817442
47.

Nazarov type cyclization on an osmium-dienylcarbene complex.

Bolaño T, Castarlenas R, Esteruelas MA, Oñate E.

J Am Chem Soc. 2009 Feb 18;131(6):2064-5. doi: 10.1021/ja8093058.

PMID:
19161302
48.

Aromatic diosmatricyclic nitrogen-containing compounds.

Esteruelas MA, Masamunt AB, Oliván M, Oñate E, Valencia M.

J Am Chem Soc. 2008 Sep 3;130(35):11612-3. doi: 10.1021/ja8048892. Epub 2008 Aug 12.

PMID:
18693727
49.

Understanding the formation of N-H tautomers from alpha-substituted pyridines: tautomerization of 2-ethylpyridine promoted by osmium.

Buil ML, Esteruelas MA, Garcés K, Oliván M, Oñate E.

J Am Chem Soc. 2007 Sep 12;129(36):10998-9. Epub 2007 Aug 16. No abstract available.

PMID:
17696542
50.

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