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Items: 1 to 50 of 223

1.

The Thermal Rearrangement of an NHC-Ligated 3-Benzoborepin to an NHC-Boranorcaradiene.

Shimoi M, Kevlishvili I, Watanabe T, Maeda K, Geib SJ, Curran DP, Liu P, Taniguchi T.

Angew Chem Int Ed Engl. 2019 Oct 31. doi: 10.1002/anie.201912234. [Epub ahead of print] Review.

PMID:
31670450
2.

Facile Synthesis of α-N-Heterocyclic Carbene-Boryl Ketones from N-Heterocyclic Carbene-Boranes and Alkenyl Triflates.

Dai W, Geib SJ, Curran DP.

J Am Chem Soc. 2019 Aug 7;141(31):12355-12361. doi: 10.1021/jacs.9b05547. Epub 2019 Jul 23.

PMID:
31294979
3.

Esters as Radical Acceptors: β-NHC-Borylalkenyl Radicals Induce Lactonization by C-C Bond Formation/Cleavage on Esters.

Shimoi M, Maeda K, Geib SJ, Curran DP, Taniguchi T.

Angew Chem Int Ed Engl. 2019 May 6;58(19):6357-6361. doi: 10.1002/anie.201902001. Epub 2019 Apr 4.

PMID:
30891902
4.

Ring-Opening Reactions of NHC-Boriranes with In Situ Generated HCl: Synthesis of a New Class of NHC-Boralactones.

Dai W, Geib SJ, Curran DP.

J Am Chem Soc. 2019 Feb 27;141(8):3623-3629. doi: 10.1021/jacs.8b13010. Epub 2019 Feb 15.

PMID:
30717598
5.

EPR and Preparative Studies of 5- endo Cyclizations of Radicals Derived from Alkenyl NHC-Boranes Bearing tert-Butyl Ester Substituents.

Dai W, Curran DP, Walton JC.

J Org Chem. 2019 Feb 15;84(4):2102-2111. doi: 10.1021/acs.joc.8b03112. Epub 2019 Feb 1.

PMID:
30663305
6.

5- Endo Cyclizations of NHC-Boraallyl Radicals Bearing Ester Substituents: Characterization of Derived 1,2-Oxaborole Radicals and Boralactones.

Dai W, McFadden TR, Curran DP, Früchtl HA, Walton JC.

J Am Chem Soc. 2018 Nov 21;140(46):15868-15875. doi: 10.1021/jacs.8b09288. Epub 2018 Nov 9.

PMID:
30369236
7.

Reactions of N-Heterocyclic Carbene Boranes with 5-Diazo-2,2-dimethyl-1,3-dioxane-4,6-dione: Synthesis of Mono- and Bis-hydrazonyl NHC-Boranes.

Dai W, Geib SJ, Curran DP.

J Org Chem. 2018 Aug 3;83(15):8775-8779. doi: 10.1021/acs.joc.8b01125. Epub 2018 Jul 24.

PMID:
30004702
8.

Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC-BF2. ).

Subervie D, Graff B, Nerkar S, Curran DP, Lalevée J, Lacôte E.

Angew Chem Int Ed Engl. 2018 Aug 6;57(32):10251-10256. doi: 10.1002/anie.201806476. Epub 2018 Jul 17.

PMID:
29928777
9.

Radical trans-Hydroboration of Alkynes with N-Heterocyclic Carbene Boranes.

Shimoi M, Watanabe T, Maeda K, Curran DP, Taniguchi T.

Angew Chem Int Ed Engl. 2018 Jul 20;57(30):9485-9490. doi: 10.1002/anie.201804515. Epub 2018 Jun 25.

PMID:
29845716
10.

Thiol-Catalyzed Radical Decyanation of Aliphatic Nitriles with Sodium Borohydride.

Kawamoto T, Oritani K, Curran DP, Kamimura A.

Org Lett. 2018 Apr 6;20(7):2084-2087. doi: 10.1021/acs.orglett.8b00626. Epub 2018 Mar 8.

PMID:
29517914
11.

Synthesis, Structure, and Acidity Constants of Ligated α-Boryl Acetic Acids.

Allen TH, Horner AR, Geib SJ, Weber SG, Curran DP.

Chemistry. 2018 Jan 19;24(4):822-825. doi: 10.1002/chem.201705754. Epub 2017 Dec 27.

PMID:
29207202
12.

N-Heterocyclic Carbene Boranes are Hydrogen Donors in Masamune-Bergman Reactions of Benzo[3,4]cyclodec-3-ene-1,5-diynes.

Watanabe T, Geib SJ, Curran DP, Taniguchi T.

J Org Chem. 2017 Dec 15;82(24):13034-13042. doi: 10.1021/acs.joc.7b01981. Epub 2017 Nov 21.

PMID:
29120175
13.

1-Butyl-3-methylimidazol-2-ylidene Borane: A Readily Available, Liquid N-Heterocyclic Carbene Borane Reagent.

Bolt DA, Curran DP.

J Org Chem. 2017 Dec 15;82(24):13746-13750. doi: 10.1021/acs.joc.7b02730. Epub 2017 Nov 21.

PMID:
29117477
14.

Generation and Structure of Unique Boriranyl Radicals.

Walton JC, McFadden TR, Curran DP.

J Am Chem Soc. 2017 Nov 22;139(46):16514-16517. doi: 10.1021/jacs.7b10788. Epub 2017 Nov 9.

PMID:
29099598
15.

N-Heterocyclic Carbene Boryl Iodides Catalyze Insertion Reactions of N-Heterocyclic Carbene Boranes and Diazoesters.

Allen TH, Kawamoto T, Gardner S, Geib SJ, Curran DP.

Org Lett. 2017 Jul 7;19(13):3680-3683. doi: 10.1021/acs.orglett.7b01777. Epub 2017 Jun 22.

PMID:
28641014
16.

Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes.

Watanabe T, Hirose D, Curran DP, Taniguchi T.

Chemistry. 2017 Apr 24;23(23):5404-5409. doi: 10.1002/chem.201700689. Epub 2017 Mar 27.

PMID:
28205265
17.

Synthesis of Boriranes by Double Hydroboration Reactions of N-Heterocyclic Carbene Boranes and Dimethyl Acetylenedicarboxylate.

McFadden TR, Fang C, Geib SJ, Merling E, Liu P, Curran DP.

J Am Chem Soc. 2017 Feb 8;139(5):1726-1729. doi: 10.1021/jacs.6b09873. Epub 2017 Jan 24.

PMID:
28106381
18.

Axially Chiral Enamides: Substituent Effects, Rotation Barriers, and Implications for their Cyclization Reactions.

Clark AJ, Curran DP, Fox DJ, Ghelfi F, Guy CS, Hay B, James N, Phillips JM, Roncaglia F, Sellars PB, Wilson P, Zhang H.

J Org Chem. 2016 Jul 1;81(13):5547-65. doi: 10.1021/acs.joc.6b00889. Epub 2016 Jun 21.

19.

Understanding Initiation with Triethylboron and Oxygen: The Differences between Low-Oxygen and High-Oxygen Regimes.

Curran DP, McFadden TR.

J Am Chem Soc. 2016 Jun 22;138(24):7741-52. doi: 10.1021/jacs.6b04014. Epub 2016 Jun 14.

PMID:
27243276
20.

Relative Reactivity of Stable Ligated Boranes and a Borohydride Salt in Rhodium(II)-Catalyzed Boron-Hydrogen Insertion Reactions.

Allen TH, Curran DP.

J Org Chem. 2016 Mar 4;81(5):2094-8. doi: 10.1021/acs.joc.6b00091. Epub 2016 Feb 23.

PMID:
26871613
21.

Fates of imine intermediates in radical cyclizations of N-sulfonylindoles and ene-sulfonamides.

Zhang H, Hay EB, Geib SJ, Curran DP.

Beilstein J Org Chem. 2015 Sep 17;11:1649-55. doi: 10.3762/bjoc.11.181. eCollection 2015.

22.

Catalysis of Radical Reactions: A Radical Chemistry Perspective.

Studer A, Curran DP.

Angew Chem Int Ed Engl. 2016 Jan 4;55(1):58-102. doi: 10.1002/anie.201505090. Epub 2015 Oct 13. Review.

PMID:
26459814
23.

Severe arthritis predicts greater improvements in function following total knee arthroplasty.

Stone OD, Duckworth AD, Curran DP, Ballantyne JA, Brenkel IJ.

Knee Surg Sports Traumatol Arthrosc. 2017 Aug;25(8):2573-2579. doi: 10.1007/s00167-015-3806-2. Epub 2015 Oct 6.

PMID:
26441252
24.

Synthesis of 1,3-Dialkylimidazol-2-ylidene Boranes from 1,3-Dialkylimidazolium Iodides and Sodium Borohydride.

Gardner S, Kawamoto T, Curran DP.

J Org Chem. 2015 Oct 2;80(19):9794-7. doi: 10.1021/acs.joc.5b01682. Epub 2015 Sep 30.

PMID:
26334670
25.

Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes.

Nerkar S, Curran DP.

Org Lett. 2015 Jul 17;17(14):3394-7. doi: 10.1021/acs.orglett.5b01101. Epub 2015 Jul 6.

PMID:
26147155
26.

Hydroboration of Arynes Formed by Hexadehydro-Diels-Alder Cyclizations with N-Heterocyclic Carbene Boranes.

Watanabe T, Curran DP, Taniguchi T.

Org Lett. 2015 Jul 17;17(14):3450-3. doi: 10.1021/acs.orglett.5b01480. Epub 2015 Jun 26.

PMID:
26114804
27.

Radical Reactions of N-Heterocyclic Carbene Boranes with Organic Nitriles: Cyanation of NHC-Boranes and Reductive Decyanation of Malononitriles.

Kawamoto T, Geib SJ, Curran DP.

J Am Chem Soc. 2015 Jul 8;137(26):8617-22. doi: 10.1021/jacs.5b04677. Epub 2015 Jun 23.

PMID:
26050710
28.

Dynamic Behavior of N-Heterocyclic Carbene Boranes: Boron-Carbene Bonds in B,B-Disubstituted N,N-Dimethylimidazol-2-ylidene Boranes Have Substantial Rotation Barriers.

Damodaran K, Li X, Pan X, Curran DP.

J Org Chem. 2015 May 1;80(9):4465-9. doi: 10.1021/acs.joc.5b00324. Epub 2015 Apr 17.

PMID:
25843519
29.

Rearrangement reactions of 1,1-divinyl-2-phenylcyclopropanes.

Hay EB, Zhang H, Curran DP.

J Am Chem Soc. 2015 Jan 14;137(1):322-7. doi: 10.1021/ja510608u. Epub 2014 Dec 22.

30.

Hydroboration of arynes with N-heterocyclic carbene boranes.

Taniguchi T, Curran DP.

Angew Chem Int Ed Engl. 2014 Nov 24;53(48):13150-4. doi: 10.1002/anie.201408345. Epub 2014 Oct 24.

PMID:
25346015
31.

The electron is a catalyst.

Studer A, Curran DP.

Nat Chem. 2014 Sep;6(9):765-73. doi: 10.1038/nchem.2031. Review.

PMID:
25143210
32.

Systematic comparison of sets of (13)C NMR spectra that are potentially identical. Confirmation of the configuration of a cuticular hydrocarbon from the cane beetle Antitrogus parvulus.

Basar N, Damodaran K, Liu H, Morris GA, Sirat HM, Thomas EJ, Curran DP.

J Org Chem. 2014 Aug 15;79(16):7477-90. doi: 10.1021/jo5012027. Epub 2014 Jul 28.

33.

Neutral sulfur nucleophiles: synthesis of thioethers and thioesters by substitution reactions of N-heterocyclic carbene boryl sulfides and thioamides.

Pan X, Curran DP.

Org Lett. 2014 May 16;16(10):2728-31. doi: 10.1021/ol5010164. Epub 2014 May 6.

PMID:
24802672
34.

Early life establishment of site-specific microbial communities in the gut.

Romano-Keeler J, Moore DJ, Wang C, Brucker RM, Fonnesbeck C, Slaughter JC, Li H, Curran DP, Meng S, Correa H, Lovvorn HN 3rd, Tang YW, Bordenstein S, George AL Jr, Weitkamp JH.

Gut Microbes. 2014 Mar-Apr;5(2):192-201. doi: 10.4161/gmic.28442. Epub 2014 Mar 5.

35.

The renaissance of organic radical chemistry - deja vu all over again.

Stephenson CR, Studer A, Curran DP.

Beilstein J Org Chem. 2013 Dec 4;9:2778-80. doi: 10.3762/bjoc.9.312. eCollection 2013. No abstract available.

36.

Radical [3 + 2]-annulation of divinylcyclopropanes: rapid synthesis of complex meloscine analogs.

Zhang H, Jeon KO, Hay EB, Geib SJ, Curran DP, LaPorte MG.

Org Lett. 2014 Jan 3;16(1):94-7. doi: 10.1021/ol403078e. Epub 2013 Dec 6.

37.

Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution.

Dewanji A, Murarka S, Curran DP, Studer A.

Org Lett. 2013 Dec 6;15(23):6102-5. doi: 10.1021/ol402995e. Epub 2013 Nov 19.

38.
39.

Formation of N-heterocyclic carbene-boryl radicals through electrochemical and photochemical cleavage of the B-S bond in N-heterocyclic carbene-boryl sulfides.

Telitel S, Vallet AL, Schweizer S, Delpech B, Blanchard N, Morlet-Savary F, Graff B, Curran DP, Robert M, Lacôte E, Lalevée J.

J Am Chem Soc. 2013 Nov 13;135(45):16938-47. doi: 10.1021/ja4066267. Epub 2013 Oct 29.

PMID:
24111491
40.

Weakly stabilized primary borenium cations and their dicationic dimers.

Prokofjevs A, Kampf JW, Solovyev A, Curran DP, Vedejs E.

J Am Chem Soc. 2013 Oct 23;135(42):15686-9. doi: 10.1021/ja407458k. Epub 2013 Oct 10.

41.

Molecular iodine initiates hydroborations of alkenes with N-heterocyclic carbene boranes.

Pan X, Boussonnière A, Curran DP.

J Am Chem Soc. 2013 Sep 25;135(38):14433-7. doi: 10.1021/ja407678e. Epub 2013 Sep 13.

PMID:
23981246
42.

Insertion of reactive rhodium carbenes into boron-hydrogen bonds of stable N-heterocyclic carbene boranes.

Li X, Curran DP.

J Am Chem Soc. 2013 Aug 14;135(32):12076-81. doi: 10.1021/ja4056245. Epub 2013 Jul 31.

PMID:
23865527
43.

Mechanistic and preparative studies of radical chain homolytic substitution reactions of N-heterocyclic carbene boranes and disulfides.

Pan X, Vallet AL, Schweizer S, Dahbi K, Delpech B, Blanchard N, Graff B, Geib SJ, Curran DP, Lalevée J, Lacôte E.

J Am Chem Soc. 2013 Jul 17;135(28):10484-91. doi: 10.1021/ja403627k. Epub 2013 Jul 3.

PMID:
23718209
44.

Reductions of aldehydes and ketones with a readily available N-heterocyclic carbene borane and acetic acid.

Lamm V, Pan X, Taniguchi T, Curran DP.

Beilstein J Org Chem. 2013 Apr 8;9:675-80. doi: 10.3762/bjoc.9.76. Print 2013.

45.

Efficient hydroxymethylation reactions of iodoarenes using CO and 1,3-dimethylimidazol-2-ylidene borane.

Kawamoto T, Okada T, Curran DP, Ryu I.

Org Lett. 2013 May 3;15(9):2144-7. doi: 10.1021/ol4006294. Epub 2013 Apr 16.

PMID:
23590524
46.

Synthesis and analysis of the all-(S) side chain of phosphomycoketides: a test of NMR predictions for saturated oligoisoprenoid stereoisomers.

Buter J, Yeh EA, Budavich OW, Damodaran K, Minnaard AJ, Curran DP.

J Org Chem. 2013 May 17;78(10):4913-8. doi: 10.1021/jo4005298. Epub 2013 Apr 25.

47.

Rotational isomers of N-methyl-N-arylacetamides and their derived enolates: implications for asymmetric Hartwig oxindole cyclizations.

Mandel J, Pan X, Hay EB, Geib SJ, Wilcox CS, Curran DP.

J Org Chem. 2013 Apr 19;78(8):4083-9. doi: 10.1021/jo400385t. Epub 2013 Apr 9.

48.

N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation.

Gatineau D, Zhao Q, Curran DP, Malacria M, Lacôte E, Fensterbank L, Goddard JP.

Dalton Trans. 2013 May 28;42(20):7458-62. doi: 10.1039/c3dt32983f.

PMID:
23459715
49.

Oxygen switch in visible-light photoredox catalysis: radical additions and cyclizations and unexpected C-C-bond cleavage reactions.

Zhu S, Das A, Bui L, Zhou H, Curran DP, Rueping M.

J Am Chem Soc. 2013 Feb 6;135(5):1823-9. doi: 10.1021/ja309580a. Epub 2013 Jan 18.

PMID:
23330701
50.

Bare-minimum fluorous mixture synthesis of a stereoisomer library of 4,8,12-trimethylnonadecanols and predictions of NMR spectra of saturated oligoisoprenoid stereoisomers.

Yeh EA, Kumli E, Damodaran K, Curran DP.

J Am Chem Soc. 2013 Jan 30;135(4):1577-84. doi: 10.1021/ja311606u. Epub 2013 Jan 18.

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