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Items: 1 to 50 of 131

1.

Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer.

Szkop KM, Geeson MB, Stephan DW, Cummins CC.

Chem Sci. 2019 Feb 7;10(12):3627-3631. doi: 10.1039/c8sc05657a. eCollection 2019 Mar 28.

2.

Orthophosphate and Sulfate Utilization for C-E (E = P, S) Bond Formation via Trichlorosilyl Phosphide and Sulfide Anions.

Geeson MB, Ríos P, Transue WJ, Cummins CC.

J Am Chem Soc. 2019 Apr 17;141(15):6375-6384. doi: 10.1021/jacs.9b01475. Epub 2019 Apr 8.

PMID:
30901207
3.

Functionalization of Intact Trimetaphosphate: A Triphosphorylating Reagent for C, N, and O Nucleophiles.

Shepard SM, Cummins CC.

J Am Chem Soc. 2019 Feb 6;141(5):1852-1856. doi: 10.1021/jacs.8b12204. Epub 2019 Jan 29.

PMID:
30646689
4.

Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus-Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow.

Transue WJ, Nava M, Terban MW, Yang J, Greenberg MW, Wu G, Foreman ES, Mustoe CL, Kennepohl P, Owen JS, Billinge SJL, Kulik HJ, Cummins CC.

J Am Chem Soc. 2019 Jan 9;141(1):431-440. doi: 10.1021/jacs.8b10775. Epub 2018 Dec 18.

PMID:
30512942
5.

Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors.

Transue WJ, Yang J, Nava M, Sergeyev IV, Barnum TJ, McCarthy MC, Cummins CC.

J Am Chem Soc. 2018 Dec 26;140(51):17985-17991. doi: 10.1021/jacs.8b09845. Epub 2018 Dec 12.

PMID:
30485736
6.

Countercation Effect on CO2 Binding to Oxo Titanate with Bulky Anilide Ligands.

Paparo A, Silvia JS, Spaniol TP, Okuda J, Cummins CC.

Chemistry. 2018 Nov 16;24(64):17072-17079. doi: 10.1002/chem.201803265. Epub 2018 Oct 23.

PMID:
30350897
7.

Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity.

Joost M, Nava M, Transue WJ, Martin-Drumel MA, McCarthy MC, Patterson D, Cummins CC.

Proc Natl Acad Sci U S A. 2018 Jun 5;115(23):5866-5871. doi: 10.1073/pnas.1804035115. Epub 2018 May 17.

8.

Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent.

Joost M, Transue WJ, Cummins CC.

Chem Sci. 2017 Dec 21;9(6):1540-1543. doi: 10.1039/c7sc04506a. eCollection 2018 Feb 14.

9.

Phosphoric acid as a precursor to chemicals traditionally synthesized from white phosphorus.

Geeson MB, Cummins CC.

Science. 2018 Mar 23;359(6382):1383-1385. doi: 10.1126/science.aar6620. Epub 2018 Feb 8.

PMID:
29439027
10.

Cobalt and Vanadium Trimetaphosphate Polyanions: Synthesis, Characterization, and Electrochemical Evaluation for Non-aqueous Redox-Flow Battery Applications.

Stauber JM, Zhang S, Gvozdik N, Jiang Y, Avena L, Stevenson KJ, Cummins CC.

J Am Chem Soc. 2018 Jan 17;140(2):538-541. doi: 10.1021/jacs.7b08751. Epub 2018 Jan 4.

PMID:
29232132
11.

An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom.

Joost M, Nava M, Transue WJ, Cummins CC.

Chem Commun (Camb). 2017 Oct 17;53(83):11500-11503. doi: 10.1039/c7cc06516g.

PMID:
28990025
12.

On the incompatibility of lithium-O2 battery technology with CO2.

Zhang S, Nava MJ, Chow GK, Lopez N, Wu G, Britt DR, Nocera DG, Cummins CC.

Chem Sci. 2017 Sep 1;8(9):6117-6122. doi: 10.1039/c7sc01230f. Epub 2017 Jun 20.

13.

Terminal tungsten pnictide complex formation through pnictaethynolate decarbonylation.

Joost M, Transue WJ, Cummins CC.

Chem Commun (Camb). 2017 Sep 26;53(77):10731-10733. doi: 10.1039/c7cc06841g.

PMID:
28920594
14.

Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds.

Transue WJ, Velian A, Nava M, García-Iriepa C, Temprado M, Cummins CC.

J Am Chem Soc. 2017 Aug 9;139(31):10822-10831. doi: 10.1021/jacs.7b05464. Epub 2017 Jul 27.

PMID:
28703579
15.

Second-Coordination-Sphere Assisted Selective Colorimetric Turn-on Fluoride Sensing by a Mono-Metallic Co(II) Hexacarboxamide Cryptand Complex.

Stauber JM, Alliger GE, Nocera DG, Cummins CC.

Inorg Chem. 2017 Jul 17;56(14):7615-7619. doi: 10.1021/acs.inorgchem.7b01335. Epub 2017 Jun 30.

PMID:
28665117
16.

A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO2/ethylene coupling.

Knopf I, Tofan D, Beetstra D, Al-Nezari A, Al-Bahily K, Cummins CC.

Chem Sci. 2017 Feb 1;8(2):1463-1468. doi: 10.1039/c6sc03614g. Epub 2016 Oct 11.

17.

Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX- (E = As, P, and N; X = S and O) Anions.

Hou GL, Chen B, Transue WJ, Yang Z, Grützmacher H, Driess M, Cummins CC, Borden WT, Wang XB.

J Am Chem Soc. 2017 Jul 5;139(26):8922-8930. doi: 10.1021/jacs.7b02984. Epub 2017 Jun 23.

PMID:
28589728
18.

Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙.

Stauber JM, Müller P, Dai Y, Wu G, Nocera DG, Cummins CC.

Chem Sci. 2016 Dec 1;7(12):6928-6933. doi: 10.1039/c6sc01754a. Epub 2016 Jul 6.

19.

Terminal Titanyl Complexes of Tri- and Tetrametaphosphate: Synthesis, Structures, and Reactivity with Hydrogen Peroxide.

Stauber JM, Cummins CC.

Inorg Chem. 2017 Mar 6;56(5):3022-3029. doi: 10.1021/acs.inorgchem.6b03149. Epub 2017 Feb 16.

PMID:
28207244
20.

Phosphinidene Reactivity of a Transient Vanadium P≡N Complex.

Courtemanche MA, Transue WJ, Cummins CC.

J Am Chem Soc. 2016 Dec 21;138(50):16220-16223. doi: 10.1021/jacs.6b10545. Epub 2016 Dec 13.

PMID:
27958729
21.

Spontaneous and Selective Formation of HSNO, a Crucial Intermediate Linking H2S and Nitroso Chemistries.

Nava M, Martin-Drumel MA, Lopez CA, Crabtree KN, Womack CC, Nguyen TL, Thorwirth S, Cummins CC, Stanton JF, McCarthy MC.

J Am Chem Soc. 2016 Sep 14;138(36):11441-4. doi: 10.1021/jacs.6b05886. Epub 2016 Aug 31.

22.

A Joint Experimental and Computational Study of the Negative Ion Photoelectron Spectroscopy of the 1-Phospha-2,3,4-triazolate Anion, HCPN3(.).

Hou GL, Chen B, Transue WJ, Hrovat DA, Cummins CC, Borden WT, Wang XB.

J Phys Chem A. 2016 Aug 11;120(31):6228-35. doi: 10.1021/acs.jpca.6b06343. Epub 2016 Jul 29.

PMID:
27434547
23.

Negative ion photoelectron spectroscopy of P2N3-: electron affinity and electronic structures of P2N3˙.

Hou GL, Chen B, Transue WJ, Hrovat DA, Cummins CC, Borden WT, Wang XB.

Chem Sci. 2016 Jul 1;7(7):4667-4675. doi: 10.1039/c5sc04667j. Epub 2016 Apr 19.

24.

Crystalline Metaphosphate Acid Salts: Synthesis in Organic Media, Structures, Hydrogen-Bonding Capability, and Implication of Superacidity.

Chakarawet K, Knopf I, Nava M, Jiang Y, Stauber JM, Cummins CC.

Inorg Chem. 2016 Jun 20;55(12):6178-85. doi: 10.1021/acs.inorgchem.6b00749. Epub 2016 Jun 7.

PMID:
27267865
25.

A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion.

Transue WJ, Velian A, Nava M, Martin-Drumel MA, Womack CC, Jiang J, Hou GL, Wang XB, McCarthy MC, Field RW, Cummins CC.

J Am Chem Soc. 2016 Jun 1;138(21):6731-4. doi: 10.1021/jacs.6b03910. Epub 2016 May 19.

PMID:
27171847
26.

WITHDRAWN: Laser resurfacing for facial acne scars.

Jordan R, Cummins CC, Burls A, Seukeran DD.

Cochrane Database Syst Rev. 2016 Apr 4;4:CD001866. doi: 10.1002/14651858.CD001866.pub2. Review. No abstract available.

PMID:
27042993
27.

Pushing Single-Oxygen-Atom-Bridged Bimetallic Systems to the Right: A Cryptand-Encapsulated Co-O-Co Unit.

Stauber JM, Bloch ED, Vogiatzis KD, Zheng SL, Hadt RG, Hayes D, Chen LX, Gagliardi L, Nocera DG, Cummins CC.

J Am Chem Soc. 2015 Dec 16;137(49):15354-7. doi: 10.1021/jacs.5b09827. Epub 2015 Dec 7.

PMID:
26559923
28.

Assembly and stabilization of {E(cyclo-P3)2} (E = Sn, Pb) as a bridging ligand spanning two triaryloxyniobium units.

Velian A, Cossairt BM, Cummins CC.

Dalton Trans. 2016 Feb 7;45(5):1891-5. doi: 10.1039/c5dt03383g. Epub 2015 Oct 27.

PMID:
26505867
29.

Anion-Receptor Mediated Oxidation of Carbon Monoxide to Carbonate by Peroxide Dianion.

Nava M, Lopez N, Müller P, Wu G, Nocera DG, Cummins CC.

J Am Chem Soc. 2015 Nov 25;137(46):14562-5. doi: 10.1021/jacs.5b08495. Epub 2015 Nov 12.

PMID:
26465825
30.

A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO2.

Paparo A, Silvia JS, Kefalidis CE, Spaniol TP, Maron L, Okuda J, Cummins CC.

Angew Chem Int Ed Engl. 2015 Jul 27;54(31):9115-9. doi: 10.1002/anie.201502532. Epub 2015 Jun 25.

PMID:
26110967
31.

Inorganic chemistry. Synthesis and characterization of P₂N₃⁻: an aromatic ion composed of phosphorus and nitrogen.

Velian A, Cummins CC.

Science. 2015 May 29;348(6238):1001-4. doi: 10.1126/science.aab0204.

33.

Ultrafast Photoinduced Electron Transfer from Peroxide Dianion.

Anderson BL, Maher AG, Nava M, Lopez N, Cummins CC, Nocera DG.

J Phys Chem B. 2015 Jun 18;119(24):7422-9. doi: 10.1021/jp5110505. Epub 2015 Feb 25.

PMID:
25635708
34.

Radical anionic versus neutral 2,2'-bipyridyl coordination in uranium complexes supported by amide and ketimide ligands.

Diaconescu PL, Cummins CC.

Dalton Trans. 2015 Feb 14;44(6):2676-83. doi: 10.1039/c4dt02422b.

35.

Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes.

Majumdar S, Stauber JM, Palluccio TD, Cai X, Velian A, Rybak-Akimova EV, Temprado M, Captain B, Cummins CC, Hoff CD.

Inorg Chem. 2014 Oct 20;53(20):11185-96. doi: 10.1021/ic5017005. Epub 2014 Oct 3.

PMID:
25280113
36.

A retro Diels-Alder route to diphosphorus chemistry: molecular precursor synthesis, kinetics of P2 transfer to 1,3-dienes, and detection of P2 by molecular beam mass spectrometry.

Velian A, Nava M, Temprado M, Zhou Y, Field RW, Cummins CC.

J Am Chem Soc. 2014 Oct 1;136(39):13586-9. doi: 10.1021/ja507922x. Epub 2014 Sep 19.

PMID:
25198657
37.

Dihydrogen tetrametaphosphate, [P4O12H2]2-: synthesis, solubilization in organic media, preparation of its anhydride [P4O11]2- and acidic methyl ester, and conversion to tetrametaphosphate metal complexes via protonolysis.

Jiang Y, Chakarawet K, Kohout AL, Nava M, Marino N, Cummins CC.

J Am Chem Soc. 2014 Aug 27;136(34):11894-7. doi: 10.1021/ja5058339. Epub 2014 Aug 14.

PMID:
25102033
38.

Electron-transfer studies of a peroxide dianion.

Ullman AM, Sun X, Graham DJ, Lopez N, Nava M, De Las Cuevas R, Müller P, Rybak-Akimova EV, Cummins CC, Nocera DG.

Inorg Chem. 2014 May 19;53(10):5384-91. doi: 10.1021/ic500759g. Epub 2014 Apr 28.

PMID:
24773522
39.

The stannylphosphide anion reagent sodium bis(triphenylstannyl) phosphide: synthesis, structural characterization, and reactions with indium, tin, and gold electrophiles.

Cummins CC, Huang C, Miller TJ, Reintinger MW, Stauber JM, Tannou I, Tofan D, Toubaei A, Velian A, Wu G.

Inorg Chem. 2014 Apr 7;53(7):3678-87. doi: 10.1021/ic403178j. Epub 2014 Mar 12.

PMID:
24621383
40.

Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide.

Cozzolino AF, Silvia JS, Lopez N, Cummins CC.

Dalton Trans. 2014 Mar 28;43(12):4639-52. doi: 10.1039/c3dt52738g.

PMID:
24492850
41.

Facile synthesis of mononuclear early transition-metal complexes of κ3cyclo-tetrametaphosphate ([P4O12]4-) and cyclo-trimetaphosphate ([P3O9]3-.

Manna CM, Nassar MY, Tofan D, Chakarawet K, Cummins CC.

Dalton Trans. 2014 Jan 28;43(4):1509-18. doi: 10.1039/c3dt52526k.

PMID:
24285119
42.

Functionalization reactions characteristic of a robust bicyclic diphosphane framework.

Tofan D, Temprado M, Majumdar S, Hoff CD, Cummins CC.

Inorg Chem. 2013 Aug 5;52(15):8851-64. doi: 10.1021/ic401052a. Epub 2013 Jul 10.

PMID:
23841641
43.

Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide.

Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Chui M, Temprado M, Silvia JS, Cozzolino AF, Tofan D, Velian A, Cummins CC, Captain B, Hoff CD.

J Am Chem Soc. 2013 Jul 31;135(30):11357-72. doi: 10.1021/ja405395z. Epub 2013 Jul 18.

PMID:
23805977
44.

Relaxation and dissociation following photoexcitation of the (μ-N2)[Mo(N[t-Bu]Ar)3]2 dinitrogen cleavage intermediate.

Huss AS, Curley JJ, Cummins CC, Blank DA.

J Phys Chem B. 2013 Feb 7;117(5):1429-36. doi: 10.1021/jp310122x. Epub 2013 Jan 28.

PMID:
23249096
45.

Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex.

Cozzolino AF, Tofan D, Cummins CC, Temprado M, Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Captain B, Hoff CD.

J Am Chem Soc. 2012 Nov 7;134(44):18249-52. doi: 10.1021/ja309621h. Epub 2012 Oct 29.

PMID:
23082724
46.

Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene.

Velian A, Cummins CC.

J Am Chem Soc. 2012 Aug 29;134(34):13978-81. doi: 10.1021/ja306902j. Epub 2012 Aug 20.

PMID:
22894133
47.

Terminal phosphinidene formation via tantalaziridine complexes.

Rankin MA, Cummins CC.

Dalton Trans. 2012 Aug 28;41(32):9615-8. doi: 10.1039/c2dt31082a. Epub 2012 Jul 12.

PMID:
22790093
48.

A highly reduced cyanogen ligand derived from cyanide reductive coupling.

Fox AR, Cummins CC.

Chem Commun (Camb). 2012 Mar 25;48(25):3061-3. doi: 10.1039/c2cc17212g. Epub 2012 Feb 17.

PMID:
22343665
49.

μ-η6,η6-Arene-bridged diuranium hexakisketimide complexes isolable in two states of charge.

Diaconescu PL, Cummins CC.

Inorg Chem. 2012 Mar 5;51(5):2902-16. doi: 10.1021/ic202163m. Epub 2012 Feb 16.

PMID:
22339231
50.

Reversible reduction of oxygen to peroxide facilitated by molecular recognition.

Lopez N, Graham DJ, McGuire R Jr, Alliger GE, Shao-Horn Y, Cummins CC, Nocera DG.

Science. 2012 Jan 27;335(6067):450-3. doi: 10.1126/science.1212678.

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