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Items: 1 to 50 of 209

1.

Trends and Risk Factors in Orthopedic Lawsuits: Analysis of a National Legal Database.

Cichos KH, Ewing MA, Sheppard ED, Fuchs C, McGwin G Jr, McMurtrie JT, Watson SL, Xu S, Fryberger C, Baker DK, Crabtree RM, Murphy AB, Vaughan LO, Perez JL, Sherrod BA, Edmonds BW, Ponce BA.

Orthopedics. 2019 Mar 1;42(2):e260-e267. doi: 10.3928/01477447-20190211-01. Epub 2019 Feb 14.

PMID:
30763449
2.

Strongly Coupled Phenazine-Porphyrin Dyads: Light-Harvesting Molecular Assemblies with Broad Absorption Coverage.

Lee SH, Matula AJ, Hu G, Troiano JL, Karpovich CJ, Crabtree RH, Batista VS, Brudvig GW.

ACS Appl Mater Interfaces. 2019 Feb 27;11(8):8000-8008. doi: 10.1021/acsami.8b20996. Epub 2019 Feb 12.

PMID:
30698407
3.

On the damage done to the structure of the Thermoplasma acidophilum proteasome by electron radiation.

Wang J, Liu Z, Crabtree RH, Frank J, Moore PB.

Protein Sci. 2018 Dec;27(12):2051-2061. doi: 10.1002/pro.3511. Epub 2018 Nov 5.

4.

Silatrane Anchors for Metal Oxide Surfaces: Optimization for Potential Photocatalytic and Electrocatalytic Applications.

Materna KL, Jiang J, Crabtree RH, Brudvig GW.

ACS Appl Mater Interfaces. 2019 Feb 13;11(6):5602-5609. doi: 10.1021/acsami.8b04138. Epub 2018 Jun 12.

PMID:
29893542
5.

A Dinuclear Iridium(V,V) Oxo-Bridged Complex Characterized Using a Bulk Electrolysis Technique for Crystallizing Highly Oxidizing Compounds.

Shopov DY, Sharninghausen LS, Sinha SB, Mercado BQ, Balcells D, Brudvig GW, Crabtree RH.

Inorg Chem. 2018 May 7;57(9):5684-5691. doi: 10.1021/acs.inorgchem.8b00757. Epub 2018 Apr 10.

PMID:
29634253
6.

Key factors in pincer ligand design.

Peris E, Crabtree RH.

Chem Soc Rev. 2018 Mar 21;47(6):1959-1968. doi: 10.1039/c7cs00693d. Epub 2018 Feb 12.

PMID:
29431828
7.

Optimization of Photoanodes for Photocatalytic Water Oxidation by Combining a Heterogenized Iridium Water-Oxidation Catalyst with a High-Potential Porphyrin Photosensitizer.

Materna KL, Jiang J, Regan KP, Schmuttenmaer CA, Crabtree RH, Brudvig GW.

ChemSusChem. 2017 Nov 23;10(22):4526-4534. doi: 10.1002/cssc.201701693. Epub 2017 Oct 23.

PMID:
28876510
8.

Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O-Donor Organic Ligand.

Sharninghausen LS, Sinha SB, Shopov DY, Mercado BQ, Balcells D, Brudvig GW, Crabtree RH.

Angew Chem Int Ed Engl. 2017 Oct 9;56(42):13047-13051. doi: 10.1002/anie.201707593. Epub 2017 Sep 6.

PMID:
28815915
9.

Intraoperative Topical Antibiotics for Infection Prophylaxis in Pelvic and Acetabular Surgery.

Owen MT, Keener EM, Hyde ZB, Crabtree RM, Hudson PW, Griffin RL, Lowe JA.

J Orthop Trauma. 2017 Nov;31(11):589-594. doi: 10.1097/BOT.0000000000000941.

PMID:
28708777
10.

Introduction: CH Activation.

Crabtree RH, Lei A.

Chem Rev. 2017 Jul 12;117(13):8481-8482. doi: 10.1021/acs.chemrev.7b00307. No abstract available.

PMID:
28697603
11.

Redox Activity of Oxo-Bridged Iridium Dimers in an N,O-Donor Environment: Characterization of Remarkably Stable Ir(IV,V) Complexes.

Sinha SB, Shopov DY, Sharninghausen LS, Stein CJ, Mercado BQ, Balcells D, Pedersen TB, Reiher M, Brudvig GW, Crabtree RH.

J Am Chem Soc. 2017 Jul 19;139(28):9672-9683. doi: 10.1021/jacs.7b04874. Epub 2017 Jul 5.

PMID:
28648068
12.

Anchoring groups for photocatalytic water oxidation on metal oxide surfaces.

Materna KL, Crabtree RH, Brudvig GW.

Chem Soc Rev. 2017 Oct 16;46(20):6099-6110. doi: 10.1039/c7cs00314e.

PMID:
28640299
13.

Antimony Complexes for Electrocatalysis: Activity of a Main-Group Element in Proton Reduction.

Jiang J, Materna KL, Hedström S, Yang KR, Crabtree RH, Batista VS, Brudvig GW.

Angew Chem Int Ed Engl. 2017 Jul 24;56(31):9111-9115. doi: 10.1002/anie.201704700. Epub 2017 Jul 4.

PMID:
28628943
14.

A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties.

Shopov DY, Rudshteyn B, Campos J, Vinyard DJ, Batista VS, Brudvig GW, Crabtree RH.

Chem Sci. 2017 Feb 1;8(2):1642-1652. doi: 10.1039/c6sc03758e. Epub 2016 Nov 7.

15.

A Pyridine Alkoxide Chelate Ligand That Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis.

Michaelos TK, Shopov DY, Sinha SB, Sharninghausen LS, Fisher KJ, Lant HMC, Crabtree RH, Brudvig GW.

Acc Chem Res. 2017 Apr 18;50(4):952-959. doi: 10.1021/acs.accounts.6b00652. Epub 2017 Mar 8.

PMID:
28272869
16.

Hypervalency, secondary bonding and hydrogen bonding: siblings under the skin.

Crabtree RH.

Chem Soc Rev. 2017 Mar 21;46(6):1720-1729. doi: 10.1039/c6cs00688d.

PMID:
28240328
17.

Homogeneous Transition Metal Catalysis of Acceptorless Dehydrogenative Alcohol Oxidation: Applications in Hydrogen Storage and to Heterocycle Synthesis.

Crabtree RH.

Chem Rev. 2017 Jul 12;117(13):9228-9246. doi: 10.1021/acs.chemrev.6b00556. Epub 2017 Jan 4.

PMID:
28051854
18.

High Oxidation State Iridium Mono-μ-oxo Dimers Related to Water Oxidation Catalysis.

Sharninghausen LS, Sinha SB, Shopov DY, Choi B, Mercado BQ, Roy X, Balcells D, Brudvig GW, Crabtree RH.

J Am Chem Soc. 2016 Dec 14;138(49):15917-15926. Epub 2016 Dec 1.

PMID:
27960326
19.

Oral Health Behaviors and Perceptions Among College Students.

Crabtree R, Kirk A, Moore M, Abraham S.

Health Care Manag (Frederick). 2016 Oct/Dec;35(4):350-360.

PMID:
27661406
20.

Controlling the rectification properties of molecular junctions through molecule-electrode coupling.

Koepf M, Koenigsmann C, Ding W, Batra A, Negre CF, Venkataraman L, Brudvig GW, Batista VS, Schmuttenmaer CA, Crabtree RH.

Nanoscale. 2016 Sep 15;8(36):16357-16362.

PMID:
27722662
21.

One-Step Trimethylstannylation of Benzyl and Alkyl Halides.

Jiang J, Crabtree RH, Brudvig GW.

J Org Chem. 2016 Oct 7;81(19):9483-9488. Epub 2016 Sep 27.

PMID:
27643532
22.

Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic-Inorganic Ligand.

Bloomfield AJ, Matula AJ, Mercado BQ, Batista VS, Crabtree RH.

Inorg Chem. 2016 Aug 15;55(16):8121-9. doi: 10.1021/acs.inorgchem.6b01218. Epub 2016 Jul 27.

PMID:
27462911
23.

Molecular design of light-harvesting photosensitizers: effect of varied linker conjugation on interfacial electron transfer.

Jiang J, Swierk JR, Hedström S, Matula AJ, Crabtree RH, Batista VS, Schmuttenmaer CA, Brudvig GW.

Phys Chem Chem Phys. 2016 Jul 28;18(28):18678-82. doi: 10.1039/c6cp04377a. Epub 2016 Jul 1.

PMID:
27364769
24.

Evaluation of modelled net primary production using MODIS and landsat satellite data fusion.

Jay S, Potter C, Crabtree R, Genovese V, Weiss DJ, Kraft M.

Carbon Balance Manag. 2016 Jun 2;11(1):8. eCollection 2016 Dec.

25.

Necessary but not sufficient? Engaging young people in the development of an avatar-based online intervention designed to provide psychosocial support to young people affected by their own or a family member's cancer diagnosis.

Phelps C, Minou M, Baker A, Hughes C, French H, Hawkins W, Leeuwenberg A, Crabtree R, Hutchings PB.

Health Expect. 2017 Jun;20(3):459-470. doi: 10.1111/hex.12473. Epub 2016 Jun 12.

26.

Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-ray Scattering and EXAFS Spectroscopy.

Yang KR, Matula AJ, Kwon G, Hong J, Sheehan SW, Thomsen JM, Brudvig GW, Crabtree RH, Tiede DM, Chen LX, Batista VS.

J Am Chem Soc. 2016 May 4;138(17):5511-4. doi: 10.1021/jacs.6b01750. Epub 2016 Apr 22.

PMID:
27087202
27.

Dihydrogen Complexation.

Crabtree RH.

Chem Rev. 2016 Aug 10;116(15):8750-69. doi: 10.1021/acs.chemrev.6b00037. Epub 2016 Mar 14. Review.

PMID:
26974601
28.

New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis.

Huang DL, Beltrán-Suito R, Thomsen JM, Hashmi SM, Materna KL, Sheehan SW, Mercado BQ, Brudvig GW, Crabtree RH.

Inorg Chem. 2016 Mar 7;55(5):2427-35. doi: 10.1021/acs.inorgchem.5b02809. Epub 2016 Feb 22.

PMID:
26901517
29.

Molecular titanium-hydroxamate complexes as models for TiO2 surface binding.

Brennan BJ, Chen J, Rudshteyn B, Chaudhuri S, Mercado BQ, Batista VS, Crabtree RH, Brudvig GW.

Chem Commun (Camb). 2016 Feb 18;52(14):2972-5. doi: 10.1039/c5cc09857b.

PMID:
26781247
30.

Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-Phenylbenzamide.

Ding W, Koepf M, Koenigsmann C, Batra A, Venkataraman L, Negre CF, Brudvig GW, Crabtree RH, Schmuttenmaer CA, Batista VS.

J Chem Theory Comput. 2015 Dec 8;11(12):5888-96. doi: 10.1021/acs.jctc.5b00823. Epub 2015 Nov 11.

PMID:
26642992
31.

A Stable Coordination Complex of Rh(IV) in an N,O-Donor Environment.

Sinha SB, Shopov DY, Sharninghausen LS, Vinyard DJ, Mercado BQ, Brudvig GW, Crabtree RH.

J Am Chem Soc. 2015 Dec 23;137(50):15692-5. doi: 10.1021/jacs.5b12148. Epub 2015 Dec 10.

PMID:
26641941
32.

Gel-assisted crystallization of [Ir4(IMe)7(CO)H10](2+) and [Ir4(IMe)8H9](3+) clusters derived from catalytic glycerol dehydrogenation.

Sharninghausen LS, Mercado BQ, Crabtree RH, Balcells D, Campos J.

Dalton Trans. 2015 Nov 14;44(42):18403-10. doi: 10.1039/c5dt03302k. Epub 2015 Oct 5.

PMID:
26435314
33.

Selective conversion of glycerol to lactic acid with iron pincer precatalysts.

Sharninghausen LS, Mercado BQ, Crabtree RH, Hazari N.

Chem Commun (Camb). 2015 Nov 21;51(90):16201-4. doi: 10.1039/c5cc06857f.

PMID:
26399400
34.

Preparation of Halogenated Fluorescent Diaminophenazine Building Blocks.

Koepf M, Lee SH, Brennan BJ, Méndez-Hernández DD, Batista VS, Brudvig GW, Crabtree RH.

J Org Chem. 2015 Oct 16;80(20):9881-8. doi: 10.1021/acs.joc.5b01339. Epub 2015 Oct 1.

PMID:
26390117
35.

Molecular Catalysts for Water Oxidation.

Blakemore JD, Crabtree RH, Brudvig GW.

Chem Rev. 2015 Dec 9;115(23):12974-3005. doi: 10.1021/acs.chemrev.5b00122. Epub 2015 Jul 7. No abstract available.

PMID:
26151088
36.

Stable Iridium(IV) Complexes of an Oxidation-Resistant Pyridine-Alkoxide Ligand: Highly Divergent Redox Properties Depending on the Isomeric Form Adopted.

Shopov DY, Rudshteyn B, Campos J, Batista VS, Crabtree RH, Brudvig GW.

J Am Chem Soc. 2015 Jun 10;137(22):7243-50. doi: 10.1021/jacs.5b04185. Epub 2015 Jun 1.

PMID:
25988658
37.

Iridium-based complexes for water oxidation.

Thomsen JM, Huang DL, Crabtree RH, Brudvig GW.

Dalton Trans. 2015 Jul 28;44(28):12452-72. doi: 10.1039/c5dt00863h.

PMID:
25978192
38.

Towards multielectron photocatalysis: a porphyrin array for lateral hole transfer and capture on a metal oxide surface.

Brennan BJ, Durrell AC, Koepf M, Crabtree RH, Brudvig GW.

Phys Chem Chem Phys. 2015 May 21;17(19):12728-34. doi: 10.1039/c5cp01683e.

PMID:
25904199
39.

A molecular catalyst for water oxidation that binds to metal oxide surfaces.

Sheehan SW, Thomsen JM, Hintermair U, Crabtree RH, Brudvig GW, Schmuttenmaer CA.

Nat Commun. 2015 Mar 11;6:6469. doi: 10.1038/ncomms7469.

40.

Methanol dehydrogenation by iridium N-heterocyclic carbene complexes.

Campos J, Sharninghausen LS, Manas MG, Crabtree RH.

Inorg Chem. 2015 Jun 1;54(11):5079-84. doi: 10.1021/ic502521c. Epub 2015 Jan 23.

PMID:
25615426
41.

Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure.

Crabtree RH.

Chem Rev. 2015 Jan 14;115(1):127-50. doi: 10.1021/cr5004375. Epub 2014 Dec 10. No abstract available.

PMID:
25493420
42.

Photoelectrochemical hole injection revealed in polyoxotitanate nanocrystals functionalized with organic adsorbates.

Negre CF, Young KJ, Oviedo MB, Allen LJ, Sánchez CG, Jarzembska KN, Benedict JB, Crabtree RH, Coppens P, Brudvig GW, Batista VS.

J Am Chem Soc. 2014 Nov 19;136(46):16420-9. doi: 10.1021/ja509270f. Epub 2014 Nov 6.

PMID:
25337894
43.

Efficient selective and atom economic catalytic conversion of glycerol to lactic acid.

Sharninghausen LS, Campos J, Manas MG, Crabtree RH.

Nat Commun. 2014 Oct 3;5:5084. doi: 10.1038/ncomms6084.

PMID:
25278373
44.

A carbene-rich but carbonyl-poor [Ir6 (IMe)8 (CO)2 H14 ](2+) polyhydride cluster as a deactivation product from catalytic glycerol dehydrogenation.

Campos J, Sharninghausen LS, Crabtree RH, Balcells D.

Angew Chem Int Ed Engl. 2014 Nov 17;53(47):12808-11. doi: 10.1002/anie.201407997. Epub 2014 Sep 22.

PMID:
25252028
45.

Electrochemical activation of Cp* iridium complexes for electrode-driven water-oxidation catalysis.

Thomsen JM, Sheehan SW, Hashmi SM, Campos J, Hintermair U, Crabtree RH, Brudvig GW.

J Am Chem Soc. 2014 Oct 1;136(39):13826-34. doi: 10.1021/ja5068299. Epub 2014 Sep 22.

PMID:
25188635
46.

Substitution of a hydroxamic acid anchor into the MK-2 dye for enhanced photovoltaic performance and water stability in a DSSC.

Koenigsmann C, Ripolles TS, Brennan BJ, Negre CF, Koepf M, Durrell AC, Milot RL, Torre JA, Crabtree RH, Batista VS, Brudvig GW, Bisquert J, Schmuttenmaer CA.

Phys Chem Chem Phys. 2014 Aug 21;16(31):16629-41. doi: 10.1039/c4cp02405b.

PMID:
24993024
47.

Linker rectifiers for covalent attachment of transition-metal catalysts to metal-oxide surfaces.

Ding W, Negre CF, Palma JL, Durrell AC, Allen LJ, Young KJ, Milot RL, Schmuttenmaer CA, Brudvig GW, Crabtree RH, Batista VS.

Chemphyschem. 2014 Apr 14;15(6):1138-47. doi: 10.1002/cphc.201400063. Epub 2014 Mar 25.

PMID:
24668518
48.

Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution.

Graeupner J, Hintermair U, Huang DL, Thomsen JM, Takase M, Campos J, Hashmi SM, Elimelech M, Brudvig GW, Crabtree RH.

Organometallics. 2013 Oct 14;32(19):5384-5390.

49.

Domain structure for an amorphous iridium-oxide water-oxidation catalyst characterized by X-ray pair distribution function analysis.

Huang J, Blakemore JD, Fazi D, Kokhan O, Schley ND, Crabtree RH, Brudvig GW, Tiede DM.

Phys Chem Chem Phys. 2014 Feb 7;16(5):1814-9. doi: 10.1039/c3cp54878c.

PMID:
24336574
50.

Modes of activation of organometallic iridium complexes for catalytic water and C-H oxidation.

Ingram AJ, Wolk AB, Flender C, Zhang J, Johnson CJ, Hintermair U, Crabtree RH, Johnson MA, Zare RN.

Inorg Chem. 2014 Jan 6;53(1):423-33. doi: 10.1021/ic402390t. Epub 2013 Nov 14.

PMID:
24228617

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