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Items: 1 to 50 of 61

1.

Kinetics of the Reaction of OH with Isoprene over a Wide Range of Temperature and Pressure Including Direct Observation of Equilibrium with the OH Adducts.

Medeiros DJ, Blitz MA, James L, Speak TH, Seakins PW.

J Phys Chem A. 2018 Sep 20;122(37):7239-7255. doi: 10.1021/acs.jpca.8b04829. Epub 2018 Sep 7.

PMID:
30137992
2.

Kinetic studies of C1 and C2 Criegee intermediates with SO2 using laser flash photolysis coupled with photoionization mass spectrometry and time resolved UV absorption spectroscopy.

Howes NUM, Mir ZS, Blitz MA, Hardman S, Lewis TR, Stone D, Seakins PW.

Phys Chem Chem Phys. 2018 Aug 29;20(34):22218-22227. doi: 10.1039/c8cp03115k.

PMID:
30118123
3.

Exploring the features on the OH + SO2 potential energy surface using theory and testing its accuracy by comparison to experimental data.

Medeiros DJ, Blitz MA, Seakins PW.

Phys Chem Chem Phys. 2018 Mar 28;20(13):8984-8990. doi: 10.1039/C8CP00091C.

PMID:
29557461
4.

A novel multiplex absorption spectrometer for time-resolved studies.

Lewis T, Heard DE, Blitz MA.

Rev Sci Instrum. 2018 Feb;89(2):024101. doi: 10.1063/1.5006539.

5.

Comment on "Methanol dimer formation drastically enhances hydrogen abstraction from methanol by OH at low temperature" by W. Siebrand, Z. Smedarchina, E. Martínez-Núñez and A. Fernández-Ramos, Phys. Chem. Chem. Phys., 2016, 18, 22712.

Shannon RJ, Gómez Martín JC, Caravan RL, Blitz MA, Plane JMC, Heard DE, Antiñolo M, Agúndez M, Jiménez E, Ballesteros B, Canosa A, El Dib G, Albaladejo J, Cernicharo J.

Phys Chem Chem Phys. 2018 Mar 28;20(12):8349-8354. doi: 10.1039/c7cp04561a. Epub 2018 Mar 1.

PMID:
29492495
6.

Obtaining effective rate coefficients to describe the decomposition kinetics of the corannulene oxyradical at high temperatures.

Wang H, You X, Blitz MA, Pilling MJ, Robertson SH.

Phys Chem Chem Phys. 2017 May 10;19(18):11064-11074. doi: 10.1039/c7cp00639j.

7.

An Experimental and Master Equation Study of the Kinetics of OH/OD + SO2: The Limiting High-Pressure Rate Coefficients.

Blitz MA, Salter RJ, Heard DE, Seakins PW.

J Phys Chem A. 2017 May 4;121(17):3184-3191. doi: 10.1021/acs.jpca.7b01295. Epub 2017 Apr 20.

8.

An Experimental Study of the Kinetics of OH/OD(v = 1,2,3) + SO2: The Limiting High-Pressure Rate Coefficients as a Function of Temperature.

Blitz MA, Salter RJ, Heard DE, Seakins PW.

J Phys Chem A. 2017 May 4;121(17):3175-3183. doi: 10.1021/acs.jpca.7b01294. Epub 2017 Apr 20.

9.

OH production from the photolysis of isoprene-derived peroxy radicals: cross-sections, quantum yields and atmospheric implications.

Hansen RF, Lewis TR, Graham L, Whalley LK, Seakins PW, Heard DE, Blitz MA.

Phys Chem Chem Phys. 2017 Jan 18;19(3):2332-2345. doi: 10.1039/c6cp06718b.

10.

Observation of a new channel, the production of CH3, in the abstraction reaction of OH radicals with acetaldehyde.

Howes NU, Lockhart JP, Blitz MA, Carr SA, Baeza-Romero MT, Heard DE, Shannon RJ, Seakins PW, Varga T.

Phys Chem Chem Phys. 2016 Sep 29;18(38):26423-26433.

11.

Temperature and Pressure Studies of the Reactions of CH3O2, HO2, and 1,2-C4H9O2 with NO2.

McKee K, Blitz MA, Pilling MJ.

J Phys Chem A. 2016 Mar 10;120(9):1408-20. doi: 10.1021/acs.jpca.5b06306. Epub 2015 Oct 13.

12.

Branching ratios for the reactions of OH with ethanol amines used in carbon capture and the potential impact on carcinogen formation in the emission plume from a carbon capture plant.

Onel L, Blitz MA, Breen J, Rickard AR, Seakins PW.

Phys Chem Chem Phys. 2015 Oct 14;17(38):25342-53. doi: 10.1039/c5cp04083c.

PMID:
26356272
13.

Reanalysis of Rate Data for the Reaction CH3 + CH3 → C2H6 Using Revised Cross Sections and a Linearized Second-Order Master Equation.

Blitz MA, Green NJ, Shannon RJ, Pilling MJ, Seakins PW, Western CM, Robertson SH.

J Phys Chem A. 2015 Jul 16;119(28):7668-82. doi: 10.1021/acs.jpca.5b01002. Epub 2015 Jun 5.

14.

Global Uncertainty Propagation and Sensitivity Analysis in the CH3OCH2 + O2 System: Combining Experiment and Theory To Constrain Key Rate Coefficients in DME Combustion.

Shannon RJ, Tomlin AS, Robertson SH, Blitz MA, Pilling MJ, Seakins PW.

J Phys Chem A. 2015 Jul 16;119(28):7430-8. doi: 10.1021/acs.jpca.5b00620. Epub 2015 Mar 25.

15.

Direct evidence for a substantive reaction between the Criegee intermediate, CH2OO, and the water vapour dimer.

Lewis TR, Blitz MA, Heard DE, Seakins PW.

Phys Chem Chem Phys. 2015 Feb 21;17(7):4859-63. doi: 10.1039/c4cp04750h.

16.

Measurements of Rate Coefficients for Reactions of OH with Ethanol and Propan-2-ol at Very Low Temperatures.

Caravan RL, Shannon RJ, Lewis T, Blitz MA, Heard DE.

J Phys Chem A. 2015 Jul 16;119(28):7130-7. doi: 10.1021/jp505790m. Epub 2014 Oct 1.

17.

Analysis of the kinetics and yields of OH radical production from the CH3OCH2 + O2 reaction in the temperature range 195-650 K: an experimental and computational study.

Eskola AJ, Carr SA, Shannon RJ, Wang B, Blitz MA, Pilling MJ, Seakins PW, Robertson SH.

J Phys Chem A. 2014 Aug 28;118(34):6773-88. doi: 10.1021/jp505422e. Epub 2014 Aug 8.

18.

Low temperature kinetics of the CH3OH + OH reaction.

Gómez Martín JC, Caravan RL, Blitz MA, Heard DE, Plane JM.

J Phys Chem A. 2014 Apr 17;118(15):2693-701. doi: 10.1021/jp5002995. Epub 2014 Apr 4.

19.

A combined experimental and theoretical study of reactions between the hydroxyl radical and oxygenated hydrocarbons relevant to astrochemical environments.

Shannon RJ, Caravan RL, Blitz MA, Heard DE.

Phys Chem Chem Phys. 2014 Feb 28;16(8):3466-78. doi: 10.1039/c3cp54664k.

20.

Experimental and theoretical study of the kinetics and mechanism of the reaction of OH radicals with dimethyl ether.

Carr SA, Still TJ, Blitz MA, Eskola AJ, Pilling MJ, Seakins PW, Shannon RJ, Wang B, Robertson SH.

J Phys Chem A. 2013 Nov 7;117(44):11142-54. doi: 10.1021/jp4070278. Epub 2013 Oct 23.

PMID:
24102528
21.

Gas-phase reactions of OH with methyl amines in the presence or absence of molecular oxygen. An experimental and theoretical study.

Onel L, Thonger L, Blitz MA, Seakins PW, Bunkan AJ, Solimannejad M, Nielsen CJ.

J Phys Chem A. 2013 Oct 17;117(41):10736-45. doi: 10.1021/jp406522z. Epub 2013 Oct 8.

PMID:
24059646
22.

Accelerated chemistry in the reaction between the hydroxyl radical and methanol at interstellar temperatures facilitated by tunnelling.

Shannon RJ, Blitz MA, Goddard A, Heard DE.

Nat Chem. 2013 Sep;5(9):745-9. doi: 10.1038/nchem.1692. Epub 2013 Jun 30.

23.

On the mechanism of iodine oxide particle formation.

Gómez Martín JC, Gálvez O, Baeza-Romero MT, Ingham T, Plane JM, Blitz MA.

Phys Chem Chem Phys. 2013 Oct 7;15(37):15612-22. doi: 10.1039/c3cp51217g.

24.

Mechanism of the reaction of OH with alkynes in the presence of oxygen.

Lockhart J, Blitz MA, Heard DE, Seakins PW, Shannon RJ.

J Phys Chem A. 2013 Jul 3;117(26):5407-18. doi: 10.1021/jp404233b. Epub 2013 Jun 20.

25.

Pressure and temperature dependent photolysis of glyoxal in the 355-414 nm region: evidence for dissociation from multiple states.

Salter RJ, Blitz MA, Heard DE, Pilling MJ, Seakins PW.

Phys Chem Chem Phys. 2013 May 7;15(17):6516-26. doi: 10.1039/c3cp43596b.

PMID:
23531876
26.

Quantum yields for the photolysis of glyoxal below 350 nm and parameterisations for its photolysis rate in the troposphere.

Salter RJ, Blitz MA, Heard DE, Kovács T, Pilling MJ, Rickard AR, Seakins PW.

Phys Chem Chem Phys. 2013 Apr 14;15(14):4984-94. doi: 10.1039/c3cp43597k.

PMID:
23443574
27.

Interception of excited vibrational quantum states by O2 in atmospheric association reactions.

Glowacki DR, Lockhart J, Blitz MA, Klippenstein SJ, Pilling MJ, Robertson SH, Seakins PW.

Science. 2012 Aug 31;337(6098):1066-9. doi: 10.1126/science.1224106.

28.

Laboratory studies of photochemistry and gas phase radical reaction kinetics relevant to planetary atmospheres.

Blitz MA, Seakins PW.

Chem Soc Rev. 2012 Oct 7;41(19):6318-47. doi: 10.1039/c2cs35204d. Epub 2012 Aug 9.

PMID:
22880207
29.

Direct Determination of the Rate Coefficient for the Reaction of OH Radicals with Monoethanol Amine (MEA) from 296 to 510 K.

Onel L, Blitz MA, Seakins PW.

J Phys Chem Lett. 2012 Apr 5;3(7):853-6. doi: 10.1021/jz300200c. Epub 2012 Mar 14.

PMID:
26286410
30.

Rate constants and branching ratios for the reaction of CH radicals with NH3: a combined experimental and theoretical study.

Blitz MA, Talbi D, Seakins PW, Smith IW.

J Phys Chem A. 2012 Jun 21;116(24):5877-85. doi: 10.1021/jp209383t. Epub 2011 Dec 23.

PMID:
22126589
31.

Site-specific rate coefficients for reaction of OH with ethanol from 298 to 900 K.

Carr SA, Blitz MA, Seakins PW.

J Phys Chem A. 2011 Apr 21;115(15):3335-45. doi: 10.1021/jp200186t. Epub 2011 Mar 28.

PMID:
21443222
32.
33.

Experimental and modeling studies of the pressure and temperature dependences of the kinetics and the OH yields in the acetyl + O2 reaction.

Carr SA, Glowacki DR, Liang CH, Baeza-Romero MT, Blitz MA, Pilling MJ, Seakins PW.

J Phys Chem A. 2011 Feb 17;115(6):1069-85. doi: 10.1021/jp1099199. Epub 2011 Jan 14.

PMID:
21235214
34.

Developments in laboratory studies of gas-phase reactions for atmospheric chemistry with applications to isoprene oxidation and carbonyl chemistry.

Seakins PW, Blitz MA.

Annu Rev Phys Chem. 2011;62:351-73. doi: 10.1146/annurev-physchem-032210-102538.

PMID:
21219141
35.

A multidimensional study of the reaction CH2I+O2: products and atmospheric implications.

Gravestock TJ, Blitz MA, Bloss WJ, Heard DE.

Chemphyschem. 2010 Dec 17;11(18):3928-41. doi: 10.1002/cphc.201000575.

PMID:
21125552
36.

Observation of a large negative temperature dependence for rate coefficients of reactions of OH with oxygenated volatile organic compounds studied at 86-112 K.

Shannon RJ, Taylor S, Goddard A, Blitz MA, Heard DE.

Phys Chem Chem Phys. 2010 Nov 7;12(41):13511-4. doi: 10.1039/c0cp00918k. Epub 2010 Sep 22.

PMID:
20859585
37.

Temperature dependent kinetics (195-798 K) and H atom yields (298-498 K) from reactions of (1)CH(2) with acetylene, ethene, and propene.

Gannon KL, Blitz MA, Liang CH, Pilling MJ, Seakins PW, Glowacki DR.

J Phys Chem A. 2010 Sep 9;114(35):9413-24. doi: 10.1021/jp102276j.

PMID:
20704298
38.

Comment on "The conical intersection dominates the generation of tropospheric hydroxyl radicals from NO2 and H2O".

Blitz MA.

J Phys Chem A. 2010 Aug 5;114(30):8016; author reply 8017. doi: 10.1021/jp1033118. No abstract available.

PMID:
20666548
39.

H-atom yields from the photolysis of acetylene and from the reaction of C2H with H2, C2H2, and C2H4.

Kovács T, Blitz MA, Seakins PW.

J Phys Chem A. 2010 Apr 15;114(14):4735-41. doi: 10.1021/jp908285t.

PMID:
20102233
40.

State resolved measurements of a (1)CH(2) removal confirm predictions of the gateway model for electronic quenching.

Gannon KL, Blitz MA, Kovács T, Pilling MJ, Seakins PW.

J Chem Phys. 2010 Jan 14;132(2):024302. doi: 10.1063/1.3263617.

PMID:
20095669
41.

A laser induced fluorescence study relating to physical properties of the iodine monoxide radical.

Gravestock TJ, Blitz MA, Heard DE.

Phys Chem Chem Phys. 2010 Jan 28;12(4):823-34. doi: 10.1039/b910571a. Epub 2009 Nov 24.

PMID:
20066367
42.

H atom formation from benzene and toluene photoexcitation at 248 nm.

Kovács T, Blitz MA, Seakins PW, Pilling MJ.

J Chem Phys. 2009 Nov 28;131(20):204304. doi: 10.1063/1.3262701.

PMID:
19947677
43.

Kinetic studies of atmospherically relevant silicon chemistry. Part II: silicon monoxide reactions.

Gómez Martín JC, Blitz MA, Plane JM.

Phys Chem Chem Phys. 2009 Dec 14;11(46):10945-54. doi: 10.1039/b911745h. Epub 2009 Oct 14.

PMID:
19924330
44.

An experimental confirmation of the products of the reaction between CN radicals and NH3.

Blitz MA, Seakins PW, Smith IW.

Phys Chem Chem Phys. 2009 Dec 14;11(46):10824-6. doi: 10.1039/b917734e. Epub 2009 Oct 20.

PMID:
19924315
45.

Studies on the Cl + C2H5I reaction; site specific abstraction reactions and thermodynamics of adduct formation studied by observation of HCL product.

Wada R, Sharma RC, Blitz MA, Seakins PW.

Phys Chem Chem Phys. 2009 Nov 28;11(44):10417-26. doi: 10.1039/b907793f. Epub 2009 Sep 23.

PMID:
19890528
46.

Kinetic studies of atmospherically relevant silicon chemistry part I: silicon atom reactions.

Gómez Martín JC, Blitz MA, Plane JM.

Phys Chem Chem Phys. 2009 Jan 28;11(4):671-8.

47.

New chemical source of the HCO radical following photoexcitation of glyoxal, (HCO)2.

Salter RJ, Blitz MA, Heard DE, Pilling MJ, Seakins PW.

J Phys Chem A. 2009 Jul 23;113(29):8278-85. doi: 10.1021/jp9030249.

PMID:
19606894
48.

Comment on "Atmospheric hydroxyl radical production from electronically excited NO2 and H2O".

Carr S, Heard DE, Blitz MA.

Science. 2009 Apr 17;324(5925):336; author reply 336. doi: 10.1126/science.1166669.

49.

Kinetics and product branching ratios of the reaction of (1)CH2 with H2 and D2.

Gannon KL, Blitz MA, Pilling MJ, Seakins PW, Klippenstein SJ, Harding LB.

J Phys Chem A. 2008 Oct 2;112(39):9575-83. doi: 10.1021/jp803038s. Epub 2008 Aug 20.

PMID:
18714945
50.

A kinetic and spectroscopic study of the CH3I-Cl and ICH2I-Cl adducts.

Gravestock TJ, Blitz MA, Heard DE.

J Phys Chem A. 2008 Oct 2;112(39):9544-54. doi: 10.1021/jp800372c. Epub 2008 Jun 3.

PMID:
18517182

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