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Items: 19

1.

Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization.

Zhao S, Gensch T, Murray B, Niemeyer ZL, Sigman MS, Biscoe MR.

Science. 2018 Nov 9;362(6415):670-674. doi: 10.1126/science.aat2299. Epub 2018 Sep 20.

2.

Stereospecific Electrophilic Fluorination of Alkylcarbastannatrane Reagents.

Ma X, Diane M, Ralph G, Chen C, Biscoe MR.

Angew Chem Int Ed Engl. 2017 Oct 2;56(41):12663-12667. doi: 10.1002/anie.201704672. Epub 2017 Sep 4.

PMID:
28833888
3.

Stereospecific Palladium-Catalyzed Acylation of Enantioenriched Alkylcarbastannatranes: A General Alternative to Asymmetric Enolate Reactions.

Wang CY, Ralph G, Derosa J, Biscoe MR.

Angew Chem Int Ed Engl. 2017 Jan 16;56(3):856-860. doi: 10.1002/anie.201609930. Epub 2016 Dec 16.

5.

Stereospecific pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides.

Li L, Zhao S, Joshi-Pangu A, Diane M, Biscoe MR.

J Am Chem Soc. 2014 Oct 8;136(40):14027-30. doi: 10.1021/ja508815w. Epub 2014 Sep 23.

6.

Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides.

Li L, Wang CY, Huang R, Biscoe MR.

Nat Chem. 2013 Jul;5(7):607-12. doi: 10.1038/nchem.1652. Epub 2013 May 19.

PMID:
23787752
7.
8.

Palladium-catalyzed borylation of primary alkyl bromides.

Joshi-Pangu A, Ma X, Diane M, Iqbal S, Kribs RJ, Huang R, Wang CY, Biscoe MR.

J Org Chem. 2012 Aug 3;77(15):6629-33. doi: 10.1021/jo301156e. Epub 2012 Jul 23.

9.

Nickel-catalyzed Kumada cross-coupling reactions of tertiary alkylmagnesium halides and aryl bromides/triflates.

Joshi-Pangu A, Wang CY, Biscoe MR.

J Am Chem Soc. 2011 Jun 8;133(22):8478-81. doi: 10.1021/ja202769t. Epub 2011 May 12.

PMID:
21553878
10.

Nickel-catalyzed Negishi cross-coupling reactions of secondary alkylzinc halides and aryl iodides.

Joshi-Pangu A, Ganesh M, Biscoe MR.

Org Lett. 2011 Mar 4;13(5):1218-21. doi: 10.1021/ol200098d. Epub 2011 Feb 10.

11.
12.

Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides.

Biscoe MR, Buchwald SL.

Org Lett. 2009 Apr 16;11(8):1773-5. doi: 10.1021/ol900295u.

13.
14.

A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides.

Biscoe MR, Fors BP, Buchwald SL.

J Am Chem Soc. 2008 May 28;130(21):6686-7. doi: 10.1021/ja801137k. Epub 2008 May 1. Erratum in: J Am Chem Soc. 2011 Oct 19;133(41):16707.

15.

Pd-catalyzed amidation of aryl chlorides using monodentate biaryl phosphine ligands: a kinetic, computational, and synthetic investigation.

Ikawa T, Barder TE, Biscoe MR, Buchwald SL.

J Am Chem Soc. 2007 Oct 31;129(43):13001-7. Epub 2007 Oct 5.

PMID:
17918833
16.
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18.

Requirements for selective hydrophobic acceleration in the reduction of ketones.

Biscoe MR, Uyeda C, Breslow R.

Org Lett. 2004 Nov 11;6(23):4331-4.

PMID:
15524476
19.

Hydrophobically directed selective reduction of ketones.

Biscoe MR, Breslow R.

J Am Chem Soc. 2003 Oct 22;125(42):12718-9.

PMID:
14558814

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