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Interfacial Engineering at the 2D/3D Heterojunction for High-Performance Perovskite Solar Cells.

Niu T, Lu J, Jia X, Xu Z, Tang MC, Barrit D, Yuan N, Ding J, Zhang X, Fan Y, Luo T, Zhang Y, Smilgies DM, Liu Z, Amassian A, Jin S, Zhao K, Liu S.

Nano Lett. 2019 Sep 11. doi: 10.1021/acs.nanolett.9b02781. [Epub ahead of print]


The Growth of Photoactive Porphyrin-Based MOF Thin Films Using the Liquid-Phase Epitaxy Approach and their Optoelectronic Properties.

Ngongang Ndjawa GO, Tchalala MR, Shekhah O, Khan JI, Mansour AE, Czaban-Jóźwiak J, Weselinski LJ, Ait Ahsaine H, Amassian A, Eddaoudi M.

Materials (Basel). 2019 Aug 1;12(15). pii: E2457. doi: 10.3390/ma12152457.


Kinetic Stabilization of the Sol-Gel State in Perovskites Enables Facile Processing of High-Efficiency Solar Cells.

Wang K, Tang MC, Dang HX, Munir R, Barrit D, De Bastiani M, Aydin E, Smilgies DM, De Wolf S, Amassian A.

Adv Mater. 2019 Aug;31(32):e1808357. doi: 10.1002/adma.201808357. Epub 2019 Jun 17.


Impressive near-infrared brightness and singlet oxygen generation from strategic lanthanide-porphyrin double-decker complexes in aqueous solution.

Zhang JX, Chan WL, Xie C, Zhou Y, Chau HF, Maity P, Harrison GT, Amassian A, Mohammed OF, Tanner PA, Wong WK, Wong KL.

Light Sci Appl. 2019 May 22;8:46. doi: 10.1038/s41377-019-0155-9. eCollection 2019.


Lattice anchoring stabilizes solution-processed semiconductors.

Liu M, Chen Y, Tan CS, Quintero-Bermudez R, Proppe AH, Munir R, Tan H, Voznyy O, Scheffel B, Walters G, Kam APT, Sun B, Choi MJ, Hoogland S, Amassian A, Kelley SO, García de Arquer FP, Sargent EH.

Nature. 2019 Jun;570(7759):96-101. doi: 10.1038/s41586-019-1239-7. Epub 2019 May 22.


Conducting and Stretchable PEDOT:PSS Electrodes: Role of Additives on Self-Assembly, Morphology, and Transport.

Dauzon E, Mansour AE, Niazi MR, Munir R, Smilgies DM, Sallenave X, Plesse C, Goubard F, Amassian A.

ACS Appl Mater Interfaces. 2019 May 15;11(19):17570-17582. doi: 10.1021/acsami.9b00934. Epub 2019 Apr 30.


Dynamical Transformation of Two-Dimensional Perovskites with Alternating Cations in the Interlayer Space for High-Performance Photovoltaics.

Zhang Y, Wang P, Tang MC, Barrit D, Ke W, Liu J, Luo T, Liu Y, Niu T, Smilgies DM, Yang Z, Liu Z, Jin S, Kanatzidis MG, Amassian A, Liu SF, Zhao K.

J Am Chem Soc. 2019 Feb 13;141(6):2684-2694. doi: 10.1021/jacs.8b13104. Epub 2019 Jan 29.


Single crystal hybrid perovskite field-effect transistors.

Yu W, Li F, Yu L, Niazi MR, Zou Y, Corzo D, Basu A, Ma C, Dey S, Tietze ML, Buttner U, Wang X, Wang Z, Hedhili MN, Guo C, Wu T, Amassian A.

Nat Commun. 2018 Dec 17;9(1):5354. doi: 10.1038/s41467-018-07706-9.


Multi-inch single-crystalline perovskite membrane for high-detectivity flexible photosensors.

Liu Y, Zhang Y, Yang Z, Ye H, Feng J, Xu Z, Zhang X, Munir R, Liu J, Zuo P, Li Q, Hu M, Meng L, Wang K, Smilgies DM, Zhao G, Xu H, Yang Z, Amassian A, Li J, Zhao K, Liu SF.

Nat Commun. 2018 Dec 13;9(1):5302. doi: 10.1038/s41467-018-07440-2.


The quantum-confined Stark effect in layered hybrid perovskites mediated by orientational polarizability of confined dipoles.

Walters G, Wei M, Voznyy O, Quintero-Bermudez R, Kiani A, Smilgies DM, Munir R, Amassian A, Hoogland S, Sargent E.

Nat Commun. 2018 Oct 11;9(1):4214. doi: 10.1038/s41467-018-06746-5.


Compositional and orientational control in metal halide perovskites of reduced dimensionality.

Quintero-Bermudez R, Gold-Parker A, Proppe AH, Munir R, Yang Z, Kelley SO, Amassian A, Toney MF, Sargent EH.

Nat Mater. 2018 Oct;17(10):900-907. doi: 10.1038/s41563-018-0154-x. Epub 2018 Sep 10.


Overcoming the Ambient Manufacturability-Scalability-Performance Bottleneck in Colloidal Quantum Dot Photovoltaics.

Kirmani AR, Sheikh AD, Niazi MR, Haque MA, Liu M, de Arquer FPG, Xu J, Sun B, Voznyy O, Gasparini N, Baran D, Wu T, Sargent EH, Amassian A.

Adv Mater. 2018 Aug;30(35):e1801661. doi: 10.1002/adma.201801661. Epub 2018 Jul 5.


2D matrix engineering for homogeneous quantum dot coupling in photovoltaic solids.

Xu J, Voznyy O, Liu M, Kirmani AR, Walters G, Munir R, Abdelsamie M, Proppe AH, Sarkar A, García de Arquer FP, Wei M, Sun B, Liu M, Ouellette O, Quintero-Bermudez R, Li J, Fan J, Quan L, Todorovic P, Tan H, Hoogland S, Kelley SO, Stefik M, Amassian A, Sargent EH.

Nat Nanotechnol. 2018 Jun;13(6):456-462. doi: 10.1038/s41565-018-0117-z. Epub 2018 Apr 23.


Phase Transition Control for High Performance Ruddlesden-Popper Perovskite Solar Cells.

Zhang X, Munir R, Xu Z, Liu Y, Tsai H, Nie W, Li J, Niu T, Smilgies DM, Kanatzidis MG, Mohite AD, Zhao K, Amassian A, Liu SF.

Adv Mater. 2018 May;30(21):e1707166. doi: 10.1002/adma.201707166. Epub 2018 Apr 2.


Stable High-Performance Perovskite Solar Cells via Grain Boundary Passivation.

Niu T, Lu J, Munir R, Li J, Barrit D, Zhang X, Hu H, Yang Z, Amassian A, Zhao K, Liu SF.

Adv Mater. 2018 Apr;30(16):e1706576. doi: 10.1002/adma.201706576. Epub 2018 Mar 12.


Functional Two-Dimensional Coordination Polymeric Layer as a Charge Barrier in Li-S Batteries.

Huang JK, Li M, Wan Y, Dey S, Ostwal M, Zhang D, Yang CW, Su CJ, Jeng US, Ming J, Amassian A, Lai Z, Han Y, Li S, Li LJ.

ACS Nano. 2018 Jan 23;12(1):836-843. doi: 10.1021/acsnano.7b08223. Epub 2018 Jan 8.


Enhanced Electrical Conductivity of Molecularly p-Doped Poly(3-hexylthiophene) through Understanding the Correlation with Solid-State Order.

Hynynen J, Kiefer D, Yu L, Kroon R, Munir R, Amassian A, Kemerink M, Müller C.

Macromolecules. 2017 Oct 24;50(20):8140-8148. doi: 10.1021/acs.macromol.7b00968. Epub 2017 Oct 11.


Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction.

Sheikh AD, Munir R, Haque MA, Bera A, Hu W, Shaikh P, Amassian A, Wu T.

ACS Appl Mater Interfaces. 2017 Oct 11;9(40):35018-35029. doi: 10.1021/acsami.7b11250. Epub 2017 Sep 28.


Crossover from band-like to thermally activated charge transport in organic transistors due to strain-induced traps.

Mei Y, Diemer PJ, Niazi MR, Hallani RK, Jarolimek K, Day CS, Risko C, Anthony JE, Amassian A, Jurchescu OD.

Proc Natl Acad Sci U S A. 2017 Aug 15;114(33):E6739-E6748. doi: 10.1073/pnas.1705164114. Epub 2017 Jul 24.


Hybrid tandem quantum dot/organic photovoltaic cells with complementary near infrared absorption.

Kim T, Palmiano E, Liang RZ, Hu H, Murali B, Kirmani AR, Firdaus Y, Gao Y, Sheikh A, Yuan M, Mohammed OF, Hoogland S, Beaujuge PM, Sargent EH, Amassian A.

Appl Phys Lett. 2017 May 29;110(22):223903. doi: 10.1063/1.4984023. Epub 2017 Jun 1.


Hybrid Doping of Few-Layer Graphene via a Combination of Intercalation and Surface Doping.

Mansour AE, Kirmani AR, Barlow S, Marder SR, Amassian A.

ACS Appl Mater Interfaces. 2017 Jun 14;9(23):20020-20028. doi: 10.1021/acsami.7b02886. Epub 2017 Jun 2.


Heterojunction oxide thin-film transistors with unprecedented electron mobility grown from solution.

Faber H, Das S, Lin YH, Pliatsikas N, Zhao K, Kehagias T, Dimitrakopulos G, Amassian A, Patsalas PA, Anthopoulos TD.

Sci Adv. 2017 Mar 31;3(3):e1602640. doi: 10.1126/sciadv.1602640. eCollection 2017 Mar.


Morphology Development in Solution-Processed Functional Organic Blend Films: An In Situ Viewpoint.

Richter LJ, DeLongchamp DM, Amassian A.

Chem Rev. 2017 May 10;117(9):6332-6366. doi: 10.1021/acs.chemrev.6b00618. Epub 2017 Apr 17.


Programmable and coherent crystallization of semiconductors.

Yu L, Niazi MR, Ngongang Ndjawa GO, Li R, Kirmani AR, Munir R, Balawi AH, Laquai F, Amassian A.

Sci Adv. 2017 Mar 3;3(3):e1602462. doi: 10.1126/sciadv.1602462. eCollection 2017 Mar.


Amorphous Tin Oxide as a Low-Temperature-Processed Electron-Transport Layer for Organic and Hybrid Perovskite Solar Cells.

Barbé J, Tietze ML, Neophytou M, Murali B, Alarousu E, Labban AE, Abulikemu M, Yue W, Mohammed OF, McCulloch I, Amassian A, Del Gobbo S.

ACS Appl Mater Interfaces. 2017 Apr 5;9(13):11828-11836. doi: 10.1021/acsami.6b13675. Epub 2017 Mar 21.


Double Charged Surface Layers in Lead Halide Perovskite Crystals.

Sarmah SP, Burlakov VM, Yengel E, Murali B, Alarousu E, El-Zohry AM, Yang C, Alias MS, Zhumekenov AA, Saidaminov MI, Cho N, Wehbe N, Mitra S, Ajia I, Dey S, Mansour AE, Abdelsamie M, Amassian A, Roqan IS, Ooi BS, Goriely A, Bakr OM, Mohammed OF.

Nano Lett. 2017 Mar 8;17(3):2021-2027. doi: 10.1021/acs.nanolett.7b00031. Epub 2017 Feb 7.


A Solution-Doped Polymer Semiconductor:Insulator Blend for Thermoelectrics.

Kiefer D, Yu L, Fransson E, Gómez A, Primetzhofer D, Amassian A, Campoy-Quiles M, Müller C.

Adv Sci (Weinh). 2016 Sep 30;4(1):1600203. doi: 10.1002/advs.201600203. eCollection 2017 Jan.


Hybrid Perovskite Thin-Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases.

Munir R, Sheikh AD, Abdelsamie M, Hu H, Yu L, Zhao K, Kim T, Tall OE, Li R, Smilgies DM, Amassian A.

Adv Mater. 2017 Jan;29(2). doi: 10.1002/adma.201604113. Epub 2016 Nov 7.


Reduced voltage losses yield 10% efficient fullerene free organic solar cells with >1 V open circuit voltages.

Baran D, Kirchartz T, Wheeler S, Dimitrov S, Abdelsamie M, Gorman J, Ashraf RS, Holliday S, Wadsworth A, Gasparini N, Kaienburg P, Yan H, Amassian A, Brabec CJ, Durrant JR, McCulloch I.

Energy Environ Sci. 2016 Dec 1;9(12):3783-3793. doi: 10.1039/c6ee02598f. Epub 2016 Nov 9.


Erratum: N-type organic electrochemical transistors with stability in water.

Giovannitti A, Nielsen CB, Sbircea DT, Inal S, Donahue M, Niazi MR, Hanifi DA, Amassian A, Malliaras GG, Rivnay J, McCulloch I.

Nat Commun. 2016 Dec 15;7:13955. doi: 10.1038/ncomms13955. No abstract available.


Reducing the efficiency-stability-cost gap of organic photovoltaics with highly efficient and stable small molecule acceptor ternary solar cells.

Baran D, Ashraf RS, Hanifi DA, Abdelsamie M, Gasparini N, Röhr JA, Holliday S, Wadsworth A, Lockett S, Neophytou M, Emmott CJ, Nelson J, Brabec CJ, Amassian A, Salleo A, Kirchartz T, Durrant JR, McCulloch I.

Nat Mater. 2017 Mar;16(3):363-369. doi: 10.1038/nmat4797. Epub 2016 Nov 21.


Hybrid organic-inorganic inks flatten the energy landscape in colloidal quantum dot solids.

Liu M, Voznyy O, Sabatini R, García de Arquer FP, Munir R, Balawi AH, Lan X, Fan F, Walters G, Kirmani AR, Hoogland S, Laquai F, Amassian A, Sargent EH.

Nat Mater. 2017 Feb;16(2):258-263. doi: 10.1038/nmat4800. Epub 2016 Nov 14.


N-type organic electrochemical transistors with stability in water.

Giovannitti A, Nielsen CB, Sbircea DT, Inal S, Donahue M, Niazi MR, Hanifi DA, Amassian A, Malliaras GG, Rivnay J, McCulloch I.

Nat Commun. 2016 Oct 7;7:13066. doi: 10.1038/ncomms13066. Erratum in: Nat Commun. 2016 Dec 15;7:13955.


Molecular Design of Semiconducting Polymers for High-Performance Organic Electrochemical Transistors.

Nielsen CB, Giovannitti A, Sbircea DT, Bandiello E, Niazi MR, Hanifi DA, Sessolo M, Amassian A, Malliaras GG, Rivnay J, McCulloch I.

J Am Chem Soc. 2016 Aug 17;138(32):10252-9. doi: 10.1021/jacs.6b05280. Epub 2016 Aug 8.


Carrier Transport Enhancement in Conjugated Polymers through Interfacial Self-Assembly of Solution-State Aggregates.

Zhao K, Khan HU, Li R, Hu H, Amassian A.

ACS Appl Mater Interfaces. 2016 Aug 3;8(30):19649-57. doi: 10.1021/acsami.6b04508. Epub 2016 Jul 22.


Double-Sided Junctions Enable High-Performance Colloidal-Quantum-Dot Photovoltaics.

Liu M, de Arquer FP, Li Y, Lan X, Kim GH, Voznyy O, Jagadamma LK, Abbas AS, Hoogland S, Lu Z, Kim JY, Amassian A, Sargent EH.

Adv Mater. 2016 Jun;28(21):4142-8. doi: 10.1002/adma.201506213. Epub 2016 Apr 1.


KO(t)Bu-Initiated Aryl C-H Iodination: A Powerful Tool for the Synthesis of High Electron Affinity Compounds.

Shi Q, Zhang S, Zhang J, Oswald VF, Amassian A, Marder SR, Blakey SB.

J Am Chem Soc. 2016 Mar 30;138(12):3946-9. doi: 10.1021/jacs.5b12259. Epub 2016 Mar 21.


Radio Frequency Coplanar ZnO Schottky Nanodiodes Processed from Solution on Plastic Substrates.

Semple J, Rossbauer S, Burgess CH, Zhao K, Jagadamma LK, Amassian A, McLachlan MA, Anthopoulos TD.

Small. 2016 Apr;12(15):1993-2000. doi: 10.1002/smll.201503110. Epub 2016 Feb 25.


Quasi Two-Dimensional Dye-Sensitized In2O3 Phototransistors for Ultrahigh Responsivity and Photosensitivity Photodetector Applications.

Mottram AD, Lin YH, Pattanasattayavong P, Zhao K, Amassian A, Anthopoulos TD.

ACS Appl Mater Interfaces. 2016 Feb;8(7):4894-902. doi: 10.1021/acsami.5b11210. Epub 2016 Feb 10.


Ligand-Stabilized Reduced-Dimensionality Perovskites.

Quan LN, Yuan M, Comin R, Voznyy O, Beauregard EM, Hoogland S, Buin A, Kirmani AR, Zhao K, Amassian A, Kim DH, Sargent EH.

J Am Chem Soc. 2016 Mar 2;138(8):2649-55. doi: 10.1021/jacs.5b11740. Epub 2016 Feb 17.


Correction to High-Efficiency Colloidal Quantum Dot Photovoltaics via Robust Self-Assembled Monolayers.

Kim GH, García de Arquer FP, Yoon YJ, Lan X, Liu M, Voznyy O, Krishnan Jagadamma L, Saud Abbas A, Yang Z, Fan F, Ip AH, Kanjanaboos P, Hoogland S, Amassian A, Kim JY, Sargent EH.

Nano Lett. 2016 Jan 13;16(1):822. doi: 10.1021/acs.nanolett.5b04797. Epub 2015 Dec 18. No abstract available.


Solution-printed organic semiconductor blends exhibiting transport properties on par with single crystals.

Niazi MR, Li R, Qiang Li E, Kirmani AR, Abdelsamie M, Wang Q, Pan W, Payne MM, Anthony JE, Smilgies DM, Thoroddsen ST, Giannelis EP, Amassian A.

Nat Commun. 2015 Nov 23;6:8598. doi: 10.1038/ncomms9598.


Hybrid Modulation-Doping of Solution-Processed Ultrathin Layers of ZnO Using Molecular Dopants.

Schießl SP, Faber H, Lin YH, Rossbauer S, Wang Q, Zhao K, Amassian A, Zaumseil J, Anthopoulos TD.

Adv Mater. 2016 May;28(20):3952-9. doi: 10.1002/adma.201503200. Epub 2015 Oct 5.


Toward Additive-Free Small-Molecule Organic Solar Cells: Roles of the Donor Crystallization Pathway and Dynamics.

Abdelsamie M, Treat ND, Zhao K, McDowell C, Burgers MA, Li R, Smilgies DM, Stingelin N, Bazan GC, Amassian A.

Adv Mater. 2015 Dec 2;27(45):7285-92. doi: 10.1002/adma.201503395. Epub 2015 Sep 29.


Bromination of Graphene: A New Route to Making High Performance Transparent Conducting Electrodes with Low Optical Losses.

Mansour AE, Dey S, Amassian A, Tanielian MH.

ACS Appl Mater Interfaces. 2015 Aug 19;7(32):17692-9. doi: 10.1021/acsami.5b03274. Epub 2015 Aug 4.


A thieno[3,2-b][1]benzothiophene isoindigo building block for additive- and annealing-free high-performance polymer solar cells.

Yue W, Ashraf RS, Nielsen CB, Collado-Fregoso E, Niazi MR, Yousaf SA, Kirkus M, Chen HY, Amassian A, Durrant JR, McCulloch I.

Adv Mater. 2015 Aug 26;27(32):4702-7. doi: 10.1002/adma.201501841. Epub 2015 Jul 14.


Core-shell heterostructured metal oxide arrays enable superior light-harvesting and hysteresis-free mesoscopic perovskite solar cells.

Mahmood K, Swain BS, Amassian A.

Nanoscale. 2015 Aug 14;7(30):12812-9. doi: 10.1039/c5nr02874d.


High Electron Mobility Thin-Film Transistors Based on Solution-Processed Semiconducting Metal Oxide Heterojunctions and Quasi-Superlattices.

Lin YH, Faber H, Labram JG, Stratakis E, Sygellou L, Kymakis E, Hastas NA, Li R, Zhao K, Amassian A, Treat ND, McLachlan M, Anthopoulos TD.

Adv Sci (Weinh). 2015 May 26;2(7):1500058. eCollection 2015 Jul.


Direct Correlation of Charge Transfer Absorption with Molecular Donor:Acceptor Interfacial Area via Photothermal Deflection Spectroscopy.

Buchaca-Domingo E, Vandewal K, Fei Z, Watkins SE, Scholes FH, Bannock JH, de Mello JC, Richter LJ, DeLongchamp DM, Amassian A, Heeney M, Salleo A, Stingelin N.

J Am Chem Soc. 2015 Apr 29;137(16):5256-9. doi: 10.1021/ja512410f. Epub 2015 Apr 16.


Highly Efficient Hybrid Photovoltaics Based on Hyperbranched Three-Dimensional TiO₂ Electron Transporting Materials.

Mahmood K, Swain BS, Amassian A.

Adv Mater. 2015 May 13;27(18):2859-65. doi: 10.1002/adma.201500336. Epub 2015 Mar 23. No abstract available.


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