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Items: 23

1.

Facile Quantum Yield Determination via NMR Actinometry.

Ji Y, DiRocco DA, Hong CM, Wismer MK, Reibarkh M.

Org Lett. 2018 Apr 20;20(8):2156-2159. doi: 10.1021/acs.orglett.8b00391. Epub 2018 Mar 28.

PMID:
29589943
2.

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis.

Twilton J, Christensen M, DiRocco DA, Ruck RT, Davies IW, MacMillan DWC.

Angew Chem Int Ed Engl. 2018 Feb 28. doi: 10.1002/anie.201800749. [Epub ahead of print]

PMID:
29490112
3.

The Evolution of Chemical High-Throughput Experimentation To Address Challenging Problems in Pharmaceutical Synthesis.

Krska SW, DiRocco DA, Dreher SD, Shevlin M.

Acc Chem Res. 2017 Dec 19;50(12):2976-2985. doi: 10.1021/acs.accounts.7b00428. Epub 2017 Nov 27.

PMID:
29172435
4.

Oxyfunctionalization of the Remote C-H Bonds of Aliphatic Amines by Decatungstate Photocatalysis.

Schultz DM, Lévesque F, DiRocco DA, Reibarkh M, Ji Y, Joyce LA, Dropinski JF, Sheng H, Sherry BD, Davies IW.

Angew Chem Int Ed Engl. 2017 Nov 27;56(48):15274-15278. doi: 10.1002/anie.201707537. Epub 2017 Oct 26.

PMID:
29044797
5.

Asymmetric Hydrogen Bonding Catalysis for the Synthesis of Dihydroquinazoline-Containing Antiviral, Letermovir.

Chung CK, Liu Z, Lexa KW, Andreani T, Xu Y, Ji Y, DiRocco DA, Humphrey GR, Ruck RT.

J Am Chem Soc. 2017 Aug 9;139(31):10637-10640. doi: 10.1021/jacs.7b05806. Epub 2017 Jul 25.

PMID:
28737937
6.

A multifunctional catalyst that stereoselectively assembles prodrugs.

DiRocco DA, Ji Y, Sherer EC, Klapars A, Reibarkh M, Dropinski J, Mathew R, Maligres P, Hyde AM, Limanto J, Brunskill A, Ruck RT, Campeau LC, Davies IW.

Science. 2017 Apr 28;356(6336):426-430. doi: 10.1126/science.aam7936.

PMID:
28450641
7.

Acridinium-Based Photocatalysts: A Sustainable Option in Photoredox Catalysis.

Joshi-Pangu A, Lévesque F, Roth HG, Oliver SF, Campeau LC, Nicewicz D, DiRocco DA.

J Org Chem. 2016 Aug 19;81(16):7244-9. doi: 10.1021/acs.joc.6b01240. Epub 2016 Jul 25.

PMID:
27454776
8.

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis.

Corcoran EB, Pirnot MT, Lin S, Dreher SD, DiRocco DA, Davies IW, Buchwald SL, MacMillan DW.

Science. 2016 Jul 15;353(6296):279-83. doi: 10.1126/science.aag0209. Epub 2016 Jun 23.

9.

Photoredox-Catalyzed Hydroxymethylation of Heteroaromatic Bases.

Huff CA, Cohen RD, Dykstra KD, Streckfuss E, DiRocco DA, Krska SW.

J Org Chem. 2016 Aug 19;81(16):6980-7. doi: 10.1021/acs.joc.6b00811. Epub 2016 Jun 23.

PMID:
27315015
10.

Chemistry informer libraries: a chemoinformatics enabled approach to evaluate and advance synthetic methods.

Kutchukian PS, Dropinski JF, Dykstra KD, Li B, DiRocco DA, Streckfuss EC, Campeau LC, Cernak T, Vachal P, Davies IW, Krska SW, Dreher SD.

Chem Sci. 2016 Apr 21;7(4):2604-2613. doi: 10.1039/c5sc04751j. Epub 2016 Jan 26.

11.

Development of a Direct Photocatalytic C-H Fluorination for the Preparative Synthesis of Odanacatib.

Halperin SD, Kwon D, Holmes M, Regalado EL, Campeau LC, DiRocco DA, Britton R.

Org Lett. 2015 Nov 6;17(21):5200-3. doi: 10.1021/acs.orglett.5b02532. Epub 2015 Oct 20.

PMID:
26484983
12.

Late-stage functionalization of biologically active heterocycles through photoredox catalysis.

Dirocco DA, Dykstra K, Krska S, Vachal P, Conway DV, Tudge M.

Angew Chem Int Ed Engl. 2014 May 5;53(19):4802-6. doi: 10.1002/anie.201402023. Epub 2014 Mar 26.

PMID:
24677697
13.
14.

Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines.

DiRocco DA, Rovis T.

Angew Chem Int Ed Engl. 2012 Jun 11;51(24):5904-6. doi: 10.1002/anie.201202442. Epub 2012 May 4. No abstract available.

15.

Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis.

DiRocco DA, Rovis T.

J Am Chem Soc. 2012 May 16;134(19):8094-7. doi: 10.1021/ja3030164. Epub 2012 May 2.

16.

Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes.

DiRocco DA, Oberg KM, Rovis T.

J Am Chem Soc. 2012 Apr 11;134(14):6143-5. doi: 10.1021/ja302031v. Epub 2012 Mar 28.

17.

Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.

DiRocco DA, Noey EL, Houk KN, Rovis T.

Angew Chem Int Ed Engl. 2012 Mar 5;51(10):2391-4. doi: 10.1002/anie.201107597. Epub 2012 Jan 26. No abstract available.

18.

N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams.

Zhao X, DiRocco DA, Rovis T.

J Am Chem Soc. 2011 Aug 17;133(32):12466-9. doi: 10.1021/ja205714g. Epub 2011 Jul 25.

19.

Organocatalytic hydroacylation of unactivated alkenes.

DiRocco DA, Rovis T.

Angew Chem Int Ed Engl. 2011 Aug 22;50(35):7982-3. doi: 10.1002/anie.201102920. Epub 2011 Jun 30.

20.

Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives.

DiRocco DA, Rovis T.

J Am Chem Soc. 2011 Jul 13;133(27):10402-5. doi: 10.1021/ja203810b. Epub 2011 Jun 16.

21.

Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction.

Um JM, DiRocco DA, Noey EL, Rovis T, Houk KN.

J Am Chem Soc. 2011 Jul 27;133(29):11249-54. doi: 10.1021/ja202444g. Epub 2011 Jul 6.

22.

Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step.

Moore JL, Silvestri AP, de Alaniz JR, DiRocco DA, Rovis T.

Org Lett. 2011 Apr 1;13(7):1742-5. doi: 10.1021/ol200256a. Epub 2011 Feb 28.

23.

Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity.

DiRocco DA, Oberg KM, Dalton DM, Rovis T.

J Am Chem Soc. 2009 Aug 12;131(31):10872-4. doi: 10.1021/ja904375q.

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