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Page 1
Diquinol Functionality Boosts the Superoxide Dismutase Mimicry of a Zn(II) Complex with a Redox-Active Ligand while Maintaining Catalyst Stability and Enhanced Activity in Phosphate Solution.
Moore JL, Oppelt J, Senft L, Franke A, Scheitler A, Dukes MW, Alix HB, Saunders AC, Karbalaei S, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. Moore JL, et al. Among authors: goldsmith cr. Inorg Chem. 2022 Dec 12;61(49):19983-19997. doi: 10.1021/acs.inorgchem.2c03256. Epub 2022 Nov 29. Inorg Chem. 2022. PMID: 36445832
A macrocyclic quinol-containing ligand enables high catalase activity even with a redox-inactive metal at the expense of the ability to mimic superoxide dismutase.
Karbalaei S, Franke A, Oppelt J, Aziz T, Jordan A, Pokkuluri PR, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. Karbalaei S, et al. Among authors: goldsmith cr. Chem Sci. 2023 Sep 5;14(36):9910-9922. doi: 10.1039/d3sc02398b. eCollection 2023 Sep 20. Chem Sci. 2023. PMID: 37736643 Free PMC article.
Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling.
Senft L, Moore JL, Franke A, Fisher KR, Scheitler A, Zahl A, Puchta R, Fehn D, Ison S, Sader S, Ivanović-Burmazović I, Goldsmith CR. Senft L, et al. Among authors: goldsmith cr. Chem Sci. 2021 Jul 13;12(31):10483-10500. doi: 10.1039/d1sc02465e. eCollection 2021 Aug 11. Chem Sci. 2021. PMID: 34447541 Free PMC article.
36 results