Format

Send to

Choose Destination
ChemSusChem. 2015 May 22;8(10):1737-44. doi: 10.1002/cssc.201500349. Epub 2015 Apr 17.

Electron bottleneck in the charge/discharge mechanism of lithium titanates for batteries.

Author information

1
Department of Advanced Materials for Energy, Catalonia Institute for Energy Research, Jardins de les Dones de Negre, 1, 08930 Sant Adria de Besos (Spain). edgar.ventosa@rub.de.
2
Department of Advanced Materials for Energy, Catalonia Institute for Energy Research, Jardins de les Dones de Negre, 1, 08930 Sant Adria de Besos (Spain).
3
ICREA and Institut Català de Nanociència i Nanotecnologia (ICN2), Campus UAB, 08193 Bellaterra, CAT (Spain).
4
Departament d'Electronica, Universitat de Barcelona, C. de Martí i Franquès, 1, 08028 Barcelona (Spain).

Abstract

The semi-solid flow battery (SSFB) is a promising storage energy technology featured by employing semi-solid fluid electrodes containing conductive additive and active Li-ion battery materials. The state of art anode material for SSFB is Li4 Ti5 O12 (LTO). This work shows that LTO improves drastically the performance in fluid electrode via hydrogen annealing manifesting the importance of the electrical conductivity of the active material in SSFBs. On the other hand, the properties of fluid electrodes allow the contributions of ionic and electrical resistance to be separated in operando. The asymmetric overpotential observed in Li4 Ti5 O12 and TiO2 is proposed to originate from the so-called electron bottleneck mechanism based on the transformation from electrically insulator to conductor upon (de-)lithiation, or vice versa, which should be considered when modelling, evaluating or designing advanced materials based on Li4 Ti5 O12 , TiO2 or others with insulating-conducting behavior materials.

KEYWORDS:

batteries; conductivity; metal oxides; oxidation; reduction

PMID:
25892099
PMCID:
PMC4529663
DOI:
10.1002/cssc.201500349
[Indexed for MEDLINE]
Free PMC Article

Supplemental Content

Full text links

Icon for Wiley Icon for PubMed Central
Loading ...
Support Center