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J Am Chem Soc. 2013 Oct 16;135(41):15342-5. doi: 10.1021/ja408971t. Epub 2013 Oct 2.

Direct construction of quaternary carbons from tertiary alcohols via photoredox-catalyzed fragmentation of tert-alkyl N-phthalimidoyl oxalates.

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1
Department of Chemistry, University of California , Irvine, California 92697-2025, United States.

Abstract

A convenient method for the direct construction of quaternary carbons from tertiary alcohols by visible-light photoredox coupling of tert-alkyl N-phthalimidoyl oxalate intermediates with electron-deficient alkenes is reported.

PMID:
24074152
PMCID:
PMC3856227
DOI:
10.1021/ja408971t
[Indexed for MEDLINE]
Free PMC Article

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