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Org Lett. 2005 Aug 4;7(16):3493-5.

A total synthesis of (+/-)-trans-kumausyne.

Author information

1
Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, CO 80309-0215, USA.

Abstract

A short total synthesis of (+/-)-trans-kumausyne is reported. Key steps include a tandem ring-opening-ring-closing metathesis and the effective introduction of the pentenyl side chain by allylation-cross metathesis. [reaction: see text].

PMID:
16048325
DOI:
10.1021/ol051199t
[Indexed for MEDLINE]

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