Search Page
Save citations to file
Email citations
Send citations to clipboard
Add to Collections
Add to My Bibliography
Create a file for external citation management software
Your saved search
Your RSS Feed
Filters
Results by year
Table representation of search results timeline featuring number of search results per year.
Year | Number of Results |
---|---|
2010 | 1 |
2012 | 1 |
2024 | 0 |
Search Results
2 results
Results by year
Filters applied: . Clear all
Page 1
Regio- and enantioselective intermolecular hydroacylation: substrate-directed addition of salicylaldehydes to homoallylic sulfides.
J Am Chem Soc. 2010 Nov 24;132(46):16330-3. doi: 10.1021/ja107198e. Epub 2010 Oct 29.
J Am Chem Soc. 2010.
PMID: 21033718
Hydroacylations between homoallylic sulfides, containing a substrate-bound directing group, and salicylaldehyde derivatives occur in the presence of a spiro-phosphoramidite ligand, (R)-SIPHOS-PE, to give alpha-branched ketones in >20:1 selectivity and up t …
Hydroacylations between homoallylic sulfides, containing a substrate-bound directing group, and salicylaldehyde derivatives occur in the pre …
Rhodium-phosphoramidite catalyzed alkene hydroacylation: mechanism and octaketide natural product synthesis.
von Delius M, Le CM, Dong VM.
von Delius M, et al.
J Am Chem Soc. 2012 Sep 12;134(36):15022-32. doi: 10.1021/ja305593y. Epub 2012 Aug 31.
J Am Chem Soc. 2012.
PMID: 22938187
Deuterium labeling studies show that branched hydride insertion is fully reversible, whereas linear hydride insertion is largely irreversible and turnover-limiting. We propose that ligand (R(a),R,R)-SIPHOS-PE effectively suppresses decarbonylation, and helps …
Deuterium labeling studies show that branched hydride insertion is fully reversible, whereas linear hydride insertion is largely irreversibl …
Item in Clipboard
Cite
Cite