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Environ Sci Pollut Res Int. 2017 Dec;24(36):28102-28120. doi: 10.1007/s11356-017-0285-7. Epub 2017 Oct 9.

Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution.

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Department of Chemistry, Environmental Pollution Control Laboratory, Aristotle University of Thessaloniki, Thessaloniki, Greece.
Research Centre for Toxic Compounds in the Environment, Masaryk University, Brno, Czech Republic.
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany.
School of Science and Technology, Man-Technology-Environment Research Center (MTM), Örebro University, Orebro, Sweden.
Department of Chemistry, Environmental Pollution Control Laboratory, Aristotle University of Thessaloniki, Thessaloniki, Greece.
Department of Chemical Engineering and Environmental Research Center, Izmir Institute of Technology, Urla, Izmir, Turkey.
Department of Environmental Engineering, Dokuz Eylul University, Kaynaklar, Izmir, Turkey.
Institute of Nuclear Technology and Radiation Protection, NCSR Demokritos Institute, Athens, Greece.
Department of Chemistry, Environmental Chemical Processes Laboratory, University of Crete, Heraklion, Greece.


The occurrence and atmospheric behavior of tri- to deca-polybrominated diphenyl ethers (PBDEs) were investigated during a 2-week campaign concurrently conducted in July 2012 at four background sites around the Aegean Sea. The study focused on the gas/particle (G/P) partitioning at three sites (Ag. Paraskevi/central Greece/suburban, Finokalia/southern Greece/remote coastal, and Urla/Turkey/rural coastal) and on the size distribution at two sites (Neochorouda/northern Greece/rural inland and Finokalia/southern Greece/remote coastal). The lowest mean total (G + P) concentrations of ∑7PBDE (BDE-28, BDE-47, BDE-66, BDE-99, BDE-100, BDE-153, BDE-154) and BDE-209 (0.81 and 0.95 pg m-3, respectively) were found at the remote site Finokalia. Partitioning coefficients, K P, were calculated, and their linear relationships with ambient temperature and the physicochemical properties of the analyzed PBDE congeners, i.e., the subcooled liquid pressure (P L°) and the octanol-air partition coefficient (K OA), were investigated. The equilibrium adsorption (P L°-based) and absorption (K OA-based) models, as well as a steady-state absorption model including an equilibrium and a non-equilibrium term, both being functions of log K OA, were used to predict the fraction Φ of PBDEs associated with the particle phase. The steady-state model proved to be superior to predict G/P partitioning of BDE-209. The distribution of particle-bound PBDEs across size fractions < 0.95, 0.95-1.5, 1.5-3.0, 3.0-7.2, and > 7.2 μm indicated a positive correlation between the mass median aerodynamic diameter and log P L° for the less brominated congeners, whereas a negative correlation was observed for the high brominated congeners. The potential source regions of PBDEs were acknowledged as a combination of long-range transport with short-distance sources.


Absorption/adsorption models; Aerosol mass size distribution; Gas/particle partitioning; Long-range transport

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